**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 5103-42-4 |2,2'-bi-1h-indene-1,1',3,3'(2h,2'h)-te| 100.0 | 225-823-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes and skin.The toxicological properties of this
material have not been fully investigated.Air sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
May cause respiratory tract irritation. Low hazard for usual
industrial handling. The toxicological properties of this substance
have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use agent most appropriate to extinguish
fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Minimize dust generation and
accumulation. Avoid contact with skin and eyes. Avoid ingestion and
inhalation. Store protected from air. Wash clothing before reuse.
Storage:
Store in a cool, dry place. Keep from contact with oxidizing
materials. Keep containers tightly closed. Do not expose to air.
Store below 50C.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 5103-42-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow
Odor: none reported
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 155 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: > 155 deg C
Solubility in water: Soluble in water.
Specific Gravity/Density: Not available.
Molecular Formula: C5H12N2S2
Molecular Weight: 164.2174
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. However, may decompose if heated.
Conditions to Avoid:
Incompatible materials, exposure to air, temperatures above 55C.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 5103-42-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,2'-bi-1h-indene-1,1',3,3'(2h,2'h)-tetrone,2,2'-dihydroxy- -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, NOS
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, NOS
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, NOS
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 5103-42-4: No information available.
Canada
CAS# 5103-42-4 is listed on Canada's NDSL List.
CAS# 5103-42-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5103-42-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/29/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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| 65473-13-4 |
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| 131-09-9 |
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1H-Benzimidazole-2-methanol, 97%
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3-Amino-2-naphthoic acid, tech. 85%
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Rosin, gum
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Rubidium Chloride, 99+%
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Salicylaldehyde, 98%
| 90-02-8 |
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Avidin (monomeric)-agarose
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Methyl 2-Iodobenzoate, 99+%
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NG-Nitro-L-arginine-methyl ester hydrochloride
| 51298-62-5 |
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NG-Nitro-D-arginine-methyl ester hydrochloride
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Ethyl butyrate, 99%
| 105-54-4 |
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2,4-Dimethyl-3-Ethylpyrrole, 96+% (GC)
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|
Salicylic Acid, reagent ACS
| 69-72-7 |
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Silver, Shot, 99.9999%, 1-3 mm
| 7440-22-4 |
|
3-Methyl-1H-pyrazole-1-carboxamide
| 873-50-7 |
|
Silver acetate, 90% (titr.)
| 563-63-3 |
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| 5103-42-4 |
|
7-Nitroindazole
| 2942-42-9 |
|
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| 0-01-1 |
|
Silver Chloride, 99+%
| 7783-90-6 |
|
Diethyldithiocarbamic acid, silver salt
| 1470-61-7 |
|
Silver Iodide, 99%
| 7783-96-2 |
|
DL-Mercaptosuccinic acid (pract), 98% (titr.)
| 70-49-5 |
|
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| 0-01-1 |
|
Odq, 98%
| 41443-28-1 |
|
PAPA NONOate
| 146672-58-4 |
|
PROLI/NO
| 0-01-1 |
|
PTIO
| 0-01-1 |
|
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| 5680-79-5 |
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L-Sepiapterin
| 17094-01-8 |
|
Ammonium sulfate
| 7783-20-2 |
|
SIN-1 hydrochloride
| 16142-27-1 |
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trans-2-Aminomethyl-1-cyclohexanol, 97%
| 5691-09-8 |
|
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| 9004-95-9 |
|
Quinidine, anhydrous, 99+%
| 56-54-2 |
|
Silver nitrate, p.a.
| 7761-88-8 |
|
Thiophene, benzene free, 99.5%
| 110-02-1 |
|
Silver(i)oxide, p.a.
| 20667-12-3 |
|
Silver Sulfate, 10 g/lt Solution in Sulfuric Acid P.A.
| 7664-93-9 |
|
1H-Benzimidazole-2-ethanamine dihydrochloride, 97%
| 0-01-1 |
|
Sodium dispersion in toluene, 30 wt% < 0.1mm particle size
| 108-88-3 |
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Spermine NONOate
| 0-01-1 |
|
(6R)-5,6,7,8-Tetrahydro-L-biopterin.dihydrochloride
| 69056-38-8 |
|
L-Thiocitrulline
| 156719-37-8 |
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TRIM
| 25371-96-4 |
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2-Chloro-3,5-Dinitrobenzoic Acid, 80%
| 2497-91-8 |
|
Dimethyl sulfite, 99%
| 616-42-2 |
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|