**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-92-2 |Di-(N-Butyl)amine | 100 | 203-921-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if
swallowed.Corrosive.
Potential Health Effects
Eye:
May cause 'blue haze' or 'halo vision'. Lachrymator (substance
which increases the flow of tears). Causes eye irritation and burns.
Skin:
May be absorbed through the skin in harmful amounts. Causes severe
skin irritation and burns.
Ingestion:
Harmful if swallowed. Causes severe digestive tract burns with
abdominal pain, vomiting, and possible death.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub or keep eyes
closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
soap and water for at least 15 minutes while removing contaminated
clothing and shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Vapors can travel to a source of ignition and flash back. Material
will burn in a fire. Wear appropriate protective clothing to prevent
contact with skin and eyes. Wear a self-contained breathing
apparatus (SCBA) to prevent contact with thermal decomposition
products. Vapors may be heavier than air. They can spread along the
ground and collect in low or confined areas. Vapors may form an
explosive mixture with air.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Contact professional fire-fighters
immediately.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not get in
eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Do not ingest or inhale. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat and flame. Store in a tightly closed container.
Store in a cool, dry, well-ventilated area away from incompatible
substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Appearance: clear, colorless
Odor: amine-like odor.
pH: Not available.
Vapor Pressure: 23 mm Hg @ 20 C
Viscosity: 0.9 mPas 20 deg C
Boiling Point: 159 deg C @ 760.00mm Hg
Freezing/Melting Point: -62 deg C
Autoignition Temperature: 260 deg C ( 500.00 deg F)
Flash Point: 39 deg C ( 102.20 deg F)
Explosion Limits, lower: .60 vol %
Explosion Limits, upper: 6.80 vol %
Decomposition Temperature:
Solubility in water: IN WATER: 4.05 G/L (25C)
Specific Gravity/Density: .7670g/cm3
Molecular Formula: C8H19N
Molecular Weight: 129.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, carbon dioxide, acids, acid chlorides,
halogenated compounds, and acid anhydrides
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, amines.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-92-2: HR7780000
LD50/LC50:
CAS# 111-92-2: Oral, mouse: LD50 = 290 mg/kg; Oral, rat: LD50 = 189
mg/kg; Skin, rabbit: LD50 = 1010 uL/kg.
Carcinogenicity:
Di-(N-Butyl)amine -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DI-n-BUTYLAMINE
Hazard Class: 8
UN Number: 2248
Packing Group: II
IMO
Shipping Name: DI-n-BUTYLAMINE
Hazard Class: 8
UN Number: 2248
Packing Group: II
RID/ADR
Shipping Name: DI-n-BUTYLAMINE
Dangerous Goods Code: 8(54B)
UN Number: 2248
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 111-92-2: 1
United Kingdom Occupational Exposure Limits
Canada
CAS# 111-92-2 is listed on Canada's DSL List.
CAS# 111-92-2 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 111-92-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/19/1997 Revision #1 Date: 8/02/2000
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(S)-3-Acetoxy-gamma-butyrolactone, 97%
| 191403-65-3 |
|
3-Chlorosalicylic Acid, 98%
| 1829-32-9 |
|
N-BOC-O-Benzyl-L-Serine, 98%
| 23680-31-1 |
|
N-BOC-O-Benzyl-D-Serine, 98%
| 47173-80-8 |
|
(1R,2R)-2-Amino-1-Phenylpropane-1,3-Diol
| 46032-98-8 |
|
4,5-Dimethoxy-2-Nitrobenzoic Acid, 98%
| 4998-07-6 |
|
(S)-(-)-2-(Carbobenzyloxyamino)-3-Phenyl-1-Propanol, 98%
| 6372-14-1 |
|
Tetracyanoethylene, 98%
| 670-54-2 |
|
2,5-Lutidine, 97%
| 589-93-5 |
|
(S)-1,2,3,4-Tetrahydroisoquinolylmethan-3-ol
| 0-01-1 |
|
Gamma-L-Glutamyl-L-Alanine
| 5875-41-2 |
|
Ethyl (3S)-4-Bromo-3-Hydroxybutanoate, 90%
| 95537-36-3 |
|
Albumin from Eggs
| 9006-50-2 |
|
Cyclohexane, 99+%, Spectrophotometric Grade
| 110-82-7 |
|
Cyclohexanol, 98%
| 108-93-0 |
|
Cyclohexene, 99%
| 110-83-8 |
|
L-Valine Ethyl Ester Hydrochloride, 99%
| 17609-47-1 |
|
D-(-)-Fructose, P.A.
| 57-48-7 |
|
D-(-)-Ribose, 99.5+%
| 50-69-1 |
|
Ethyl (R)-Nipecotate L-Tartarate, 97%
| 167392-57-6 |
|
D-Sorbitol, P.A.
| 50-70-4 |
|
Diethylphosphonoacetic Acid
| 3095-95-2 |
|
N-[(S)-(+)-Ethoxycarbonyl)-3-Phenylpropyl]-L-Alanine, 97%
| 82717-96-2 |
|
D-(+)-Xylose, p.a.
| 58-86-6 |
|
Dansyl Chloride, 98%
| 605-65-2 |
|
Diethyl(4-Nitrobenzyl)Phosphonate
| 0-01-1 |
|
4-tert-Amylcalix(8)Arene
| 93503-77-6 |
|
Decahydronaphthalene, spectro grade, 98% (GC)
| 91-17-8 |
|
4-tert-Butylcalix(6)Arene Hexaacetic Acid Hexaethyl Ester
| 92003-62-8 |
|
Rubicene
| 197-61-5 |
|
4-tert-Butylcalix(4)Arene Tetraacetic Acid
| 113215-72-8 |
|
4-tert-Butylcalix(8)Arene Octaacetic Acid Octaethyl Ester
| 92003-63-9 |
|
N-[3-(Acetylthio)-(2S)-Methyl-1-Oxopropyl]-L-Proline Hydrate, 97%
| 64838-55-7 |
|
(1S,2S)-2-Amino-1-(4-Nitrophenyl)Propane-1,3-Diol, 96%
| 2964-48-9 |
|
2-Bromo-5-nitroaniline, 98%
| 10403-47-1 |
|
2-Hydroxyethyl stearate, 95%
| 111-60-4 |
|
4-Isopropylbenzaldehyde, 98%
| 122-03-2 |
|
Citric acid, trilithium salt tetrahydrate, 98%
| 919-16-4 |
|
D(+)-Glucose, reagent ACS, anhydrous
| 50-99-7 |
|
Di-n-Butylamine, p.a.
| 111-92-2 |
|
(Carbomethoxymethyl)triphenylphosphonium chloride, 97%
| 2181-97-7 |
|
Talc
| 14807-96-6 |
|
Ammonium Oxalate, Monohydrate, Reagent ACS (Crystals)
| 1113-38-8 |
|
(2-Hydroxyethyl)triphenylphosphonium bromide, 98%
| 7237-34-5 |
|
3-Endo-Aminobicyclo??2.2.1??Hept-5-ene-2- Endo-Carboxylic Acid, 98%
| 88330-29-4 |
|
Dibutyl phthalate
| 84-74-2 |
|
Dimethyl Allylphosphonate, 97%
| 757-54-0 |
|
Diethanolamine, 99%
| 111-42-2 |
|
Diethyl Phthalate,99%
| 84-66-2 |
|
3,5-Dibenzyloxybenzyl Alcohol
| 24131-31-5 |
|
|