**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1076-43-3 |Benzene-d6 | | 214-061-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 11 45 48/23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. May cause cancer. Toxic : danger of serious damage
to health by prolonged exposure through inhalation, contact with skin
and if swallowed.Hygroscopic.
Potential Health Effects
Eye:
Causes redness and pain.
Skin:
Causes skin irritation. If absorbed, causes symptoms similar to
those of ingestion. May cause dermatitis.
Ingestion:
May cause central nervous system depression, characterized by
excitement, followed by headache, dizziness, drowsiness, and nausea.
Advanced stages may cause collapse, unconsciousness, coma and
possible death due to respiratory failure. Causes throat
constriction, vomiting, convulsions, and shock.
Inhalation:
May cause respiratory tract irritation. May cause adverse central
nervous system effects including headache, convulsions, and possible
death. May cause effects similar to those described for ingestion.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. Prolonged or repeated exposure may cause adverse
reproductive effects. May cause liver and kidney damage. May cause
bone marrow abnormalities with damage to blood forming tissues. May
cause cancer in humans. May cause anemia and other blood cell
abnormalities.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Possible aspiration hazard. Get medical aid
immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide. Water may be ineffective. Water may
spread fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Wear a self contained breathing
apparatus and appropriate Personal protection. (See Exposure
Controls, Personal Protection section). Remove all sources of
ignition.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Appearance: colourless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 79 deg C @ 760.00mm Hg
Freezing/Melting Point: 6.8 deg C
Autoignition Temperature: 555 deg C ( 1,031.00 deg F)
Flash Point: -11 deg C ( 12.20 deg F)
Explosion Limits, lower: 1.20 vol %
Explosion Limits, upper: 8.00 vol %
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9500
Molecular Formula: C6D6
Molecular Weight: 84.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, bromine trifluoride, chlorine trifluoride, liquid
chlorine, nitric acid, perchlorates, silver perchlorate, sodium
peroxide, oxygen, ozone, nitrosyl perchlorate, bromine pentafluoride,
chromic anhydride.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1076-43-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Benzene-d6 -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BENZENE
Hazard Class: 3
UN Number: 1114
Packing Group: II
IMO
Shipping Name: BENZENE
Hazard Class: 3.2
UN Number: 1114
Packing Group: II
RID/ADR
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 45 May cause cancer.
R 48/23/24/25 Toxic : danger of serious damage to
health by prolonged exposure through inhalation,
contact with skin and if swallowed.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1076-43-3: No information available.
United Kingdom Occupational Exposure Limits
Canada
CAS# 1076-43-3 is listed on Canada's NDSL List.
CAS# 1076-43-3 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 1076-43-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/16/2002 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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MLU-acid (aqueous solution with 6% HF, 5.4% HCl) - custom grade
| 7647-01-0 |
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| 480-65-9 |
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4,6-Dinitroresorcinol
| 616-74-0 |
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3-Benzyloxyacetophenone, 97%
| 34068-01-4 |
|
Diphenyl Ditelluride, 98%
| 32294-60-3 |
|
Dibutyl ditelluride
| 77129-69-2 |
|
3-Amino-2-Chloropyridine, 96%
| 6298-19-7 |
|
Isophytol, 95%
| 505-32-8 |
|
1,3-Diethoxybenzene, 95%
| 2049-73-2 |
|
2-Methyl-2-thiazoline, 97%
| 2346-00-1 |
|
Sodium Glycolate, 97%
| 2836-32-0 |
|
1,4-Diethoxybenzene, 98%
| 122-95-2 |
|
Carbamoyl-DL-Aspartic Acid, 98%
| 923-37-5 |
|
1,2-Diethoxybenzene, 98%
| 2050-46-6 |
|
4-N-Propylbiphenyl, 98%
| 10289-45-9 |
|
Pyridoxal Hydrochloride, 99%
| 65-22-5 |
|
delta-Decalactone, 95%
| 705-86-2 |
|
L-Ascorbic Acid Sodium Salt, 99%
| 134-03-2 |
|
2,4-Dichlorobenzotrifluoride, 99%
| 320-60-5 |
|
Chromium(III)oxide, 99%
| 1308-38-9 |
|
Acetone-d6 with 0.03% TMS, 99.9 atom% D
| 666-52-4 |
|
Acetonitrile-d3, 99.9 Atom% D
| 2206-26-0 |
|
Benzene-d6
| 71-43-2 |
|
Benzene-d6, with 0.03% TMS, 99.6 atom% D
| 1076-43-3 |
|
5-Methoxyindole-2-carboxylic acid, 99%
| 4382-54-1 |
|
Chloroform-d, stabilized with silver foil, 99.8 atom% D
| 865-49-6 |
|
Deuterium oxide, packaged in 0.75 ml ampules, 99.8 atom% D
| 7789-20-0 |
|
(Methylsulfoxide)-d6, with 1% TMS, packaged in 0.75 ml ampules, 99.9
| 2206-27-1 |
|
(Methylsulfoxide)-d6, with 0.03% TMS, 99.9 atom% D
| 2206-27-1 |
|
Methyl-d3 alcohol-d, packaged in 0.75 ml ampules, 100.0 atom % D
| 67-56-1 |
|
Methyl-d3 alcohol-d, with 0.03% TMS, packaged in 0.75 ml ampules,
| 67-56-1 |
|
n-Acetyl-L-phenylalanyl-3,5-diiodo-L-tyrosine
| 3786-08-1 |
|
Pyridine-d5, packaged in 0.75 ml ampules, 99.8 atom% D
| 7291-22-7 |
|
Pyridine-d5, with 0.03% TMS, 100.0 atom% D
| 7291-22-7 |
|
Toluene-d8
| 108-88-3 |
|
2,3,5-Tribromothiophene, 98%
| 3141-24-0 |
|
Polyvinylpyrrolidone K-90, 20% solution in water
| 9003-39-8 |
|
Phenylurea, 97%
| 64-10-8 |
|
2,4-Dichlorophenethylamine, 98%
| 52516-13-9 |
|
Calcium iodate hydrate, 98%
| 7789-80-2 |
|
2-Fluorophenethylamine, 99%
| 52721-69-4 |
|
3-Fluorophenethylamine, 99%
| 404-70-6 |
|
4-Fluorophenethylamine, 99%
| 1583-88-6 |
|
3,4,5-Trimethoxybenzylamine, 96%
| 18638-99-8 |
|
Oxalic Acid Bis-(Cyclohexylidenehydrazide)
| 370-81-0 |
|
2,5-Dihydroxy-4-Benzenediacetic Acid, 99+%
| 5488-16-4 |
|
Phosgene iminium chloride, 98%
| 33842-02-3 |
|
2-Bromophenethylalcohol, 99%
| 1074-16-4 |
|
3-Bromophenethylalcohol, 97%
| 28229-69-8 |
|
2-Chlorophenethylalcohol, 98%
| 19819-95-5 |
|
|