**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 112-55-0 |1-Dodecanethiol | 98.0 | 203-984-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause dermatitis. May cause reddening of
the skin. Chronic exposure may result in sensitization.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Repeated exposure may cause sensitization dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide, or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to light yellow
Odor: skunk-like
pH: Not available.
Vapor Pressure: 154 mm Hg @20C
Viscosity: Not available.
Boiling Point: 266 - 283 deg C @ 760.00mm Hg
Freezing/Melting Point: -7 deg C
Autoignition Temperature: 230 deg C ( 446.00 deg F)
Flash Point: 99 deg C ( 210.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 350 deg C
Solubility in water: Insoluble.
Specific Gravity/Density: .8450g/cm3
Molecular Formula: C12H26S
Molecular Weight: 202.40
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, alkali metals.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 112-55-0: JR3155000
LD50/LC50:
Not available.
Carcinogenicity:
1-Dodecanethiol -
Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 112-55-0: No information available.
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 112-55-0 is listed on Canada's DSL List.
CAS# 112-55-0 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 112-55-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
L-Ascorbic acid
| 50-81-7 |
|
L-Asparagine Monohydrate
| 5794-13-8 |
|
L-Tryptophan
| 73-22-3 |
|
L-Tyrosine
| 60-18-4 |
|
L-Methionine
| 63-68-3 |
|
Methyl 5-oxazolecarboxylate, 96%
| 121432-12-0 |
|
L-Histidine
| 71-00-1 |
|
L-Histidine Hydrochloride Monohydrate
| 5934-29-2 |
|
Cycloheptatriene, 90%
| 544-25-2 |
|
2-Iodobenzyl alcohol, 99%
| 5159-41-1 |
|
5-Chlorovaleryl Chloride, 96%
| 1575-61-7 |
|
2-Nitro-p-phenylenediamine, 95-99%
| 5307-14-2 |
|
1,4-Dioxaspiro[4.5]decan-8-ol, 98+%
| 22428-87-1 |
|
Pyrazino[2,3-f]Quinoxaline, 99+%
| 231-23-2 |
|
Lanthanum chloride heptahydrate
| 10025-84-0 |
|
Lanthanum Oxide
| 1312-81-8 |
|
Lanthanum Nitrate Hexahydrate
| 10099-59-9 |
|
2,3-Pentanedione, 97%
| 600-14-6 |
|
Lauric Acid
| 143-07-7 |
|
Alpha-NPO, Scintillation Grade
| 846-63-9 |
|
4-Benzylpiperidine, 98%
| 31252-42-3 |
|
2-(2-Quinoxalinyl)malondialdehyde
| 0-00-0 |
|
4-Nitro-Benzylthiocyanate, 99%
| 13287-49-5 |
|
Methyl vinyl ketone
| 78-94-4 |
|
Lead
| 7439-92-1 |
|
2-Methoxy-5-nitroaniline, 99%
| 99-59-2 |
|
Methyltriphenylphosphonium iodide, 97%
| 2065-66-9 |
|
Lead(II) acetate trihydrate
| 301-04-2 |
|
4-Ethylbiphenyl-4'-carboxylic acid, 98%
| 5731-13-5 |
|
Mono-(Trimethylsilyl)Phosphite
| 91076-68-5 |
|
N-Acetylanthranilic acid, 99%
| 89-52-1 |
|
1,2,2,6,6-Pentamethylpiperidine, 95% (GC)
| 79-55-0 |
|
Dihydrogentrifluoride Polymer-Supported, ca 7 mMol HF/g of Amberlyst
| 12260-12-7 |
|
Lead (II) Chloride
| 7758-95-4 |
|
Triisopropanolamine borate, 98+%
| 101-00-8 |
|
(S)-3-tert.-Butyl-2,5-piperazinedione
| 65016-62-8 |
|
2-Methoxynaphthalene, 98%
| 93-04-9 |
|
Lead chromate
| 7758-97-6 |
|
1-(2'-Thienyl)Ethylmercaptan, 98%
| 94089-02-8 |
|
4-Bromobenzotrifluoride, 99%
| 402-43-7 |
|
Lead Dioxide
| 1309-60-0 |
|
N-Hydroxymaleimide, 97%
| 4814-74-8 |
|
1-Dodecanethiol, 98.5+% (gc)
| 112-55-0 |
|
2,4,6-Trimethylaniline, 97%
| 88-05-1 |
|
Iodobenzene diacetate, 98%
| 3240-34-4 |
|
Trans 2, cis 6-nonadienol, 94%
| 28069-72-9 |
|
1,5-Dihydroxy-1,2,3,4-Tetrahydro-Naphthalene, Tech.
| 40771-26-4 |
|
Acrolein dimethyl acetal, 99%
| 6044-68-4 |
|
Lead(II) nitrate
| 10099-74-8 |
|
Lead Oxide Yellow
| 1317-36-8 |
|
|