**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 12125-02-9 |Ammonium chloride | >99.0 | 235-186-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes.Hygroscopic (absorbs
moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin.
Ingestion:
May cause irritation of the digestive tract. May cause systemic
toxicity with acidosis. May be harmful if swallowed.
Inhalation:
If heated, dust or fume may cause respiratory tract irritation. May
be harmful if inhaled.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Substance is
noncombustible. Containers may explode in the heat of a fire. May
polymerize explosively when involved in a fire.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. Cool containers with flooding quantities
of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Store protected from moisture. Store below 40C.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 12125-02-9:
United Kingdom, WEL - TWA: 10 mg/m3 TWA (fume)
United Kingdom, WEL - STEL: 20 mg/m3 STEL (fume)
Belgium - TWA: 10 mg/m3 VLE (fumes)
Belgium - STEL: 20 mg/m3 VLE (fumes)
France - VME: 10 mg/m3 VME (fume)
Malaysia: 10 mg/m3 TWA (fume)
Netherlands: 10 mg/m3 MAC (smoke)
Russia: 10 mg/m3 TWA (fumes)
Spain: 10 mg/m3 VLA-ED (fume)
Spain: 20 mg/m3 VLA-EC (fume)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear impervious gloves.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: colorless or white
Odor: odorless
pH: 5.0 (10% sol at 25C)
Vapor Pressure: 1 mm Hg @ 160.4C
Viscosity: Not available.
Boiling Point: 520 deg C(sublimes)
Freezing/Melting Point: 328 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 39.6% at 176F.
Specific Gravity/Density: 1.53 (Water=1)
Molecular Formula: NH4Cl
Molecular Weight: 53.4877
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Hygroscopic: absorbs moisture or water from
the air. Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid:
Excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Acids, bases, bromine trifluoride, nitrates, potassium chlorates,
silver salts, carbonates, bromine pentafluoride, lead salts.
Hazardous Decomposition Products:
Ammonia and hydrochloric acid fumes.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 12125-02-9: BP4550000 BP4570000
LD50/LC50:
CAS# 12125-02-9: Draize test, rabbit, eye: 500 mg/24H Mild; Draize
test, rabbit, eye: 100 mg Severe; Oral, mouse: LD50 = 1300 mg/kg;
Oral, rat: LD50 = 1650 mg/kg.
Carcinogenicity:
Ammonium chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: LC50 = 109.0 mg/L; 48 Hr.; Static conditionsSunfish (fresh
water) TLm=6 ppm/96H
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 12125-02-9: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36 Irritating to eyes.
Safety Phrases:
S 22 Do not breathe dust.
WGK (Water Danger/Protection)
CAS# 12125-02-9: 1
Canada
CAS# 12125-02-9 is listed on Canada's DSL List.
CAS# 12125-02-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 12125-02-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/15/1999 Revision #4 Date: 11/25/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
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| ALL MSDS PAGES IN THIS GROUP
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Tautomycin
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Oleic acid
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Ammonium Bromide
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Orcinol Monohydrate, 99%
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Rotenone, 97%
| 83-79-4 |
|
Osmium tetroxide, 2.5 wt% sol. in tert- butanol,stab. with
| 20816-12-0 |
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| 144-62-7 |
|
n-Acetylprocainamide hydrochloride, 99%
| 34118-92-8 |
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Taurocholic Acid, Sodium Salt Hydrate, 97% (TLC)
| 145-42-6 |
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3,5-Diphenylpyrazole
| 1145-01-3 |
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1,4-Dichlorobenzene, 97%
| 106-46-7 |
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4-Nitrophenol
| 100-02-7 |
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4-Nitro-m-xylene, 99%
| 89-87-2 |
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(R)-(+)-(3,4-Dimethoxy)benzyl-1-phenylethylamine, 98%
| 134430-93-6 |
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Palladium(II) chloride
| 7647-10-1 |
|
(S)-(-)-(3,4-Dimethoxy)-benzyl-1-phenylethylamine, 98%
| 0-00-0 |
|
tert-Butyl (3R)-3-amino-3-phenylpropanoate, 97%
| 161671-34-7 |
|
Paraformaldehyde, 96%
| 30525-89-4 |
|
tert-Butyl (3S)-3-amino-3-phenylpropanoate, 97%
| 120686-18-2 |
|
tert-Butyl (3S)-3-Amino-4-Phenylbutanoate, 97%
| 120686-17-1 |
|
tert-Butyl (3R)-3-Amino-4-Phenylbutanoate, 97%
| 166023-31-0 |
|
Ammonium Carbonate
| 506-87-6 |
|
tert-Butyl (3R)-3-Amino-5-Methylhexanoate, 97%
| 166023-29-6 |
|
tert-Butyl (3S)-3-Amino-5-Methylhexanoate, 97%
| 166023-30-9 |
|
tert-Butyl (3S)-3-Aminobutanoate, 95%
| 161105-54-0 |
|
Tert-Butyl (3R)-3-Aminobutanoate
| 158849-23-1 |
|
Pentane, 98%
| 109-66-0 |
|
Pepsin (powder)
| 9001-75-6 |
|
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| 7601-90-3 |
|
tert-Butyl (3R)-3-Amino-4-Hexenoate, 97%
| 204587-89-3 |
|
Periodic Acid , 99+%
| 10450-60-9 |
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Ammonium Chloride
| 12125-02-9 |
|
tert-Butyl (3S)-3-Amino-4-Hexenoate, 97%
| 204587-90-6 |
|
|