**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 12109-71-6 |Bis(methylcyclopentadienyl)zirconium d| 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.The toxicological properties of this material have not
been fully investigated.Corrosive.Moisture sensitive.Air sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. May
cause burns to the digestive tract.
Inhalation:
May cause severe irritation of the respiratory tract with possible
burns.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water
inside containers. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation. Place under an inert
atmosphere. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Keep container tightly closed. Do not get on skin or in
eyes. Do not ingest or inhale. Use with adequate ventilation. Handle
under an inert atmosphere. Store protected from air. Do not allow
contact with water. Discard contaminated shoes. Keep from contact
with moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Do not expose
to air. Store protected from moisture. Store under an inert
atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 12109-71-6:
United Kingdom, WEL - TWA: (listed as zirconium compounds, n.o.s.
mg/m3 TWA (as Zr)
United Kingdom, WEL - STEL: (listed as zirconium compounds, n.o.s
10 mg/m3 STEL (as Zr)
United States OSHA: 5 mg/m3 TWA (as Zr) (listed under Zirconium
compounds, n.o.s.).
Belgium - TWA: (listed as zirconium compounds, n.o.s.): 5 mg/m3 V
(as Zr)
Belgium - STEL: (listed as zirconium compounds, n.o.s.): 10 mg/m3
(as Zr)
Malaysia: (listed as zirconium compounds, n.o.s.): 5 mg/m3 TWA (a
Zr)
Netherlands: (listed as zirconium compounds, n.o.s.): 5 mg/m3 MAC
Zr)
Spain: (listed as zirconium compounds, n.o.s.): 5 mg/m3 VLA-ED (a
Zr)
Spain: (listed as zirconium compounds, n.o.s.): 10 mg/m3 VLA-EC (
Zr)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 180.5-184 C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in toluene
Specific Gravity/Density:
Molecular Formula: C12H14Cl2Zr
Molecular Weight: 320.35
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Air sensitive. Moisture sensitive.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, exposure to air,
metals.
Incompatibilities with Other Materials:
Acids, bases, strong oxidizing agents, chemically active metals, air,
moisture.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 12109-71-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Bis(methylcyclopentadienyl)zirconium dichloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 12109-71-6: No information available.
Canada
CAS# 12109-71-6 is listed on Canada's NDSL List.
CAS# 12109-71-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 12109-71-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/18/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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2-Methoxyphenyl isothiocyanate
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| 12109-71-6 |
|
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| 134535-29-8 |
|
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| 60940-34-3 |
|
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| 67648-61-7 |
|
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| 1099-45-2 |
|
4,4'(5')-Diaminodibenzo-15-crown-5 dihydrochloride, 97%
| |
|
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| 4263-52-9 |
|
L-Serine, 99%
| 56-45-1 |
|
L-(-)-Proline, 99+%
| 147-85-3 |
|
Poly(4-vinylpyridine), linear(average m.w. 20,000)
| 25232-41-1 |
|
Poly(vinylpyridine),linear (average m.w. 200,000)
| 25232-41-1 |
|
Poly(2-vinylpyridine), linear, m.w. 40,000
| 25014-15-7 |
|
p-Cresol, p.a.
| 106-44-5 |
|
p-Cresol, 99+%
| 106-44-5 |
|
m-Cresol, 97%
| 108-39-4 |
|
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| 95-48-7 |
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| 95-48-7 |
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| 404-24-0 |
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| 155323-17-4 |
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| 14444-77-0 |
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