**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 110-02-1 |Thiophene | >99 | 203-729-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 20/21/22 36
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation, in contact with skin and if
swallowed. Irritating to eyes.Stench.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause nausea and vomiting.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Extremely flammable liquid and vapor. Vapor may
cause flash fire. Vapors are heavier than air and may travel to a
source of ignition and flash back. Vapors can spread along the ground
and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Use only with adequate
ventilation. Keep away from heat, sparks and flame. Avoid breathing
vapor.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area. Separate from
oxidizing materials.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
CAS# 110-02-1:
Russia: 20 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless - APHA: 10 max
Odor: stench
pH: Not available.
Vapor Pressure: 79.7 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 84 deg C @ 760 mm Hg
Freezing/Melting Point: -38 deg C
Autoignition Temperature: 395 deg C ( 743.00 deg F)
Flash Point: -9 deg C ( 15.80 deg F)
Explosion Limits, lower: 1.5%
Explosion Limits, upper: 12.5%
Decomposition Temperature: >850 deg C
Solubility in water: insoluble
Specific Gravity/Density: 1.0500 g/cm3
Molecular Formula: C4H4S
Molecular Weight: 84.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 110-02-1: XM7350000
LD50/LC50:
CAS# 110-02-1: Dermal, guinea pig: LD50 = >20 mL/kg; Inhalation,
mouse: LC50 = 9500 mg/m3/2H; Oral, mouse: LD50 = 420 mg/kg; Oral,
rat: LD50 = 1400 mg/kg.
Carcinogenicity:
Thiophene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Thiophene
Hazard Class: 3
UN Number: 2414
Packing Group: II
IMO
Shipping Name: THIOPHENE
Hazard Class: 3
UN Number: 2414
Packing Group: II
RID/ADR
Shipping Name: Thiophene
Hazard Class: 3
UN Number: 2414
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36 Irritating to eyes.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 110-02-1: 3
Canada
CAS# 110-02-1 is listed on Canada's DSL List.
CAS# 110-02-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 110-02-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/02/1999 Revision #3 Date: 8/06/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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3-Amino-2-naphthoic acid, tech. 85%
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| 90-02-8 |
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NG-Nitro-D-arginine-methyl ester hydrochloride
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3-Methyl-1H-pyrazole-1-carboxamide
| 873-50-7 |
|
Silver acetate, 90% (titr.)
| 563-63-3 |
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| 5103-42-4 |
|
7-Nitroindazole
| 2942-42-9 |
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| 0-01-1 |
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Silver Chloride, 99+%
| 7783-90-6 |
|
Diethyldithiocarbamic acid, silver salt
| 1470-61-7 |
|
Silver Iodide, 99%
| 7783-96-2 |
|
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| 70-49-5 |
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| 0-01-1 |
|
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| 41443-28-1 |
|
PAPA NONOate
| 146672-58-4 |
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PROLI/NO
| 0-01-1 |
|
PTIO
| 0-01-1 |
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| 5680-79-5 |
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L-Sepiapterin
| 17094-01-8 |
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Ammonium sulfate
| 7783-20-2 |
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| 16142-27-1 |
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trans-2-Aminomethyl-1-cyclohexanol, 97%
| 5691-09-8 |
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| 9004-95-9 |
|
Quinidine, anhydrous, 99+%
| 56-54-2 |
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Silver nitrate, p.a.
| 7761-88-8 |
|
Thiophene, benzene free, 99.5%
| 110-02-1 |
|
Silver(i)oxide, p.a.
| 20667-12-3 |
|
Silver Sulfate, 10 g/lt Solution in Sulfuric Acid P.A.
| 7664-93-9 |
|
1H-Benzimidazole-2-ethanamine dihydrochloride, 97%
| 0-01-1 |
|
Sodium dispersion in toluene, 30 wt% < 0.1mm particle size
| 108-88-3 |
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Spermine NONOate
| 0-01-1 |
|
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| 69056-38-8 |
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L-Thiocitrulline
| 156719-37-8 |
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TRIM
| 25371-96-4 |
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| 2497-91-8 |
|
Dimethyl sulfite, 99%
| 616-42-2 |
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|