**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 612-82-8 |o-Tolidine dihydrochloride | 99 | 210-322-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 22 45 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. May cause cancer. Toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause eye burns.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Avoid generating dusty conditions. Carefully scoop
up and place into appropriate disposal container. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Do not store in direct sunlight. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 612-82-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: off-white to buff
Odor: None reported.
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 300 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C14H16N2.2HCl
Molecular Weight: 285.20
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. However, may decompose if heated.
Conditions to Avoid:
Dust generation, temperatures above 150C.
Incompatibilities with Other Materials:
Strong oxidizers.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 612-82-8: DD1226000
LD50/LC50:
Not available.
Carcinogenicity:
o-Tolidine dihydrochloride -
California: carcinogen, initial date 4/1/92
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 45 May cause cancer.
R 22 Harmful if swallowed.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 612-82-8: No information available.
Canada
CAS# 612-82-8 is listed on Canada's DSL List.
CAS# 612-82-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 612-82-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/26/1998 Revision #4 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(S)-Di-2-naphthylprolinol, 99%
| 0-01-1 |
|
(R)-Di-2-naphthylprolinol, 99%
| 130798-48-0 |
|
(4S)-N-(tert-Butyldimethylsilyl)azetidin-2-one-4-carboxylic acid, 99%
| 82938-50-9 |
|
Rolipram
| 61413-54-5 |
|
Rottlerin
| 82-08-6 |
|
Ryanodine
| 15662-33-6 |
|
Nitric Acid ,C.P., 63%
| 7697-37-2 |
|
Saxitoxin
| 35523-89-8 |
|
Nitromethane, 96%, spectrophotometric grade
| 75-52-5 |
|
Sphingosine 1-phosphate (high purity)
| 26993-30-6 |
|
Sodium nitroferricyanide dihydrate, p.a.
| 13755-38-9 |
|
Staurosporine
| 62996-74-1 |
|
1,2-Dichlorobenzene, 99+%, Spectrophotometric Grade
| 95-50-1 |
|
Suramin.hexasodium salt
| 129-46-4 |
|
o-Tolidine dihydrochloride, 99%
| 612-82-8 |
|
1-Octanol, 99+%
| 111-87-5 |
|
Tautomycin
| 109946-35-2 |
|
Oleic acid
| 112-80-1 |
|
Tetrodotoxin
| 4368-28-9 |
|
Ammonium Bromide
| 12124-97-9 |
|
Orcinol Monohydrate, 99%
| 6153-39-5 |
|
Rotenone, 97%
| 83-79-4 |
|
Osmium tetroxide, 2.5 wt% sol. in tert- butanol,stab. with
| 20816-12-0 |
|
Oxalic acid, dihydrate, reagent ACS
| 144-62-7 |
|
n-Acetylprocainamide hydrochloride, 99%
| 34118-92-8 |
|
Taurocholic Acid, Sodium Salt Hydrate, 97% (TLC)
| 145-42-6 |
|
3,5-Diphenylpyrazole
| 1145-01-3 |
|
1,4-Dichlorobenzene, 97%
| 106-46-7 |
|
4-Nitrophenol
| 100-02-7 |
|
4-Nitro-m-xylene, 99%
| 89-87-2 |
|
(R)-(+)-(3,4-Dimethoxy)benzyl-1-phenylethylamine, 98%
| 134430-93-6 |
|
Palladium(II) chloride
| 7647-10-1 |
|
(S)-(-)-(3,4-Dimethoxy)-benzyl-1-phenylethylamine, 98%
| 0-00-0 |
|
tert-Butyl (3R)-3-amino-3-phenylpropanoate, 97%
| 161671-34-7 |
|
Paraformaldehyde, 96%
| 30525-89-4 |
|
tert-Butyl (3S)-3-amino-3-phenylpropanoate, 97%
| 120686-18-2 |
|
tert-Butyl (3S)-3-Amino-4-Phenylbutanoate, 97%
| 120686-17-1 |
|
tert-Butyl (3R)-3-Amino-4-Phenylbutanoate, 97%
| 166023-31-0 |
|
Ammonium Carbonate
| 506-87-6 |
|
tert-Butyl (3R)-3-Amino-5-Methylhexanoate, 97%
| 166023-29-6 |
|
tert-Butyl (3S)-3-Amino-5-Methylhexanoate, 97%
| 166023-30-9 |
|
tert-Butyl (3S)-3-Aminobutanoate, 95%
| 161105-54-0 |
|
Tert-Butyl (3R)-3-Aminobutanoate
| 158849-23-1 |
|
Pentane, 98%
| 109-66-0 |
|
Pepsin (powder)
| 9001-75-6 |
|
Perchloric acid, reagent ACS, 70% in water
| 7601-90-3 |
|
tert-Butyl (3R)-3-Amino-4-Hexenoate, 97%
| 204587-89-3 |
|
Periodic Acid , 99+%
| 10450-60-9 |
|
Ammonium Chloride
| 12125-02-9 |
|
tert-Butyl (3S)-3-Amino-4-Hexenoate, 97%
| 204587-90-6 |
|
|