**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1470-61-7 |Silver diethyldithiocarbamate | 99 | 216-003-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. Can cause nervous system damage.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to
those described for ingestion. The toxicological properties of this
substance have not been fully investigated.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
inhalation or ingestion of silver salts may cause argyria
characterized by a permanent blue-gray discoloration of the eyes,
skin, mucous membranes, and internal organs. This malady results from
the accumulation of silver in the body.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. Combustion generates toxic fumes.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Consider reclamation rather than disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid contact with skin and eyes. Avoid breathing dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep refrigerated. (Store below 4C/39F.) Store
protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 1470-61-7:
United Kingdom, WEL - TWA: (listed as silver soluble compounds):
mg/m3 TWA (as Ag)
United Kingdom, WEL - STEL: (listed as silver soluble compounds):
0.03 mg/m3 STEL (as Ag)
United States OSHA: 0.01 mg/m3 TWA (listed under Silver soluble
compounds).
Belgium - TWA: (listed as silver soluble compounds): 0.01 mg/m3 V
(as Ag)
France - VME: (listed as silver soluble compounds): 0.01 mg/m3 VM
(as Ag)
Germany: (listed as silver soluble compounds): 0.01 mg/m3 VME (as
Japan: (listed as silver compounds): 0.01 mg/m3 OEL (as Ag)
Malaysia: (listed as silver soluble compounds): 0.01 mg/m3 TWA (a
Ag)
Netherlands: (listed as silver soluble compounds): 0.01 mg/m3 MAC
Ag)
Spain: (listed as silver soluble compounds): 0.01 mg/m3 VLA-ED (a
Ag)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: beige green
Odor: characteristic odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 172-175 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C5H10AgNS2
Molecular Weight: 256.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. However, may decompose if heated. May discolor on exposure
to light.
Conditions to Avoid:
Light, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1470-61-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Silver diethyldithiocarbamate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1470-61-7: 1
Canada
CAS# 1470-61-7 is listed on Canada's DSL List.
CAS# 1470-61-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1470-61-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 5/26/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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| 65473-13-4 |
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2-Chloroanthraquinone, 99%
| 131-09-9 |
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1H-Benzimidazole-2-methanol, 97%
| 4856-97-7 |
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3-Amino-2-naphthoic acid, tech. 85%
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Resorcinol, 90% (Titr.)
| 108-46-3 |
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Riboflavin 98%
| 83-88-5 |
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Rosin, gum
| 8050-09-7 |
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Rubidium Chloride, 99+%
| 7791-11-9 |
|
Salicylaldehyde, 98%
| 90-02-8 |
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Avidin (monomeric)-agarose
| 0-01-1 |
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Methyl 2-Iodobenzoate, 99+%
| 610-97-9 |
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NG-Nitro-L-arginine-methyl ester hydrochloride
| 51298-62-5 |
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NG-Nitro-D-arginine-methyl ester hydrochloride
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Ethyl butyrate, 99%
| 105-54-4 |
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2,4-Dimethyl-3-Ethylpyrrole, 96+% (GC)
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| 69-72-7 |
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Silver, Shot, 99.9999%, 1-3 mm
| 7440-22-4 |
|
3-Methyl-1H-pyrazole-1-carboxamide
| 873-50-7 |
|
Silver acetate, 90% (titr.)
| 563-63-3 |
|
Ammonium Pyrrolidine Dithiocarbamate
| 5103-42-4 |
|
7-Nitroindazole
| 2942-42-9 |
|
S-Nitroso-N-acetyl-D,L-penicillamine
| 0-01-1 |
|
Silver Chloride, 99+%
| 7783-90-6 |
|
Diethyldithiocarbamic acid, silver salt
| 1470-61-7 |
|
Silver Iodide, 99%
| 7783-96-2 |
|
DL-Mercaptosuccinic acid (pract), 98% (titr.)
| 70-49-5 |
|
S-Nitroso-L-glutathione
| 0-01-1 |
|
Odq, 98%
| 41443-28-1 |
|
PAPA NONOate
| 146672-58-4 |
|
PROLI/NO
| 0-01-1 |
|
PTIO
| 0-01-1 |
|
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| 5680-79-5 |
|
L-Sepiapterin
| 17094-01-8 |
|
Ammonium sulfate
| 7783-20-2 |
|
SIN-1 hydrochloride
| 16142-27-1 |
|
trans-2-Aminomethyl-1-cyclohexanol, 97%
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|
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| 9004-95-9 |
|
Quinidine, anhydrous, 99+%
| 56-54-2 |
|
Silver nitrate, p.a.
| 7761-88-8 |
|
Thiophene, benzene free, 99.5%
| 110-02-1 |
|
Silver(i)oxide, p.a.
| 20667-12-3 |
|
Silver Sulfate, 10 g/lt Solution in Sulfuric Acid P.A.
| 7664-93-9 |
|
1H-Benzimidazole-2-ethanamine dihydrochloride, 97%
| 0-01-1 |
|
Sodium dispersion in toluene, 30 wt% < 0.1mm particle size
| 108-88-3 |
|
Spermine NONOate
| 0-01-1 |
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| 69056-38-8 |
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L-Thiocitrulline
| 156719-37-8 |
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TRIM
| 25371-96-4 |
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| 2497-91-8 |
|
Dimethyl sulfite, 99%
| 616-42-2 |
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|