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MSDS 
:
 Iron (III) Chloride, Anhydrous, Reagent (Powder), 96% (Titr.)
CAS 
:
 7705-08-0
SYNONYMS 
:
 Ferric chloride; Iron (III) chloride; Iron sesquichloride; Iron     trichloride
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7705-08-0 |Ferric chloride | 96 | 231-729-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 22 34

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns.Corrosive.Water-reactive.

Potential Health Effects
Eye:
Causes eye burns. Contact produces irritation, tearing, and
burning pain. When substance becomes wet or comes in contact with
moisture of the mucous membranes, it will cause irritation. Iron
particles which become imbedded in the eye may lead to siderosis in
varying degrees. A yellowish green or brown discoloration of the eye
is the first sign of siderosis.
Skin:
Causes skin burns. Contact with skin causes irritation and possible
burns, especially if the skin is wet or moist. May be absorbed
through the skin. May cause skin rash (in milder cases), and cold and
clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause low blood pressure, rapid
heartbeat, skin discoloration, and possible coma. Ingestion of iron
compounds may cause hemorrhage and necrosis of the stomach with
shock, severe diarrhea, and possible coma.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects.
Chronic:
Prolonged or repeated exposure may cause adverse reproductive
effects. May cause liver and kidney damage. Effects may be delayed.
Laboratory experiments have resulted in mutagenic effects. Repeated
exposure may increase iron levels in the liver, spleen and lymphatic
system. Damage may occur in the spleen and liver.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
If water-reactive products are embedded in the skin, no water should
be applied. The embedded products should be covered with a light
oil.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
The use of Deferoxamine as a chelating agent should be determined
only by qualified medical personnel.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Reacts violently with water giving off flammable
gas which may explode. Material will not burn. During a fire,
irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Water Reactive. Material will react
with water and may release a flammable and/or toxic gas. May ignite
or explode on contact with steam or moist air. May re-ignite after
fire is extinguished.
Extinguishing Media:
Use dry sand or earth to smother fire. Substance is noncombustible;
use agent most appropriate to extinguish surrounding fire. DO NOT
USE WATER! Do NOT get water inside containers. Contact professional
fire-fighters immediately. Cool containers with flooding quantities
of water until well after fire is out.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Do not expose spill to water.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not allow
water to get into the container because of violent reaction. Minimize
dust generation and accumulation. Keep container tightly closed. Do
not get on skin or in eyes. Do not ingest or inhale. Do not allow
contact with water. Discard contaminated shoes. Keep from contact
with moist air and steam.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Keep away from water. Store protected from
moisture.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
CAS# 7705-08-0:

Belgium - TWA: (listed as iron salts (soluble)): 1 mg/m3 VLE (as
Malaysia: (listed as iron salts (soluble)): 1 mg/m3 TWA (as Fe)
Netherlands: (listed as iron salts (soluble)): 1 mg/m3 MAC (as Fe
Spain: (listed as iron salts (soluble)): 1 mg/m3 VLA-ED (as Fe)

Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or
other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Color: dark gray to black or brown
Odor: Not available.
pH: 2.0 (0.1M aq. sol.)
Vapor Pressure: < 1 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 316 deg C
Freezing/Melting Point: 300 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 2.9 (water=1)
Molecular Formula: Cl3Fe
Molecular Weight: 162.206

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures. Combines vigorously
or explosively with water.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Water.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases, chlorine.
Hazardous Polymerization: Has not been reported

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 7705-08-0: LJ9100000
LD50/LC50:
CAS# 7705-08-0: Oral, mouse: LD50 = 200 mg/kg; Oral, rat: LD50 = 316
mg/kg.
Carcinogenicity:
Ferric chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
Water flea Daphnia: TLm = 15 ppm; 96 Hr; fresh waterFish: Striped
bass: LC50 = 6 mg/L; 24-96 Hr; Static bioassay (as iron)Fish: Striped
bass: LC50 = 4 mg/L; 24-96 Hr; Static bioassay (as iron)

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: FERRIC CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1773
Packing Group: III
IMO
Shipping Name: FERRIC CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1773
Packing Group: III
RID/ADR
Shipping Name: FERRIC CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 1773
Packing group: III
USA RQ: CAS# 7705-08-0: 1000 lb final RQ; 454 kg final RQ

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
WGK (Water Danger/Protection)
CAS# 7705-08-0: 1
Canada
CAS# 7705-08-0 is listed on Canada's DSL List.
CAS# 7705-08-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7705-08-0 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 7/07/1999 Revision #4 Date: 3/18/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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