**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 72976-70-6 |Trilithiumheptaphosphide, Dimethoxyeth| ca 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 15/29 17
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with water liberates toxic, extremely flammable gas.
Spontaneously flammable in air.Moisture sensitive.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Evacuate area and fight fire from a safe distance. As in any fire,
wear a self-contained breathing apparatus in pressure-demand,
MSHA/NIOSH (approved or equivalent), and full protective gear. May
burn with invisible flame. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Spontaneously ignitable in air.
Extinguishing Media:
Use dry sand or earth to smother fire. If water is the only media
available, use in flooding amounts. Use agent most appropriate to
extinguish fire. Do NOT get water inside containers. Contact
professional fire-fighters immediately.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Isolate area and
deny entry. Provide ventilation. Place under an inert atmosphere. Do
not get water inside containers. Do not use combustible materials
such as paper towels to clean up spill.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Use with
adequate ventilation. Minimize dust generation and accumulation. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation. Handle under an inert atmosphere. Do not
allow contact with water. Keep from contact with moist air and
steam.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area. Do not expose to air.
Store protected from moisture. Store under an inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
CAS# 72976-70-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: yellow to orange
Odor: stench
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in thf, dme
Specific Gravity/Density:
Molecular Formula: Li3P7.3Dme
Molecular Weight: 507.96
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Powder or liquid is pyrophoric.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, moisture,
exposure to air, strong oxidants.
Incompatibilities with Other Materials:
Moisture.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 72976-70-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Trilithiumheptaphosphide, Dimethoxyethane Complex -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PYROPHORIC ORGANOMETALLIC COMPOUND, N.O.S.*
Hazard Class: 4.2
UN Number: 3203
Packing Group:
IMO
Shipping Name: PYROPHORIC ORGANOMETALLIC COMPOUND, N.O.S.
Hazard Class: 4.2
UN Number: 3203
Packing Group: I
RID/ADR
Shipping Name: PYROPHORIC ORGANOMETALLIC COMPOUND, N.O.S.
Hazard Class: 4.2
UN Number: 3203
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 15/29 Contact with water liberates toxic,
extremely flammable gas.
R 17 Spontaneously flammable in air.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 72976-70-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 72976-70-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 72976-70-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/05/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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|
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|
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| 0-01-1 |
|
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| 12109-71-6 |
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| 60940-34-3 |
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| 1099-45-2 |
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| |
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|
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| 56-45-1 |
|
L-(-)-Proline, 99+%
| 147-85-3 |
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| 25232-41-1 |
|
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| 25232-41-1 |
|
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| 25014-15-7 |
|
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| 106-44-5 |
|
p-Cresol, 99+%
| 106-44-5 |
|
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| 108-39-4 |
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| 95-48-7 |
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| 95-48-7 |
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