**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 110-71-4 |Ethylene glycol dimethyl ether | 99 | 203-794-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 11 19 20 60 61
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. May form explosive peroxides. Harmful by
inhalation. May impair fertility. May cause harm to the unborn child.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be absorbed through the skin in
harmful amounts.
Ingestion:
May cause irritation of the digestive tract. May cause systemic
toxicity with acidosis. May cause cardiac disturbances. May cause
central nervous system depression.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Inhalation at high concentrations may cause CNS depression and
asphixiation.
Chronic:
May cause liver and kidney damage. In laboratory studies with
ethylene glycol dimethyl ether, birth defects, fetotoxicity,
embryolethality, anemia, bone marrow damage, hemolysis,
immunosuppression and damage to the male reproductive tissues have
been observed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
soap and water for at least 15 minutes while removing contaminated
clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable Liquid. Can release vapors that form
explosive mixtures at temperatures above the flashpoint. Use water
spray to keep fire-exposed containers cool. May form explosive
peroxides. Vapors are heavier than air and may travel to a source of
ignition and flash back. Vapors can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use dry chemical,
carbon dioxide, or alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Ground and bond containers when
transferring material. Avoid contact with eyes, skin, and clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep container tightly closed. Avoid ingestion and
inhalation. If peroxide formation is suspected, do not open or move
container. Do not pressurize, cut, weld, braze, solder, drill, grind,
or expose empty containers to heat, sparks or open flames. Use only
with adequate ventilation.
Storage:
Store in a tightly closed container. Keep from contact with
oxidizing materials. Store in a cool, dry, well-ventilated area away
from incompatible substances. Flammables-area. After opening, purge
container with nitrogen before reclosing. Periodically test for
peroxide formation on long-term storage. Addition of water or
appropriate reducing materials will lessen peroxide formation.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear chemical goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: water-white
Odor: Strong.
pH: Not available.
Vapor Pressure: 61.2 mm Hg @ 20 deg C
Viscosity: 0.455 mPas 25 deg C
Boiling Point: 84 - 86 deg C @ 760mm Hg
Freezing/Melting Point: -58 deg C
Autoignition Temperature: 395 deg F ( 201.67 deg C)
Flash Point: -6 deg C ( 21.20 deg F)
Explosion Limits, lower: 1.60 vol %
Explosion Limits, upper: 10.40 vol %
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: .8600g/cm3
Molecular Formula: C4H10O2
Molecular Weight: 90.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Prolonged exposure
to air and sunlight may form unstable peroxides.
Conditions to Avoid:
Light, ignition sources, exposure to air, excess heat, evaporating to
near dryness.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 110-71-4: KI1451000
LD50/LC50:
CAS# 110-71-4: Oral, mouse: LD50 = 3200 mg/kg.
Carcinogenicity:
Ethylene glycol dimethyl ether -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 1,2-DIMETHOXYETHANE
Hazard Class: 3
UN Number: 2252
Packing Group: II
IMO
Shipping Name: 1,2-DIMETHOXYETHANE
Hazard Class: 3.2
UN Number: 2252
Packing Group: II
RID/ADR
Shipping Name: 1,2-DIMETHOXYETHANE
Dangerous Goods Code: 3(3B)
UN Number: 2252
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 19 May form explosive peroxides.
R 20 Harmful by inhalation.
R 60 May impair fertility.
R 61 May cause harm to the unborn child.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 110-71-4: 1
United Kingdom Occupational Exposure Limits
Canada
CAS# 110-71-4 is listed on Canada's DSL List.
