**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 372-19-0 |3-Fluoroaniline | 98 | 206-747-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 33 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Danger of cumulative effects. Irritating to eyes and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Effects may be delayed 2 to 4 hours. Methemoglobinemia is
characterized by dizziness, drowsiness, headache, shortness of
breath, cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood), rapid heart rate and chocolate-brown
colored blood.
Inhalation:
May cause respiratory tract irritation. Aspiration may lead to
pulmonary edema. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Combustible liquid. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep container tightly closed. Keep away from
heat, sparks and flame. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 372-19-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear dark brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 186 deg C @ 756.00 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 77 deg C ( 170.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.1560 g/cm3
Molecular Formula: C6H6FN
Molecular Weight: 111.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Acids, acid anhydrides, acid chlorides, chloroformates.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen fluoride gas, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 372-19-0: BY1400000
LD50/LC50:
Not available.
Carcinogenicity:
3-Fluoroaniline -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLUOROANILINES
Hazard Class: 6.1
UN Number: 2941
Packing Group: III
IMO
Shipping Name: FLUOROANILINES
Hazard Class: 6.1
UN Number: 2941
Packing Group: III
RID/ADR
Shipping Name: FLUOROANILINES
Hazard Class: 6.1
UN Number: 2941
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 33 Danger of cumulative effects.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 372-19-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 372-19-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 372-19-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Amino-2-Cyclohexen-1-One, 96%
| 5220-49-5 |
|
2-Allylphenol, 99+% (GC)
| 1745-81-9 |
|
Ethyl 3-methyl-3-phenylglycidate, 98% mixture of cis and trans
| 77-83-8 |
|
Ethyl 4-Bromobenzoate, 96% (GC)
| 5798-75-4 |
|
D(+)-Camphor
| 464-49-3 |
|
Copper(i) bromide, 98%
| 7787-70-4 |
|
4-Bromo-2-Fluoroanisole, 99+%
| 2357-52-0 |
|
3-Chloro-4-Hydroxybenzoic Acid Hemihydrate 98%
| 3964-58-7 |
|
1,8-Dichloro-9,10-Bis(Phenylethynyl) Anthracene
| 51749-83-8 |
|
4-Ethylresorcinol, 98%
| 2896-60-8 |
|
Anthraquinone-2,6-disulfonic acid, disodium salt
| 84-50-4 |
|
(2,4,7-Trinitro-9-Fluorenylidene)Malononitrile 98%
| 1172-02-7 |
|
p-Methylstyrene, stabilized, 98%
| 622-97-9 |
|
Coumarin 1, Laser Grade
| 91-44-1 |
|
2-Chloro-4-Fluorocinnamic Acid
| 133220-86-7 |
|
2-Iodo-2-Methylpropane, 95% (GC)
| 558-17-8 |
|
2,6-Dibromo-N-Chloro-P-Benzoquinoneimine, 97% (UV-Vis)
| 537-45-1 |
|
Ethyl crotonate, 98%
| 10544-63-5 |
|
Alpha-Bromo-P-Toluic Acid, 97%
| 6232-88-8 |
|
3-Ethyl-2-Methylbenzothiazolinium P-Toluenesulfonate (Pract), 98%
| 14933-76-7 |
|
Thiomorpholine, 98%
| 123-90-0 |
|
Pyruvic Aldehyde, 40 wt. % Solution in Water
| 78-98-8 |
|
4-Methylcyclohexanone, 98%
| 589-92-4 |
|
1,10-Dibromodecane, 97%
| 4101-68-2 |
|
5-Amino-1,3-dimethylpyrazole hydrochloride 99%
| 3524-32-1 |
|
Maleic Anhydride, 99% (pellets)
| 108-31-6 |
|
Ethyl Salicylate, 99+%
| 118-61-6 |
|
2,6-Dimethyl-3,5-heptanedione, 99%
| 18362-64-6 |
|
o-Chlorocinnamic acid, 99.5%, predominantly trans
| 3752-25-8 |
|
1,3-Dichloro-2-methoxy-5-nitrobenzene, 99%
| 17742-69-7 |
|
Lauroyl chloride, 98%
| 112-16-3 |
|
Boc-D-Alanine, 99+%
| 7764-95-6 |
|
Ethyl 4-Bromobutyrate, 95%
| 2969-81-5 |
|
2',4',5'-TRIHYDROXYBUTYROPHENONE, 98% (UV-VIS)
| 1421-63-2 |
|
Cyclotridecanone, tech.
| 832-10-0 |
|
3-Bromo-5-Chloro-1,2,4-Thiadiazole
| 37159-60-7 |
|
Poly(caprolactone) diol, average m.w.2000
| 36890-68-3 |
|
1-Bromo-2-fluoroethane
| 762-49-2 |
|
N-Phenylbenzylamine, 99% (GC)
| 103-32-2 |
|
4-Isothiocyanato-TEMPO, free radical, 95%
| 36410-81-8 |
|
Thianaphthene, 97%
| 95-15-8 |
|
4'-Isocyanatobenzo-15-Crown-5, 99%
| 83935-62-0 |
|
n-Bromosuccinimide, 99%
| 128-08-5 |
|
3-Acetyl-4,5-dimethyl-5-hydroxy-1,5- dihydro-2h-pyrrol-2-one, 99%
| |
|
3-Fluoroaniline, 98%
| 372-19-0 |
|
1-Amino-3,3-Diethoxypropane, 97%
| 41365-75-7 |
|
2-Nitroanisole
| 91-23-6 |
|
Brilliant cresyl blue-bb (cert)
| 10127-36-3 |
|
(-)-Dimethyl D-Tartrate, 99%
| 13171-64-7 |
|
2-Chloro-5-nitrobenzoic acid, 99+%(gc)
| 2516-96-3 |
|
|