**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3844-45-9 |C.i. acid blue 9, disodium salt | ca. 100 | 223-339-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 33
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Danger of cumulative effects.Cancer suspect agent.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
Cancer suspect agent.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 3844-45-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: dark blue
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 283 deg C
Autoignition Temperature: Not available.
Flash Point: 283 deg C ( 541.40 deg F)
Explosion Limits, lower: Npt available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 283 deg C
Solubility in water: soluble
Specific Gravity/Density:
Molecular Formula: C37H34N2O9S3Na2
Molecular Weight: 792.84
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and
toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3844-45-9: BQ4725000
LD50/LC50:
Not available.
Carcinogenicity:
C.i. acid blue 9, disodium salt -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 33 Danger of cumulative effects.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 3844-45-9: 1
Canada
CAS# 3844-45-9 is listed on Canada's DSL List.
CAS# 3844-45-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3844-45-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/19/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
S-(4-Chlorobenzyl)-Thiuronium Chloride, 99+%
| 544-47-8 |
|
N-Formyl-4-(Methylamino)Benzoic Acid
| 51865-84-0 |
|
2,5-Dibromo-4-fluorotoluene
| |
|
Ammonium-d4 deuteroxide, 26 wt % solution in D2O, 99+ atom % D
| 1336-21-6 |
|
3,4-Dihydroxybenzoic Acid, 97%
| 99-50-3 |
|
d-Erythruronolactone acetonide, 95+% (nmr)
| 85254-46-2 |
|
1-Phenyloctane, 99%
| 2189-60-8 |
|
N,N-Dimethyl-M-Phenylenediamine Dihydro-Chloride, 99%
| 3575-32-4 |
|
5-Methyl-5-phenylhydantoin, 99%
| 6843-49-8 |
|
Sodium Hexafluorophosphate, 98.5+%
| 21324-39-0 |
|
Allylurea, 95%
| 557-11-9 |
|
Methyl Trimethylacetate, 99%
| 598-98-1 |
|
m-Anisaldehyde, 97%
| 591-31-1 |
|
Cyclopentadienyltitanium Trichloride
| 1270-98-0 |
|
Erioglaucine disodiumsalt (c.i. 42090)
| 3844-45-9 |
|
Cyclopentadienylsodium (18% in tetrahydrofuran)
| 109-99-9 |
|
Methyl morpholinoacetate, 99+%
| |
|
Thiobenzoic Acid, 90-95%
| 98-91-9 |
|
DL-Serine Methyl Ester Hydrochloride, 99%
| 5619-04-5 |
|
Dl-3,4-dihydroxyphenylglycol
| 28822-73-3 |
|
4-Tert.-butylcyclohexanol, 99%, mixture of isomers
| 98-52-2 |
|
2-Amino-6-Purinethiol, 95%
| 154-42-7 |
|
3-Nitrobenzonitrile, 98%
| 619-24-9 |
|
Direct Blue 71
| 4399-55-7 |
|
4,4'-Sulfonylbis-(Methylbenzoate) Tech.
| 3965-53-5 |
|
5-Chloro-2-Nitroaniline, 97%
| 1635-61-6 |
|
N-Methyl-o-toluidine
| 611-21-2 |
|
2',3'-O-Isopropylideneuridine, 99%
| 362-43-6 |
|
1-Bromo-2,4-difluorobenzene, 99%
| 348-57-2 |
|
2,2-Dimethylglutaric Acid, 98+%
| 681-57-2 |
|
Methyl Benzoylformate, 99%
| 15206-55-0 |
|
1,4-Dibromobenzene, 99%
| 106-37-6 |
|
2',4'-Dichloroacetophenone, 94%
| 2234-16-4 |
|
Formamidinesulfinic Acid, 99%
| 1758-73-2 |
|
2-Naphthalenesulfonic acid sodium salt, 99+% (uv-vis)
| 532-02-5 |
|
2,4,6-Tribromoaniline, 98%
| 147-82-0 |
|
3-(Diethylamino)-1,2-Propanediol, 98%
| 621-56-7 |
|
Diallyl phthalate, 98%
| 131-17-9 |
|
Triethyl 1,1,2-Ethanetricarboxylate, 99%
| 7459-46-3 |
|
3-Amino-3-phenylpropionic acid
| |
|
Trans-2-Hydroxymethyl-1-Cyclohexylamine Hydrochloride, 99+%
| 28250-45-5 |
|
2-Chlorobenzamide, 98%
| 609-66-5 |
|
(D)-(+)-Threitol, 98%
| 2418-52-2 |
|
Magnesium Cyclohexanebutyrate
| 62669-64-1 |
|
d-Isoproterenol d-bitartrate
| 14638-70-1 |
|
3'-Isothiocyanatoacetanilide
| 3137-83-5 |
|
Phenyl sulfone, 97%
| 127-63-9 |
|
o-Neopentyl-s-triphenylstannyl xanthate
| 143037-51-8 |
|
DL-Alpha-Methyltryptamine, 99%
| 299-26-3 |
|
3-Buten-1-ol, 96%
| 627-27-0 |
|
|