**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 91-23-6 |2-Nitroanisole | 99 | 202-052-1 |
|----------------|--------------------------------------|----------|-----------|
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T
Risk Phrases: 22 45
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. May cause cancer.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. No skin absorption data found. No data
found on whether or not this chemical would be likely to cause an
allergic skin reaction.
Ingestion:
May cause irritation of the digestive tract. Methemoglobinemia is
characterized by dizziness, drowsiness, headache, shortness of
breath, cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood), rapid heart rate and chocolate-brown
colored blood. May be harmful if swallowed. Overexposure may cause
methemoglobinemia.
Inhalation:
Effects may be delayed. May cause respiratory tract irritation.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
For large fires, use water spray, fog, or alcohol-resistant foam.
For small fires, use dry chemical, carbon dioxide, halon, or water
spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 91-23-6:
Russia: 1 mg/m3 TWA
CAS# 29191-53-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear brown yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: 0.0036 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 273 deg C
Freezing/Melting Point: 9.4 deg C
Autoignition Temperature: 464 deg C ( 867.20 deg F)
Flash Point: 142 deg C ( 287.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 1.2500 g/cm3
Molecular Formula: C7H7NO3
Molecular Weight: 153.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 91-23-6: BZ8790000
CAS# 29191-53-5 unlisted.
LD50/LC50:
CAS# 91-23-6: Oral, mouse: LD50 = 1300 mg/kg; Oral, mouse: LD50 =
1300 mg/kg; Oral, rat: LD50 = 740 mg/kg; Oral, rat: LD50 = 760
mg/kg.
CAS# 29191-53-5.
Carcinogenicity:
2-Nitroanisole -
California: carcinogen, initial date 10/1/92
NTP: Suspect carcinogen
IARC: Group 2B carcinogen
Nitro-methoxybenzene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Water danger/protection: WGK2 Invertebrate toxicity: EC50 (24 hr)
Daphnia magna 13 mg/l (nominal value) [Kuehn, R. et al Water Res.
1989, 23(4), 501-510]
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITROANISOLE, LIQUID
Hazard Class: 6.1
UN Number: 2730
Packing Group: III
IMO
Shipping Name: NITROANISOLES, LIQUID
Hazard Class: 6.1
UN Number: 2730
Packing Group: III
RID/ADR
Shipping Name: NITROANISOLE
Hazard Class: 6.1
UN Number: 2730
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 22 Harmful if swallowed.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 91-23-6: 3
CAS# 29191-53-5: No information available.
Canada
CAS# 91-23-6 is listed on Canada's NDSL List.
CAS# 91-23-6 is listed on Canada's Ingredient Disclosure List.
CAS# 29191-53-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 91-23-6 is listed on the TSCA inventory.
CAS# 29191-53-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 8/21/1998 Revision #4 Date: 12/06/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3-Amino-2-Cyclohexen-1-One, 96%
| 5220-49-5 |
|
2-Allylphenol, 99+% (GC)
| 1745-81-9 |
|
Ethyl 3-methyl-3-phenylglycidate, 98% mixture of cis and trans
| 77-83-8 |
|
Ethyl 4-Bromobenzoate, 96% (GC)
| 5798-75-4 |
|
D(+)-Camphor
| 464-49-3 |
|
Copper(i) bromide, 98%
| 7787-70-4 |
|
4-Bromo-2-Fluoroanisole, 99+%
| 2357-52-0 |
|
3-Chloro-4-Hydroxybenzoic Acid Hemihydrate 98%
| 3964-58-7 |
|
1,8-Dichloro-9,10-Bis(Phenylethynyl) Anthracene
| 51749-83-8 |
|
4-Ethylresorcinol, 98%
| 2896-60-8 |
|
Anthraquinone-2,6-disulfonic acid, disodium salt
| 84-50-4 |
|
(2,4,7-Trinitro-9-Fluorenylidene)Malononitrile 98%
| 1172-02-7 |
|
p-Methylstyrene, stabilized, 98%
| 622-97-9 |
|
Coumarin 1, Laser Grade
| 91-44-1 |
|
2-Chloro-4-Fluorocinnamic Acid
| 133220-86-7 |
|
2-Iodo-2-Methylpropane, 95% (GC)
| 558-17-8 |
|
2,6-Dibromo-N-Chloro-P-Benzoquinoneimine, 97% (UV-Vis)
| 537-45-1 |
|
Ethyl crotonate, 98%
| 10544-63-5 |
|
Alpha-Bromo-P-Toluic Acid, 97%
| 6232-88-8 |
|
3-Ethyl-2-Methylbenzothiazolinium P-Toluenesulfonate (Pract), 98%
| 14933-76-7 |
|
Thiomorpholine, 98%
| 123-90-0 |
|
Pyruvic Aldehyde, 40 wt. % Solution in Water
| 78-98-8 |
|
4-Methylcyclohexanone, 98%
| 589-92-4 |
|
1,10-Dibromodecane, 97%
| 4101-68-2 |
|
5-Amino-1,3-dimethylpyrazole hydrochloride 99%
| 3524-32-1 |
|
Maleic Anhydride, 99% (pellets)
| 108-31-6 |
|
Ethyl Salicylate, 99+%
| 118-61-6 |
|
2,6-Dimethyl-3,5-heptanedione, 99%
| 18362-64-6 |
|
o-Chlorocinnamic acid, 99.5%, predominantly trans
| 3752-25-8 |
|
1,3-Dichloro-2-methoxy-5-nitrobenzene, 99%
| 17742-69-7 |
|
Lauroyl chloride, 98%
| 112-16-3 |
|
Boc-D-Alanine, 99+%
| 7764-95-6 |
|
Ethyl 4-Bromobutyrate, 95%
| 2969-81-5 |
|
2',4',5'-TRIHYDROXYBUTYROPHENONE, 98% (UV-VIS)
| 1421-63-2 |
|
Cyclotridecanone, tech.
| 832-10-0 |
|
3-Bromo-5-Chloro-1,2,4-Thiadiazole
| 37159-60-7 |
|
Poly(caprolactone) diol, average m.w.2000
| 36890-68-3 |
|
1-Bromo-2-fluoroethane
| 762-49-2 |
|
N-Phenylbenzylamine, 99% (GC)
| 103-32-2 |
|
4-Isothiocyanato-TEMPO, free radical, 95%
| 36410-81-8 |
|
Thianaphthene, 97%
| 95-15-8 |
|
4'-Isocyanatobenzo-15-Crown-5, 99%
| 83935-62-0 |
|
n-Bromosuccinimide, 99%
| 128-08-5 |
|
3-Acetyl-4,5-dimethyl-5-hydroxy-1,5- dihydro-2h-pyrrol-2-one, 99%
| |
|
3-Fluoroaniline, 98%
| 372-19-0 |
|
1-Amino-3,3-Diethoxypropane, 97%
| 41365-75-7 |
|
2-Nitroanisole
| 91-23-6 |
|
Brilliant cresyl blue-bb (cert)
| 10127-36-3 |
|
(-)-Dimethyl D-Tartrate, 99%
| 13171-64-7 |
|
2-Chloro-5-nitrobenzoic acid, 99+%(gc)
| 2516-96-3 |
|
|