**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| |Ethylene Glycol-D4 | 99 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause moderate eye irritation.
Skin:
May cause skin irritation. Low hazard for usual industrial handling.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation. Heated or misted substance
may cause headache, irregular eye movements, and possible coma.
Chronic:
May cause kidney injury.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Ethanol may inhibit methanol metabolism.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Water or foam may cause frothing.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Avoid contact with skin and eyes. Keep
container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# :
United Kingdom, WEL - TWA: (listed as tellurium): 0.1 mg/m3 TWA
United Kingdom, WEL - STEL: (listed as tellurium): 0.3 mg/m3 STEL
United States OSHA: 0.1 mg/m3 TWA (listed under Tellurium).
Belgium - TWA: (listed as tellurium): 0.1 mg/m3 VLE
France - VME: (listed as tellurium): 0.1 mg/m3 VME
Germany: (listed as tellurium): 0.1 mg/m3 VME
Malaysia: (listed as tellurium): 0.1 mg/m3 TWA
Netherlands: (listed as tellurium): 0.1 mg/m3 MAC
Russia: (listed as tellurium): 0.01 mg/m3 TWA
Spain: (listed as tellurium): 0.1 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: odorless
pH: Not available.
Vapor Pressure: .05 mm Hg @ 20C
Viscosity: mPas 20 deg C
Boiling Point: 86-87 deg C @ 8mm Hg
Freezing/Melting Point: -13 deg C
Autoignition Temperature: 410 deg C ( 770.00 deg F)
Flash Point: 111 deg C ( 231.80 deg F)
Explosion Limits, lower: 3.20 vol %
Explosion Limits, upper: 15.30 vol %
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density: 1.1890g/cm3
Molecular Formula: C2H2D4O2
Molecular Weight: 66.0688
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Sodium hydroxide, sodium peroxide, sulfuric acid, potassium
permanganate, chlorosulfonic acid, oleum, chromium trioxide,
phosphorous pentasulfide, silvered-copper wire, titanium butoxide,
ammonium dichromate, silver chlorate, sodium chloride, uranyl
nitrate.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethylene Glycol-D4 -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Goldfish LD50= >5000mg/L/24Hr Guppies LC50= 493,000ppm/7D Shrimp
(salt water) LC50= >100ppm/48Hr
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 2 Keep out of reach of children.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# : No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/19/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Aluminum, rods (2-7 mm), 99.5%
| 7429-90-5 |
|
2-Methoxyphenyl isothiocyanate
| 3288-04-8 |
|
Potassium Ferrocyanide Trihydrate, Reagent ACS (Crystals)
| 14459-95-1 |
|
Phenylselenyl bromide, 98%
| 34837-55-3 |
|
Triethyl 3-phenylsulfonylorthopropionate
| 38435-09-5 |
|
1,3-Bis(phenylthio)propane, 98% (gc)
| 28118-53-8 |
|
3-Nitrobenzenesulfonyl chloride
| 121-51-7 |
|
1,3-Dimethoxycalix[4]arenecrown-6, 99+% (TLC)
| |
|
Calcium Hypochlorite, Tech., Granular, 65% Available Chlorine
| 7778-54-3 |
|
Biona-compound
| 71868-26-3 |
|
4-Amino-1-Naphthalenesulfonic Acid, 98% (Titr.)
| 84-86-6 |
|
Triethylenetetramine Tetrahydrochloride, 99% (Titr.)
| 4961-40-4 |
|
1,3-Diisopropoxycalix[4]Arenecrown-6
| 0-01-1 |
|
1,3-Dioctyloxycalix[4]arenecrown-6
| 161282-97-9 |
|
Calcium Chloride, Anhydrous, 95%, Irregular Granules
| 10043-52-4 |
|
2,5 Dimethoxycinnamic Acid, 99%
| 10538-51-9 |
|
Allyldibutyltin chloride, 97%
| 64549-05-9 |
|
Aluminum, Powder, 99.99%
| 7429-90-5 |
|
Carbazol-9-yl-Methanol, 98% (HPLC)
| 0-01-1 |
|
Bis(methylcyclopentadienyl)zirconium dichloride
| 12109-71-6 |
|
Phenylphosporodiamidate
| 7450-69-3 |
|
N-Methyl-N-Trimethylsilylmethyl-N'-Tert-Butyl Formamidine
| 80376-66-5 |
|
2-Amino-6-Chlorobenzoic Acid, 99% (HPLC)
| 2148-56-3 |
|
2-Butoxypyridine
| 27361-16-6 |
|
Trilithiumheptaphosphide, Dimethoxyethane Complex
| 72976-70-6 |
|
Tert-Butyldichlorophosphine
| 25979-07-1 |
|
4-Methoxyphenoxyacetic Acid
| 1877-75-4 |
|
Molybdenum Tetrachloride Dimethoxyethane Complex
| 134535-29-8 |
|
Ebselen, 99%
| 60940-34-3 |
|
2-(4-Hydroxyphenoxy)propionic Acid, 98% (HPLC)
| 67648-61-7 |
|
(Carbethoxymethylene)triphenylphosphorane, free of
| 1099-45-2 |
|
4,4'(5')-Diaminodibenzo-15-crown-5 dihydrochloride, 97%
| |
|
2-Bromoethanesulfonic Acid Sodium Salt (Pract.)
| 4263-52-9 |
|
L-Serine, 99%
| 56-45-1 |
|
L-(-)-Proline, 99+%
| 147-85-3 |
|
Poly(4-vinylpyridine), linear(average m.w. 20,000)
| 25232-41-1 |
|
Poly(vinylpyridine),linear (average m.w. 200,000)
| 25232-41-1 |
|
Poly(2-vinylpyridine), linear, m.w. 40,000
| 25014-15-7 |
|
p-Cresol, p.a.
| 106-44-5 |
|
p-Cresol, 99+%
| 106-44-5 |
|
m-Cresol, 97%
| 108-39-4 |
|
o-Cresol, p.a.
| 95-48-7 |
|
o-Cresol, 98%
| 95-48-7 |
|
n-Trifluoroacetylaniline
| 404-24-0 |
|
(+)-Chiracamphox
| 155323-17-4 |
|
Diethyl phenyl orthoformate, 98+%
| 14444-77-0 |
|
N-Decane-D22, 99 Atom % D
| |
|
Bromoethane-D5, 99 Atom % D, Stabilized With Silver
| 3675-63-6 |
|
Ethylene Glycol-D4, 99%D
| |
|
N,N'-Dicyclohexylcarbodiimide, 1M solution in dichloromethane
| 75-09-2 |
|
|