**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 84-74-2 |Dibutyl phthalate | 99 | 201-557-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 50 61 62
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic to aquatic organisms. May cause harm to the unborn child.
Possible risk of impaired fertility.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. A single prolonged skin exposure is not
likely to result in the material being absorbed in harmful amounts.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Inhalation of a mist of this material may cause respiratory tract
irritation. Material has a low vapor pressure, so exposure to vapor
is not likely. May cause central nervous system effects.
Chronic:
May cause adverse reproductive effects. Possible risk of harm to the
unborn child.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid breathing
vapors from heated material. Avoid contact with eyes, skin, and
clothing. Avoid breathing spray or mist.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 84-74-2:
United Kingdom, WEL - TWA: 5 mg/m3 TWA
United Kingdom, WEL - STEL: 10 mg/m3 STEL
United States OSHA: 5 mg/m3 TWA
Belgium - TWA: 5 mg/m3 VLE
France - VME: 5 mg/m3 VME
Japan: 5 mg/m3 OEL
Malaysia: 1 ppm TWA; 8.6 mg/m3 TWA
Russia: 0.5 mg/m3 TWA
Spain: 5 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to light yellow
Odor: odorless
pH: Not available.
Vapor Pressure: 0.00007 mm Hg @ 25 deg C
Viscosity: 21 cps @ 20 deg C
Boiling Point: 340 deg C
Freezing/Melting Point: -35 deg C
Autoignition Temperature: 402 deg C ( 755.60 deg F)
Flash Point: 157 deg C ( 314.60 deg F)
Explosion Limits, lower: 0.5% @ 235C
Explosion Limits, upper: 2.5%
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: 1.043
Molecular Formula: C16H22O4
Molecular Weight: 278.34
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 84-74-2: TI0875000
LD50/LC50:
CAS# 84-74-2: Inhalation, mouse: LC50 = 25 gm/m3/2H; Inhalation,
rat: LC50 = 4250 mg/m3; Oral, mouse: LD50 = 3474 mg/kg; Oral, rat:
LD50 = 7499 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
Carcinogenicity:
Dibutyl phthalate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Bluegill/Sunfish: 1.2mg/L; 96HFish: Fathead Minnow: 1.3mg/L;
96H
Other
Dangerous to aquatic life in high concentrations.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 84-74-2: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 61 May cause harm to the unborn child.
R 50 Very toxic to aquatic organisms.
R 62 Possible risk of impaired fertility.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 84-74-2: 2
Canada
CAS# 84-74-2 is listed on Canada's DSL List.
CAS# 84-74-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 84-74-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/26/1999 Revision #7 Date: 4/22/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(S)-3-Acetoxy-gamma-butyrolactone, 97%
| 191403-65-3 |
|
3-Chlorosalicylic Acid, 98%
| 1829-32-9 |
|
N-BOC-O-Benzyl-L-Serine, 98%
| 23680-31-1 |
|
N-BOC-O-Benzyl-D-Serine, 98%
| 47173-80-8 |
|
(1R,2R)-2-Amino-1-Phenylpropane-1,3-Diol
| 46032-98-8 |
|
4,5-Dimethoxy-2-Nitrobenzoic Acid, 98%
| 4998-07-6 |
|
(S)-(-)-2-(Carbobenzyloxyamino)-3-Phenyl-1-Propanol, 98%
| 6372-14-1 |
|
Tetracyanoethylene, 98%
| 670-54-2 |
|
2,5-Lutidine, 97%
| 589-93-5 |
|
(S)-1,2,3,4-Tetrahydroisoquinolylmethan-3-ol
| 0-01-1 |
|
Gamma-L-Glutamyl-L-Alanine
| 5875-41-2 |
|
Ethyl (3S)-4-Bromo-3-Hydroxybutanoate, 90%
| 95537-36-3 |
|
Albumin from Eggs
| 9006-50-2 |
|
Cyclohexane, 99+%, Spectrophotometric Grade
| 110-82-7 |
|
Cyclohexanol, 98%
| 108-93-0 |
|
Cyclohexene, 99%
| 110-83-8 |
|
L-Valine Ethyl Ester Hydrochloride, 99%
| 17609-47-1 |
|
D-(-)-Fructose, P.A.
| 57-48-7 |
|
D-(-)-Ribose, 99.5+%
| 50-69-1 |
|
Ethyl (R)-Nipecotate L-Tartarate, 97%
| 167392-57-6 |
|
D-Sorbitol, P.A.
| 50-70-4 |
|
Diethylphosphonoacetic Acid
| 3095-95-2 |
|
N-[(S)-(+)-Ethoxycarbonyl)-3-Phenylpropyl]-L-Alanine, 97%
| 82717-96-2 |
|
D-(+)-Xylose, p.a.
| 58-86-6 |
|
Dansyl Chloride, 98%
| 605-65-2 |
|
Diethyl(4-Nitrobenzyl)Phosphonate
| 0-01-1 |
|
4-tert-Amylcalix(8)Arene
| 93503-77-6 |
|
Decahydronaphthalene, spectro grade, 98% (GC)
| 91-17-8 |
|
4-tert-Butylcalix(6)Arene Hexaacetic Acid Hexaethyl Ester
| 92003-62-8 |
|
Rubicene
| 197-61-5 |
|
4-tert-Butylcalix(4)Arene Tetraacetic Acid
| 113215-72-8 |
|
4-tert-Butylcalix(8)Arene Octaacetic Acid Octaethyl Ester
| 92003-63-9 |
|
N-[3-(Acetylthio)-(2S)-Methyl-1-Oxopropyl]-L-Proline Hydrate, 97%
| 64838-55-7 |
|
(1S,2S)-2-Amino-1-(4-Nitrophenyl)Propane-1,3-Diol, 96%
| 2964-48-9 |
|
2-Bromo-5-nitroaniline, 98%
| 10403-47-1 |
|
2-Hydroxyethyl stearate, 95%
| 111-60-4 |
|
4-Isopropylbenzaldehyde, 98%
| 122-03-2 |
|
Citric acid, trilithium salt tetrahydrate, 98%
| 919-16-4 |
|
D(+)-Glucose, reagent ACS, anhydrous
| 50-99-7 |
|
Di-n-Butylamine, p.a.
| 111-92-2 |
|
(Carbomethoxymethyl)triphenylphosphonium chloride, 97%
| 2181-97-7 |
|
Talc
| 14807-96-6 |
|
Ammonium Oxalate, Monohydrate, Reagent ACS (Crystals)
| 1113-38-8 |
|
(2-Hydroxyethyl)triphenylphosphonium bromide, 98%
| 7237-34-5 |
|
3-Endo-Aminobicyclo??2.2.1??Hept-5-ene-2- Endo-Carboxylic Acid, 98%
| 88330-29-4 |
|
Dibutyl phthalate
| 84-74-2 |
|
Dimethyl Allylphosphonate, 97%
| 757-54-0 |
|
Diethanolamine, 99%
| 111-42-2 |
|
Diethyl Phthalate,99%
| 84-66-2 |
|
3,5-Dibenzyloxybenzyl Alcohol
| 24131-31-5 |
|
|