**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 110-19-0 |Isobutyl acetate | 100 % | 203-745-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11 66
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Repeated exposure may cause skin dryness or
cracking.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. May cause narcotic effects in
high concentration.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use with adequate
ventilation. Avoid contact with skin and eyes. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry place. Store in a tightly closed
container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels.
Exposure Limits
CAS# 110-19-0:
United Kingdom, WEL - TWA: 150 ppm TWA; 724 mg/m3 TWA
United Kingdom, WEL - STEL: 187 ppm STEL; 903 mg/m3 STEL
United States OSHA: 150 ppm TWA; 700 mg/m3 TWA
Belgium - TWA: 150 ppm VLE; 723 mg/m3 VLE
France - VME: 150 ppm VME; 710 mg/m3 VME
France - VLE: 200 ppm VLE; 940 mg/m3 VLE
Germany: 100 ppm TWA; 480 mg/m3 TWA
Malaysia: 150 ppm TWA; 713 mg/m3 TWA
Netherlands: 150 mg/m3 STEL
Netherlands: 700 mg/m3 MAC
Spain: 150 ppm VLA-ED; 724 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Fruit-like odor.
pH: Not available.
Vapor Pressure: 10 mm Hg @ 20 C
Viscosity: 0.7 mPa s 20 C
Boiling Point: 118 deg C
Freezing/Melting Point: -99 deg C
Autoignition Temperature: 793 deg F ( 422.78 deg C)
Flash Point: 64 deg F ( 17.78 deg C)
Explosion Limits, lower: 2.4
Explosion Limits, upper: 10.5
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble in water.
Specific Gravity/Density: 0.8685
Molecular Formula: C6H12O2
Molecular Weight: 116.0828
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, ignition
sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents and strong bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 110-19-0: AI4025000
LD50/LC50:
CAS# 110-19-0: Draize test, rabbit, eye: 500 mg/24H Moderate; Draize
test, rabbit, skin: 500 mg/24H Moderate; Oral, rabbit: LD50 = 4763
mg/kg; Oral, rat: LD50 = 13400 mg/kg; Skin, rabbit: LD50 = >17400
mg/kg.
Carcinogenicity:
Isobutyl acetate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ISOBUTYL ACETATE
Hazard Class: 3
UN Number: 1213
Packing Group: II
IMO
Shipping Name: ISOBUTYL ACETATE
Hazard Class: 3
UN Number: 1213
Packing Group: II
RID/ADR
Shipping Name: ISOBUTYL ACETATE
Hazard Class: 3
UN Number: 1213
Packing group: II
USA RQ: CAS# 110-19-0: 5000 lb final RQ (Listed under Butyl acetate); 2270 kg fi
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
R 66 Repeated exposure may cause skin dryness or
cracking.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 25 Avoid contact with eyes.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 110-19-0: 1
Canada
CAS# 110-19-0 is listed on Canada's DSL List.
CAS# 110-19-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 110-19-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/12/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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