**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 320-60-5 |2,4-Dichlorobenzotrifluoride | 98-99% | 206-278-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause burning sensations, coughing,
wheezing, laryngitis, shortness of breath and headache.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. May cause burning
sensation, coughing, wheezing, laryngitis, shortness of breath,
headache, nausea, and vomiting.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Combustible liquid. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. Containers may explode when heated. Runoff from fire control
or dilution water may cause pollution.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Do not breathe dust, vapor, mist, or
gas. Do not get in eyes, on skin, or on clothing. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep container tightly closed. Keep away from heat, sparks and flame.
Do not ingest or inhale. Use only in a chemical fume hood. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 320-60-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 117-118 deg C@760mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 72 deg C ( 161.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.484g/cm3
Molecular Formula: C7H3Cl2F3
Molecular Weight: 215
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not currently available.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen fluoride
gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 320-60-5: CZ5566877
LD50/LC50:
CAS# 320-60-5: Oral, rat: LD50 = 2150 mg/kg.
Carcinogenicity:
2,4-Dichlorobenzotrifluoride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 320-60-5: 2
Canada
CAS# 320-60-5 is listed on Canada's NDSL List.
CAS# 320-60-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 320-60-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/16/2002 Revision #3 Date: 5/23/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
MLU-acid (aqueous solution with 6% HF, 5.4% HCl) - custom grade
| 7647-01-0 |
|
Isodehydroacetic Acid, 98%
| 480-65-9 |
|
4,6-Dinitroresorcinol
| 616-74-0 |
|
3-Benzyloxyacetophenone, 97%
| 34068-01-4 |
|
Diphenyl Ditelluride, 98%
| 32294-60-3 |
|
Dibutyl ditelluride
| 77129-69-2 |
|
3-Amino-2-Chloropyridine, 96%
| 6298-19-7 |
|
Isophytol, 95%
| 505-32-8 |
|
1,3-Diethoxybenzene, 95%
| 2049-73-2 |
|
2-Methyl-2-thiazoline, 97%
| 2346-00-1 |
|
Sodium Glycolate, 97%
| 2836-32-0 |
|
1,4-Diethoxybenzene, 98%
| 122-95-2 |
|
Carbamoyl-DL-Aspartic Acid, 98%
| 923-37-5 |
|
1,2-Diethoxybenzene, 98%
| 2050-46-6 |
|
4-N-Propylbiphenyl, 98%
| 10289-45-9 |
|
Pyridoxal Hydrochloride, 99%
| 65-22-5 |
|
delta-Decalactone, 95%
| 705-86-2 |
|
L-Ascorbic Acid Sodium Salt, 99%
| 134-03-2 |
|
2,4-Dichlorobenzotrifluoride, 99%
| 320-60-5 |
|
Chromium(III)oxide, 99%
| 1308-38-9 |
|
Acetone-d6 with 0.03% TMS, 99.9 atom% D
| 666-52-4 |
|
Acetonitrile-d3, 99.9 Atom% D
| 2206-26-0 |
|
Benzene-d6
| 71-43-2 |
|
Benzene-d6, with 0.03% TMS, 99.6 atom% D
| 1076-43-3 |
|
5-Methoxyindole-2-carboxylic acid, 99%
| 4382-54-1 |
|
Chloroform-d, stabilized with silver foil, 99.8 atom% D
| 865-49-6 |
|
Deuterium oxide, packaged in 0.75 ml ampules, 99.8 atom% D
| 7789-20-0 |
|
(Methylsulfoxide)-d6, with 1% TMS, packaged in 0.75 ml ampules, 99.9
| 2206-27-1 |
|
(Methylsulfoxide)-d6, with 0.03% TMS, 99.9 atom% D
| 2206-27-1 |
|
Methyl-d3 alcohol-d, packaged in 0.75 ml ampules, 100.0 atom % D
| 67-56-1 |
|
Methyl-d3 alcohol-d, with 0.03% TMS, packaged in 0.75 ml ampules,
| 67-56-1 |
|
n-Acetyl-L-phenylalanyl-3,5-diiodo-L-tyrosine
| 3786-08-1 |
|
Pyridine-d5, packaged in 0.75 ml ampules, 99.8 atom% D
| 7291-22-7 |
|
Pyridine-d5, with 0.03% TMS, 100.0 atom% D
| 7291-22-7 |
|
Toluene-d8
| 108-88-3 |
|
2,3,5-Tribromothiophene, 98%
| 3141-24-0 |
|
Polyvinylpyrrolidone K-90, 20% solution in water
| 9003-39-8 |
|
Phenylurea, 97%
| 64-10-8 |
|
2,4-Dichlorophenethylamine, 98%
| 52516-13-9 |
|
Calcium iodate hydrate, 98%
| 7789-80-2 |
|
2-Fluorophenethylamine, 99%
| 52721-69-4 |
|
3-Fluorophenethylamine, 99%
| 404-70-6 |
|
4-Fluorophenethylamine, 99%
| 1583-88-6 |
|
3,4,5-Trimethoxybenzylamine, 96%
| 18638-99-8 |
|
Oxalic Acid Bis-(Cyclohexylidenehydrazide)
| 370-81-0 |
|
2,5-Dihydroxy-4-Benzenediacetic Acid, 99+%
| 5488-16-4 |
|
Phosgene iminium chloride, 98%
| 33842-02-3 |
|
2-Bromophenethylalcohol, 99%
| 1074-16-4 |
|
3-Bromophenethylalcohol, 97%
| 28229-69-8 |
|
2-Chlorophenethylalcohol, 98%
| 19819-95-5 |
|
|