**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-42-2 |Diethanolamine | 99.0 | 203-868-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 38 41 48/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to skin. Risk of serious damage to
eyes. Harmful : danger of serious damage to health by prolonged
exposure if swallowed.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes severe eye irritation. May cause inflammation of the cornea
and iris.
Skin:
May cause skin irritation. May be absorbed through the skin.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May cause lung damage.
Chronic:
May cause liver and kidney damage. May cause reproductive and fetal
effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
Use carbon dioxide or dry chemical. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use with adequate
ventilation. Avoid contact with eyes, skin, and clothing. Avoid
ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Storage under
a nitrogen blanket has been recommended.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 111-42-2:
Belgium - TWA: 0.46 ppm VLE; 2 mg/m3 VLE
France - VME: 3 ppm VME; 15 mg/m3 VME
Germany: 15 mg/m3 TWA (inhalable fraction)
Germany: Skin absorber
Malaysia: 0.46 ppm TWA; 2 mg/m3 TWA
Netherlands: 0.46 ppm MAC; 2 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 0.46 ppm VLA-ED; 2 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Mild ammoniacal odor.
pH: Not available.
Vapor Pressure: < 0.01 mm Hg @ 20 deg C
Viscosity: 352 cps 30 deg C
Boiling Point: 268 deg C
Freezing/Melting Point: 28 deg C
Autoignition Temperature: 662 deg C ( 1,223.60 deg F)
Flash Point: 138 deg C ( 280.40 deg F)
Explosion Limits, lower: 1.6
Explosion Limits, upper: 9.8
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 1.09
Molecular Formula: C4H11NO2
Molecular Weight: 105.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Reacts with carbon dioxide from the air and formaldehyde.
Incompatibile with strong oxidizers, strong acids, acid anhydrides,
and halides. Corrosive to copper, copper alloys, zinc, and galvanized
iron. Heating of ethanolamines above 60C will cause darkening of
material.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-42-2: KL2975000
LD50/LC50:
CAS# 111-42-2: Dermal, guinea pig: LD50 = 11900 uL/kg; Draize test,
rabbit, eye: 5500 mg Severe; Draize test, rabbit, eye: 750 ug/24H
Severe; Draize test, rabbit, skin: 500 mg/24H Mild; Oral, mouse:
LD50 = 3300 mg/kg; Oral, rabbit: LD50 = 2200 mg/kg; Oral, rat: LD50 =
620 uL/kg; Skin, rabbit: LD50 = 7640 uL/kg.
Carcinogenicity:
Diethanolamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Bluegill/Sunfish: 1800mg/L; 24HFish: Goldfish: 800mg/L;
24HFish: Fathead Minnow: LC50 = >100.00 mg/L; 96 Hr.; Static
ConditionBacteria: Phytobacterium phosphoreum: EC50 = 5000 mg/L; 5
minutes; Microtox test
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CAUSTIC ALKALI LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1719
Packing Group: III
IMO
Shipping Name: CAUSTIC ALKALI LIQUIDS, N.O.S.
Hazard Class: 8
UN Number: 1719
Packing Group: III
RID/ADR
Shipping Name: Caustic Alkali Liquids, N.O.S.
Hazard Class: 8
UN Number: 1719
Packing group:
USA RQ: CAS# 111-42-2: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
R 48/22 Harmful : danger of serious damage to health
by prolonged exposure if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 46 If swallowed, seek medical advice immediately
and show this container or label.
WGK (Water Danger/Protection)
CAS# 111-42-2: 1
Canada
CAS# 111-42-2 is listed on Canada's DSL List.
