**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13037-60-0 |2-Bromophenyl isothiocyanate | 98% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Lachrymator (substance which
increases the flow of tears).Corrosive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
May cause allergic respiratory reaction. May cause irritation of the
respiratory tract with burning pain in the nose and throat, coughing,
wheezing, shortness of breath and pulmonary edema. Causes chemical
burns to the respiratory tract. Inhalation may be fatal as a result
of spasm, inflammation, edema of the larynx and bronchi, chemical
pneumonitis and pulmonary edema.
Chronic:
Repeated or prolonged exposure may cause allergic reactions in
sensitive individuals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
Use carbon dioxide. Use dry chemical. Do NOT get water inside
containers. Cool containers with flooding quantities of water until
well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not get in eyes, on skin, or on clothing. Keep container tightly
closed. Do not ingest or inhale. Use with adequate ventilation. Do
not allow contact with water. Use only in a chemical fume hood.
Discard contaminated shoes. Keep from contact with moist air and
steam.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Corrosives area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 13037-60-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: pale-yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 257 deg C @ 770.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.5910g/cm3
Molecular Formula: C7H4BrNS
Molecular Weight: 214.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
High temperatures, incompatible materials, moisture, exposure to
moist air or water.
Incompatibilities with Other Materials:
Alcohols, acids, amines, strong bases, strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide,
hydrogen bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13037-60-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Bromophenyl isothiocyanate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13037-60-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13037-60-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13037-60-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/01/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3'-Fluoro-4'-methoxyacetophenone, 99%
| 455-91-4 |
|
1,4-Cyclohexanebis(methylamine) (pract) cis and trans mixture, 95%
| 2549-93-1 |
|
Benzyl-2-bromoacetate, 96%
| 5437-45-6 |
|
n-(tert-Butoxycarbonyl)ethanolamine, 98%
| 26690-80-2 |
|
DL-2,4-Diaminobutyric acid dihydrochloride , 98%
| 65427-54-5 |
|
n-Acetyl-l-tryptophan ethyl ester, 99%
| 2382-80-1 |
|
1,2-Pentanediol, 97%
| 5343-92-0 |
|
Methyl 5-bromovalerate, 97%
| 5454-83-1 |
|
Ethyl P-Nitrocinnamate, 99% Predominantly Trans
| 953-26-4 |
|
Ethyl 6-bromohexanoate, 99%
| 25542-62-5 |
|
2-BROMO-4-FLUOROANILINE, 97%
| 1003-98-1 |
|
d-Xylonic gamma-lactone, 96%
| 15384-37-9 |
|
6-Bromo-2-Naphthyl-Beta-D-Galactopyranoside, 98%
| 15572-30-2 |
|
d-Trehalose anhydrous
| 6138-23-4 |
|
2-(P-Toluenesulfonyl)Ethanol
| 22381-54-0 |
|
D-Glucuronic Acid, 98%
| 6556-12-3 |
|
DL-Lysine, 98%
| 70-54-2 |
|
(s)-(+)-2-(Methoxymethyl)pyrrolidine, 99%
| 63126-47-6 |
|
1,1-Diphenylhydrazine hydrochloride, 99%
| 530-47-2 |
|
4-Iodo-D-phenylalanine, monohydrate, 97%
| 0-00-1 |
|
L-Iditol, 99%
| 488-45-9 |
|
N-(9-Fluorenylmethoxycarbonyl)-L-Phenylalanine Pentafluorophenyl
| 86060-92-6 |
|
N-(9-Fluorenylmethoxycarbonyl)-L-Valine Pentafluorophenyl Ester, 97%
| 86060-87-9 |
|
N-(9-Fluorenylmethoxycarbonyl)glycine Pentafluorophenyl Ester, 97%
| 86060-85-7 |
|
N-Epsilon-(Tert-Butoxycarbonyl)-L-Lysine, 97%
| 2418-95-3 |
|
N-Alpha-(Tert-Butoxycarbonyl)-L-Lysine, 99%
| 13734-28-6 |
|
L-Leucine-4-Nitroanilide, 99%
| 4178-93-2 |
|
Vinyl chloroformate, 99%, stabilized with 50-100 ppm BHT
| 5130-24-5 |
|
o-(5-Norbornene-2,3-dicarboximido)-n,n,n', n'-tetramethyluronium bf4,
| 125700-73-4 |
|
O-((Ethoxycarbonyl)Cyanomethyleneamino)-N, N,N',N'-Tetramethyluronium
| 136849-72-4 |
|
l-Aspartyl-l-phenylalanine
| 13433-09-5 |
|
Dodecanedioyl Dichloride, 98%
| 4834-98-4 |
|
2,2,2-Trifluoroethanesulfonyl Chloride, 99 %
| 1648-99-3 |
|
2-Bromo-2-methylbutane, 95%
| 507-36-8 |
|
3-Doxyl-5-Alpha-Cholestane, Free Radical, 98%
| 18353-76-9 |
|
3-Bromopentane, 97%
| 1809-10-5 |
|
2-Bromovaleric acid, 98%
| 584-93-0 |
|
(S)-(+)-1-Iodo-2-Methylbutane, 99%
| 29394-58-9 |
|
2-Bromophenyl Isothiocyanate, 98%
| 13037-60-0 |
|
3-Bromophenyl Isothiocyanate, 97%
| 2131-59-1 |
|
Phenyl 2-(trimethylsilyl)ethyl sulfone, 99+%
| 73476-18-3 |
|
2,4-Dichlorophenyl Isothiocyanate, 95%
| 6590-96-1 |
|
2-Fluorophenyl Isothiocyanate, 98%
| 38985-64-7 |
|
4-Methoxyphenyl Isothiocyanate, 98%
| 2284-20-0 |
|
Propyl Isothiocyanate, 98%
| 628-30-8 |
|
2-Ethylhexyl Bromide, 95%
| 18908-66-2 |
|
1,2,3-Tribromopropane, 97%
| 96-11-7 |
|
Iron (II) Acetate, 95%
| 3094-87-9 |
|
1,2-Dibromobutane, 97%
| 533-98-2 |
|
2,3-Dibromobutane, 99%, Mixture of (+/-) and Meso
| 5408-86-6 |
|
|