**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 123-90-0 |Thiomorpholine | 98 | 204-660-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Stench.Air sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. Do not use mouth-to-mouth resuscitation if victim
ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with an activated carbon adsorbent and place
into a closed container for disposal. Provide ventilation. Place
under an inert atmosphere.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Keep container tightly closed. Keep away from heat, sparks and
flame. Do not get on skin or in eyes. Do not ingest or inhale. Use
with adequate ventilation. Store protected from air. Use and store
under nitrogen. Use only in a chemical fume hood. Discard
contaminated shoes.
Storage:
Keep container closed when not in use. Corrosives area. Do not
expose to air. Store under nitrogen. Store in a cool, dry area away
from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 123-90-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: stench
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 169 deg C @ 760.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: > 98 deg C (> 208.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: miscible
Specific Gravity/Density: 1.0260g/cm3
Molecular Formula: C4H9NS
Molecular Weight: 103.18
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Air sensitive.
Volatile in steam.
Conditions to Avoid:
Incompatible materials, exposure to air, steam.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, air.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 123-90-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Thiomorpholine -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3267
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3267
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3267
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 123-90-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 123-90-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 123-90-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/14/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Amino-2-Cyclohexen-1-One, 96%
| 5220-49-5 |
|
2-Allylphenol, 99+% (GC)
| 1745-81-9 |
|
Ethyl 3-methyl-3-phenylglycidate, 98% mixture of cis and trans
| 77-83-8 |
|
Ethyl 4-Bromobenzoate, 96% (GC)
| 5798-75-4 |
|
D(+)-Camphor
| 464-49-3 |
|
Copper(i) bromide, 98%
| 7787-70-4 |
|
4-Bromo-2-Fluoroanisole, 99+%
| 2357-52-0 |
|
3-Chloro-4-Hydroxybenzoic Acid Hemihydrate 98%
| 3964-58-7 |
|
1,8-Dichloro-9,10-Bis(Phenylethynyl) Anthracene
| 51749-83-8 |
|
4-Ethylresorcinol, 98%
| 2896-60-8 |
|
Anthraquinone-2,6-disulfonic acid, disodium salt
| 84-50-4 |
|
(2,4,7-Trinitro-9-Fluorenylidene)Malononitrile 98%
| 1172-02-7 |
|
p-Methylstyrene, stabilized, 98%
| 622-97-9 |
|
Coumarin 1, Laser Grade
| 91-44-1 |
|
2-Chloro-4-Fluorocinnamic Acid
| 133220-86-7 |
|
2-Iodo-2-Methylpropane, 95% (GC)
| 558-17-8 |
|
2,6-Dibromo-N-Chloro-P-Benzoquinoneimine, 97% (UV-Vis)
| 537-45-1 |
|
Ethyl crotonate, 98%
| 10544-63-5 |
|
Alpha-Bromo-P-Toluic Acid, 97%
| 6232-88-8 |
|
3-Ethyl-2-Methylbenzothiazolinium P-Toluenesulfonate (Pract), 98%
| 14933-76-7 |
|
Thiomorpholine, 98%
| 123-90-0 |
|
Pyruvic Aldehyde, 40 wt. % Solution in Water
| 78-98-8 |
|
4-Methylcyclohexanone, 98%
| 589-92-4 |
|
1,10-Dibromodecane, 97%
| 4101-68-2 |
|
5-Amino-1,3-dimethylpyrazole hydrochloride 99%
| 3524-32-1 |
|
Maleic Anhydride, 99% (pellets)
| 108-31-6 |
|
Ethyl Salicylate, 99+%
| 118-61-6 |
|
2,6-Dimethyl-3,5-heptanedione, 99%
| 18362-64-6 |
|
o-Chlorocinnamic acid, 99.5%, predominantly trans
| 3752-25-8 |
|
1,3-Dichloro-2-methoxy-5-nitrobenzene, 99%
| 17742-69-7 |
|
Lauroyl chloride, 98%
| 112-16-3 |
|
Boc-D-Alanine, 99+%
| 7764-95-6 |
|
Ethyl 4-Bromobutyrate, 95%
| 2969-81-5 |
|
2',4',5'-TRIHYDROXYBUTYROPHENONE, 98% (UV-VIS)
| 1421-63-2 |
|
Cyclotridecanone, tech.
| 832-10-0 |
|
3-Bromo-5-Chloro-1,2,4-Thiadiazole
| 37159-60-7 |
|
Poly(caprolactone) diol, average m.w.2000
| 36890-68-3 |
|
1-Bromo-2-fluoroethane
| 762-49-2 |
|
N-Phenylbenzylamine, 99% (GC)
| 103-32-2 |
|
4-Isothiocyanato-TEMPO, free radical, 95%
| 36410-81-8 |
|
Thianaphthene, 97%
| 95-15-8 |
|
4'-Isocyanatobenzo-15-Crown-5, 99%
| 83935-62-0 |
|
n-Bromosuccinimide, 99%
| 128-08-5 |
|
3-Acetyl-4,5-dimethyl-5-hydroxy-1,5- dihydro-2h-pyrrol-2-one, 99%
| |
|
3-Fluoroaniline, 98%
| 372-19-0 |
|
1-Amino-3,3-Diethoxypropane, 97%
| 41365-75-7 |
|
2-Nitroanisole
| 91-23-6 |
|
Brilliant cresyl blue-bb (cert)
| 10127-36-3 |
|
(-)-Dimethyl D-Tartrate, 99%
| 13171-64-7 |
|
2-Chloro-5-nitrobenzoic acid, 99+%(gc)
| 2516-96-3 |
|
|