CAS# 111-42-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-42-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/08/1999 Revision #4 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
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N-BOC-O-Benzyl-L-Serine, 98%
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(1R,2R)-2-Amino-1-Phenylpropane-1,3-Diol
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|
4,5-Dimethoxy-2-Nitrobenzoic Acid, 98%
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| 6372-14-1 |
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Tetracyanoethylene, 98%
| 670-54-2 |
|
2,5-Lutidine, 97%
| 589-93-5 |
|
(S)-1,2,3,4-Tetrahydroisoquinolylmethan-3-ol
| 0-01-1 |
|
Gamma-L-Glutamyl-L-Alanine
| 5875-41-2 |
|
Ethyl (3S)-4-Bromo-3-Hydroxybutanoate, 90%
| 95537-36-3 |
|
Albumin from Eggs
| 9006-50-2 |
|
Cyclohexane, 99+%, Spectrophotometric Grade
| 110-82-7 |
|
Cyclohexanol, 98%
| 108-93-0 |
|
Cyclohexene, 99%
| 110-83-8 |
|
L-Valine Ethyl Ester Hydrochloride, 99%
| 17609-47-1 |
|
D-(-)-Fructose, P.A.
| 57-48-7 |
|
D-(-)-Ribose, 99.5+%
| 50-69-1 |
|
Ethyl (R)-Nipecotate L-Tartarate, 97%
| 167392-57-6 |
|
D-Sorbitol, P.A.
| 50-70-4 |
|
Diethylphosphonoacetic Acid
| 3095-95-2 |
|
N-[(S)-(+)-Ethoxycarbonyl)-3-Phenylpropyl]-L-Alanine, 97%
| 82717-96-2 |
|
D-(+)-Xylose, p.a.
| 58-86-6 |
|
Dansyl Chloride, 98%
| 605-65-2 |
|
Diethyl(4-Nitrobenzyl)Phosphonate
| 0-01-1 |
|
4-tert-Amylcalix(8)Arene
| 93503-77-6 |
|
Decahydronaphthalene, spectro grade, 98% (GC)
| 91-17-8 |
|
4-tert-Butylcalix(6)Arene Hexaacetic Acid Hexaethyl Ester
| 92003-62-8 |
|
Rubicene
| 197-61-5 |
|
4-tert-Butylcalix(4)Arene Tetraacetic Acid
| 113215-72-8 |
|
4-tert-Butylcalix(8)Arene Octaacetic Acid Octaethyl Ester
| 92003-63-9 |
|
N-[3-(Acetylthio)-(2S)-Methyl-1-Oxopropyl]-L-Proline Hydrate, 97%
| 64838-55-7 |
|
(1S,2S)-2-Amino-1-(4-Nitrophenyl)Propane-1,3-Diol, 96%
| 2964-48-9 |
|
2-Bromo-5-nitroaniline, 98%
| 10403-47-1 |
|
2-Hydroxyethyl stearate, 95%
| 111-60-4 |
|
4-Isopropylbenzaldehyde, 98%
| 122-03-2 |
|
Citric acid, trilithium salt tetrahydrate, 98%
| 919-16-4 |
|
D(+)-Glucose, reagent ACS, anhydrous
| 50-99-7 |
|
Di-n-Butylamine, p.a.
| 111-92-2 |
|
(Carbomethoxymethyl)triphenylphosphonium chloride, 97%
| 2181-97-7 |
|
Talc
| 14807-96-6 |
|
Ammonium Oxalate, Monohydrate, Reagent ACS (Crystals)
| 1113-38-8 |
|
(2-Hydroxyethyl)triphenylphosphonium bromide, 98%
| 7237-34-5 |
|
3-Endo-Aminobicyclo??2.2.1??Hept-5-ene-2- Endo-Carboxylic Acid, 98%
| 88330-29-4 |
|
Dibutyl phthalate
| 84-74-2 |
|
Dimethyl Allylphosphonate, 97%
| 757-54-0 |
|
Diethanolamine, 99%
| 111-42-2 |
|
Diethyl Phthalate,99%
| 84-66-2 |
|
3,5-Dibenzyloxybenzyl Alcohol
| 24131-31-5 |
|
|