**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 762-49-2 |1-Bromo-2-fluoroethane | 99 | 212-100-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+ F N
Risk Phrases: 11 28 36/37/38 59
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Very toxic if swallowed. Irritating to eyes,
respiratory system and skin. Dangerous for the ozone layer.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Prolonged or repeated contact may dry/defat the skin and cause
irritation.
Ingestion:
May be fatal if swallowed.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Patients with fluorohydrocarbon poisoning should not be given
epinephrine or similar drugs because of the tendency of
fluorohydrocarbon to induce cardiac arrhythmia, including
ventricular fibrillation.
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Flammable liquid and
vapor. Vapors are heavier than air and may travel to a source of
ignition and flash back. Vapors can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors. Approach spill
from upwind.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 762-49-2:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: pale yellow
Odor: Typical organohalide odor.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 71 - 72.5 deg C @ 760 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: -1 deg C ( 30.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.7050 g/cm3
Molecular Formula: C2H4BrF
Molecular Weight: 126.96
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, magnesium.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen fluoride gas, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 762-49-2: KH6610000
LD50/LC50:
CAS# 762-49-2: Oral, rat: LD50 = 5 mg/kg; Skin, rabbit: LD50 = >20
mg/kg.
Rat LCLo inhalation; dose: 11 ppm/4H.
Carcinogenicity:
1-Bromo-2-fluoroethane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.*
Hazard Class: 3
UN Number: 1992
Packing Group: I
IMO
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3.2
UN Number: 1992
Packing Group: I
RID/ADR
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3
UN Number: 1992
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ F N
Risk Phrases:
R 11 Highly flammable.
R 28 Very toxic if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 59 Dangerous for the ozone layer.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
S 59 Refer to manufacturer/supplier for information
on recovery/recycling.
WGK (Water Danger/Protection)
CAS# 762-49-2: 3
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 762-49-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 762-49-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/25/1999 Revision #5 Date: 4/16/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Amino-2-Cyclohexen-1-One, 96%
| 5220-49-5 |
|
2-Allylphenol, 99+% (GC)
| 1745-81-9 |
|
Ethyl 3-methyl-3-phenylglycidate, 98% mixture of cis and trans
| 77-83-8 |
|
Ethyl 4-Bromobenzoate, 96% (GC)
| 5798-75-4 |
|
D(+)-Camphor
| 464-49-3 |
|
Copper(i) bromide, 98%
| 7787-70-4 |
|
4-Bromo-2-Fluoroanisole, 99+%
| 2357-52-0 |
|
3-Chloro-4-Hydroxybenzoic Acid Hemihydrate 98%
| 3964-58-7 |
|
1,8-Dichloro-9,10-Bis(Phenylethynyl) Anthracene
| 51749-83-8 |
|
4-Ethylresorcinol, 98%
| 2896-60-8 |
|
Anthraquinone-2,6-disulfonic acid, disodium salt
| 84-50-4 |
|
(2,4,7-Trinitro-9-Fluorenylidene)Malononitrile 98%
| 1172-02-7 |
|
p-Methylstyrene, stabilized, 98%
| 622-97-9 |
|
Coumarin 1, Laser Grade
| 91-44-1 |
|
2-Chloro-4-Fluorocinnamic Acid
| 133220-86-7 |
|
2-Iodo-2-Methylpropane, 95% (GC)
| 558-17-8 |
|
2,6-Dibromo-N-Chloro-P-Benzoquinoneimine, 97% (UV-Vis)
| 537-45-1 |
|
Ethyl crotonate, 98%
| 10544-63-5 |
|
Alpha-Bromo-P-Toluic Acid, 97%
| 6232-88-8 |
|
3-Ethyl-2-Methylbenzothiazolinium P-Toluenesulfonate (Pract), 98%
| 14933-76-7 |
|
Thiomorpholine, 98%
| 123-90-0 |
|
Pyruvic Aldehyde, 40 wt. % Solution in Water
| 78-98-8 |
|
4-Methylcyclohexanone, 98%
| 589-92-4 |
|
1,10-Dibromodecane, 97%
| 4101-68-2 |
|
5-Amino-1,3-dimethylpyrazole hydrochloride 99%
| 3524-32-1 |
|
Maleic Anhydride, 99% (pellets)
| 108-31-6 |
|
Ethyl Salicylate, 99+%
| 118-61-6 |
|
2,6-Dimethyl-3,5-heptanedione, 99%
| 18362-64-6 |
|
o-Chlorocinnamic acid, 99.5%, predominantly trans
| 3752-25-8 |
|
1,3-Dichloro-2-methoxy-5-nitrobenzene, 99%
| 17742-69-7 |
|
Lauroyl chloride, 98%
| 112-16-3 |
|
Boc-D-Alanine, 99+%
| 7764-95-6 |
|
Ethyl 4-Bromobutyrate, 95%
| 2969-81-5 |
|
2',4',5'-TRIHYDROXYBUTYROPHENONE, 98% (UV-VIS)
| 1421-63-2 |
|
Cyclotridecanone, tech.
| 832-10-0 |
|
3-Bromo-5-Chloro-1,2,4-Thiadiazole
| 37159-60-7 |
|
Poly(caprolactone) diol, average m.w.2000
| 36890-68-3 |
|
1-Bromo-2-fluoroethane
| 762-49-2 |
|
N-Phenylbenzylamine, 99% (GC)
| 103-32-2 |
|
4-Isothiocyanato-TEMPO, free radical, 95%
| 36410-81-8 |
|
Thianaphthene, 97%
| 95-15-8 |
|
4'-Isocyanatobenzo-15-Crown-5, 99%
| 83935-62-0 |
|
n-Bromosuccinimide, 99%
| 128-08-5 |
|
3-Acetyl-4,5-dimethyl-5-hydroxy-1,5- dihydro-2h-pyrrol-2-one, 99%
| |
|
3-Fluoroaniline, 98%
| 372-19-0 |
|
1-Amino-3,3-Diethoxypropane, 97%
| 41365-75-7 |
|
2-Nitroanisole
| 91-23-6 |
|
Brilliant cresyl blue-bb (cert)
| 10127-36-3 |
|
(-)-Dimethyl D-Tartrate, 99%
| 13171-64-7 |
|
2-Chloro-5-nitrobenzoic acid, 99+%(gc)
| 2516-96-3 |
|
|