**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1270-98-0 |Cyclopentadienyltitanium Trichloride | 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause headache. May cause nausea
and vomiting.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. Do NOT get water inside
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Provide ventilation. Do not get water
inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Minimize
dust generation and accumulation. Do not breathe dust, vapor, mist,
or gas. Keep container tightly closed. Do not get on skin or in eyes.
Use with adequate ventilation. Do not allow contact with water.
Discard contaminated shoes. Keep from contact with moist air and
steam.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1270-98-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: yellow-orange
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Decomposes
Freezing/Melting Point: 170 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 210 deg C
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C5H5Cl3Ti
Molecular Weight: 219.36
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, moisture, excess heat,
exposure to moist air or water.
Incompatibilities with Other Materials:
Strong acids, strong bases, strong oxidizing agents, strong reducing
agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, titanium/titanium oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1270-98-0: XR1927300
LD50/LC50:
Not available.
Carcinogenicity:
Cyclopentadienyltitanium Trichloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1270-98-0: No information available.
Canada
CAS# 1270-98-0 is listed on Canada's DSL List.
CAS# 1270-98-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1270-98-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/10/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
S-(4-Chlorobenzyl)-Thiuronium Chloride, 99+%
| 544-47-8 |
|
N-Formyl-4-(Methylamino)Benzoic Acid
| 51865-84-0 |
|
2,5-Dibromo-4-fluorotoluene
| |
|
Ammonium-d4 deuteroxide, 26 wt % solution in D2O, 99+ atom % D
| 1336-21-6 |
|
3,4-Dihydroxybenzoic Acid, 97%
| 99-50-3 |
|
d-Erythruronolactone acetonide, 95+% (nmr)
| 85254-46-2 |
|
1-Phenyloctane, 99%
| 2189-60-8 |
|
N,N-Dimethyl-M-Phenylenediamine Dihydro-Chloride, 99%
| 3575-32-4 |
|
5-Methyl-5-phenylhydantoin, 99%
| 6843-49-8 |
|
Sodium Hexafluorophosphate, 98.5+%
| 21324-39-0 |
|
Allylurea, 95%
| 557-11-9 |
|
Methyl Trimethylacetate, 99%
| 598-98-1 |
|
m-Anisaldehyde, 97%
| 591-31-1 |
|
Cyclopentadienyltitanium Trichloride
| 1270-98-0 |
|
Erioglaucine disodiumsalt (c.i. 42090)
| 3844-45-9 |
|
Cyclopentadienylsodium (18% in tetrahydrofuran)
| 109-99-9 |
|
Methyl morpholinoacetate, 99+%
| |
|
Thiobenzoic Acid, 90-95%
| 98-91-9 |
|
DL-Serine Methyl Ester Hydrochloride, 99%
| 5619-04-5 |
|
Dl-3,4-dihydroxyphenylglycol
| 28822-73-3 |
|
4-Tert.-butylcyclohexanol, 99%, mixture of isomers
| 98-52-2 |
|
2-Amino-6-Purinethiol, 95%
| 154-42-7 |
|
3-Nitrobenzonitrile, 98%
| 619-24-9 |
|
Direct Blue 71
| 4399-55-7 |
|
4,4'-Sulfonylbis-(Methylbenzoate) Tech.
| 3965-53-5 |
|
5-Chloro-2-Nitroaniline, 97%
| 1635-61-6 |
|
N-Methyl-o-toluidine
| 611-21-2 |
|
2',3'-O-Isopropylideneuridine, 99%
| 362-43-6 |
|
1-Bromo-2,4-difluorobenzene, 99%
| 348-57-2 |
|
2,2-Dimethylglutaric Acid, 98+%
| 681-57-2 |
|
Methyl Benzoylformate, 99%
| 15206-55-0 |
|
1,4-Dibromobenzene, 99%
| 106-37-6 |
|
2',4'-Dichloroacetophenone, 94%
| 2234-16-4 |
|
Formamidinesulfinic Acid, 99%
| 1758-73-2 |
|
2-Naphthalenesulfonic acid sodium salt, 99+% (uv-vis)
| 532-02-5 |
|
2,4,6-Tribromoaniline, 98%
| 147-82-0 |
|
3-(Diethylamino)-1,2-Propanediol, 98%
| 621-56-7 |
|
Diallyl phthalate, 98%
| 131-17-9 |
|
Triethyl 1,1,2-Ethanetricarboxylate, 99%
| 7459-46-3 |
|
3-Amino-3-phenylpropionic acid
| |
|
Trans-2-Hydroxymethyl-1-Cyclohexylamine Hydrochloride, 99+%
| 28250-45-5 |
|
2-Chlorobenzamide, 98%
| 609-66-5 |
|
(D)-(+)-Threitol, 98%
| 2418-52-2 |
|
Magnesium Cyclohexanebutyrate
| 62669-64-1 |
|
d-Isoproterenol d-bitartrate
| 14638-70-1 |
|
3'-Isothiocyanatoacetanilide
| 3137-83-5 |
|
Phenyl sulfone, 97%
| 127-63-9 |
|
o-Neopentyl-s-triphenylstannyl xanthate
| 143037-51-8 |
|
DL-Alpha-Methyltryptamine, 99%
| 299-26-3 |
|
3-Buten-1-ol, 96%
| 627-27-0 |
|
|