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MSDS 
:
 1-Octanol, 99+%
CAS 
:
 111-87-5
SYNONYMS 
:
 Capryl alcohol; n-Octanol; n-Octyl alcohol; n-Caprylic alcohol; Octyl     alcohol.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-87-5 |1-Octanol | 99.0+ | 203-917-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Irritating to eyes.

Potential Health Effects
Eye:
May cause eye irritation. Vapors may cause eye irritation. May
cause transient corneal injury.
Skin:
May cause mild skin irritation. May be absorbed through the skin.
Prolonged or repeated contact may dry/defat the skin and cause
irritation.
Ingestion:
May cause digestive tract disturbances. Possible aspiration hazard.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Combustible liquid and vapor. Vapors are heavier
than air and may travel to a source of ignition and flash back.
Vapors can spread along the ground and collect in low or confined
areas. This liquid floats on water and may travel to a source of
ignition and spread fire.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames. Use only with adequate ventilation.
Keep away from heat and flame. Avoid breathing vapor or mist.
Storage:
Keep away from heat and flame. Store in a tightly closed container.
Store in a cool, dry, well-ventilated area away from incompatible
substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment

Eyes:
Wear chemical goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid
Color: clear, colorless
Odor: penetrating odor - sweetish odor
pH: Not available.
Vapor Pressure: 0.08 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 195 deg C
Freezing/Melting Point: -16 deg C
Autoignition Temperature: 523 deg F ( 272.78 deg C)
Flash Point: 178 deg F ( 81.11 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: 0.8240
Molecular Formula: C8H18O
Molecular Weight: 130.23

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Acids, acid chlorides, oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 111-87-5: RH6550000
LD50/LC50:
CAS# 111-87-5: Dermal, guinea pig: LD50 = >1 gm/kg; Draize test,
rabbit, skin: 500 mg/24H Mild; Oral, mouse: LD50 = 1790 mg/kg; Oral,
mouse: LD50 = 15000 mg/kg; Oral, rat: LD50 = >3200 mg/kg; Oral, rat:
LD50 = 20000 mg/kg.
Carcinogenicity:
1-Octanol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
Fish: Fathead Minnow: LC50 = 13.5 mg/L; 96 Hr.; Flow-through
ConditionFish: Rainbow trout: LC50 = 18.0 mg/L; 96 Hr.;
UnspecifiedWater flea Daphnia: EC50 = 23.0 mg/L; 96 Hr.;
UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 = 3.7-7.3 mg/L;
30 minutes; Microtox test
Other
If spilled into U.S. waters, it may be reportable under 33 CFR Part
153 if it produces a sheen.

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36 Irritating to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 39 Wear eye/face protection.
WGK (Water Danger/Protection)
CAS# 111-87-5: 1
United Kingdom Occupational Exposure Limits

United Kingdom Maximum Exposure Limits

Canada
CAS# 111-87-5 is listed on Canada's DSL List.
CAS# 111-87-5 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 111-87-5: OEL-RUSSIA:STEL 10 mg/m3
US FEDERAL
TSCA
CAS# 111-87-5 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 6/08/1999 Revision #4 Date: 10/05/2004

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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