CAS# 110-71-4 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 110-71-4: OEL-RUSSIA:STEL 10 mg/m3
US FEDERAL
TSCA
CAS# 110-71-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/25/1999 Revision #3 Date: 3/01/2001
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Creatinine, 99+%
| 60-27-5 |
|
Cholic acid sodium salt, 99% (Titr.)
| 361-09-1 |
|
2,2-Dichlorooctanoic Acid, 95%
| 102272-30-0 |
|
5-Methoxy-2-Nitrobenzoic Acid, 97%
| 1882-69-5 |
|
Ethyl Phenoxyacetate, 98%
| 2555-49-9 |
|
1-Naphthyl Butyrate, 98%
| 3121-70-8 |
|
2,5-Dimethyl-3,4-Diphenylcyclopentadienone Dimer, 97%
| 38883-84-0 |
|
2,6-Dichlorophenyl Isocyanate, 98%
| 39920-37-1 |
|
Ethyl Acetate, 99.5+%, Spectrophotometric Grade
| 141-78-6 |
|
Ethyl acetoacetate, p.a.
| 141-97-9 |
|
Ethylbenzene, 99%
| 100-41-4 |
|
Tetraethyl Orthosilicate
| 78-10-4 |
|
Sodium bisulfite, reagent ACS
| 7446-09-5 |
|
4'-Phenoxyacetophenone, 98%
| 5031-78-7 |
|
3-Amino-2-Methylbenzoic Acid, 97%
| 52130-17-3 |
|
1,2-Dibromoethane, p.a.
| 106-93-4 |
|
Benzyl Sulfide, 98%
| 538-74-9 |
|
2-Amino-4,5-Dimethoxybenzoic Acid, 98%
| 5653-40-7 |
|
2-Carboxycinnamic Acid, 98%
| 612-40-8 |
|
Benzyl sulphone, 98%
| 620-32-6 |
|
1-Naphthol-4-sulfonic acid sodium salt (pract)
| 6099-57-6 |
|
(2S)-Bornane-10,2-Sultam, 99+%, (99+% e.e.)
| 108448-77-7 |
|
1,2-Dichloroethane, spectrophotometric grade, 99+%
| 107-06-2 |
|
Holmium atomic absorption standard solution, 1 mg/ml Ho in 2% HNO3
| 7440-60-0 |
|
Ethylene glycol dimethyl ether, 99+%
| 110-71-4 |
|
Ethyl 2-cyano-3-methyl-2-butenoate, 98%
| 759-58-0 |
|
Ethylenediamine, p.a.
| 107-15-3 |
|
Octanesulfonyl Chloride, 98%
| 7795-95-1 |
|
Iodine Monobromide, 98%
| 7789-33-5 |
|
Ammonium Iron(III)-Citrate
| 1185-57-5 |
|
3-Methyl-2,4-pentanedione, 96%
| 815-57-6 |
|
Iron (III) Chloride, Anhydrous, Reagent (Powder), 96% (Titr.)
| 7705-08-0 |
|
1-Propylpyridinium bromide, 98%
| 873-71-2 |
|
2',5'-Dihydroxypropiophenone, 98%
| 938-46-5 |
|
Ammonium iron(III) oxalate trihydrate, 98%
| 13268-42-3 |
|
3-Bromocyclohexene, 95%
| 1521-51-3 |
|
2,4-Dibromo-2,4-Dimethyl-3-Pentanone, 98%
| 17346-16-6 |
|
1,2-Epoxy-7-octene, 97%
| 19600-63-6 |
|
Allyl Chloroacetate, 98%
| 2916-14-5 |
|
1-Allylimidazole, 97%
| 31410-01-2 |
|
2,4,6-Trichlorobenzoyl chloride, 98%
| 4136-95-2 |
|
Iron(III) chloride hexahydrate, pure, granulated, 99%
| 7705-08-0 |
|
Benzylurea, 98%
| 538-32-9 |
|
Benzyl Acetoacetate, 98%
| 5396-89-4 |
|
4-Amino-3-nitrophenol, 98%
| 610-81-1 |
|
Iron(III) nitrate nonahydrate, reagent ACS
| 7782-61-8 |
|
1-Aminopyridinium iodide, 98%
| 6295-87-0 |
|
Iron(II) chloride tetrahydrate, 99+%
| 13478-10-9 |
|
2,4-Dibromomesitylene, 98%
| 6942-99-0 |
|
5-Amino-2-chlorobenzoic acid, 97%
| 89-54-3 |
|
|