**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2284-20-0 |4-Methoxyphenyl Isothiocyanate | 98.0 | 218-921-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 42/43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
May cause sensitization by inhalation and skin contact.The
toxicological properties of this material have not been fully
investigated.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. May cause asthmatic attacks
due to allergic sensitization of the respiratory tract. The
toxicological properties of this substance have not been fully
investigated.
Chronic:
Chronic inhalation may cause effects similar to those of acute
inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Combustion generates toxic fumes. During a fire,
irritating and highly toxic gases may be generated by thermal
decomposition or combustion.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Do NOT get water inside containers. For
large fires, use water spray, fog or alcohol-resistant foam. Do NOT
use straight streams of water. Most foams will react with the
material and release corrosive/toxic gases.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Use water
spray to disperse the gas/vapor. Provide ventilation. Do not get
water inside containers. A vapor suppressing foam may be used to
reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Do not allow contact with water.
Discard contaminated shoes. Keep from contact with moist air and
steam.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 2284-20-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: fish-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 280 - 281 deg C @ 760.00mm Hg
Freezing/Melting Point: 18 deg C
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.1960g/cm3
Molecular Formula: C8H7NOS
Molecular Weight: 165.22
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
High temperatures, incompatible materials, moisture, exposure to
moist air or water.
Incompatibilities with Other Materials:
Moisture, strong acids, strong bases, strong oxidizing agents, strong
reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and
toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2284-20-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Methoxyphenyl Isothiocyanate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 37 Wear suitable gloves.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 2284-20-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2284-20-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2284-20-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/18/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3'-Fluoro-4'-methoxyacetophenone, 99%
| 455-91-4 |
|
1,4-Cyclohexanebis(methylamine) (pract) cis and trans mixture, 95%
| 2549-93-1 |
|
Benzyl-2-bromoacetate, 96%
| 5437-45-6 |
|
n-(tert-Butoxycarbonyl)ethanolamine, 98%
| 26690-80-2 |
|
DL-2,4-Diaminobutyric acid dihydrochloride , 98%
| 65427-54-5 |
|
n-Acetyl-l-tryptophan ethyl ester, 99%
| 2382-80-1 |
|
1,2-Pentanediol, 97%
| 5343-92-0 |
|
Methyl 5-bromovalerate, 97%
| 5454-83-1 |
|
Ethyl P-Nitrocinnamate, 99% Predominantly Trans
| 953-26-4 |
|
Ethyl 6-bromohexanoate, 99%
| 25542-62-5 |
|
2-BROMO-4-FLUOROANILINE, 97%
| 1003-98-1 |
|
d-Xylonic gamma-lactone, 96%
| 15384-37-9 |
|
6-Bromo-2-Naphthyl-Beta-D-Galactopyranoside, 98%
| 15572-30-2 |
|
d-Trehalose anhydrous
| 6138-23-4 |
|
2-(P-Toluenesulfonyl)Ethanol
| 22381-54-0 |
|
D-Glucuronic Acid, 98%
| 6556-12-3 |
|
DL-Lysine, 98%
| 70-54-2 |
|
(s)-(+)-2-(Methoxymethyl)pyrrolidine, 99%
| 63126-47-6 |
|
1,1-Diphenylhydrazine hydrochloride, 99%
| 530-47-2 |
|
4-Iodo-D-phenylalanine, monohydrate, 97%
| 0-00-1 |
|
L-Iditol, 99%
| 488-45-9 |
|
N-(9-Fluorenylmethoxycarbonyl)-L-Phenylalanine Pentafluorophenyl
| 86060-92-6 |
|
N-(9-Fluorenylmethoxycarbonyl)-L-Valine Pentafluorophenyl Ester, 97%
| 86060-87-9 |
|
N-(9-Fluorenylmethoxycarbonyl)glycine Pentafluorophenyl Ester, 97%
| 86060-85-7 |
|
N-Epsilon-(Tert-Butoxycarbonyl)-L-Lysine, 97%
| 2418-95-3 |
|
N-Alpha-(Tert-Butoxycarbonyl)-L-Lysine, 99%
| 13734-28-6 |
|
L-Leucine-4-Nitroanilide, 99%
| 4178-93-2 |
|
Vinyl chloroformate, 99%, stabilized with 50-100 ppm BHT
| 5130-24-5 |
|
o-(5-Norbornene-2,3-dicarboximido)-n,n,n', n'-tetramethyluronium bf4,
| 125700-73-4 |
|
O-((Ethoxycarbonyl)Cyanomethyleneamino)-N, N,N',N'-Tetramethyluronium
| 136849-72-4 |
|
l-Aspartyl-l-phenylalanine
| 13433-09-5 |
|
Dodecanedioyl Dichloride, 98%
| 4834-98-4 |
|
2,2,2-Trifluoroethanesulfonyl Chloride, 99 %
| 1648-99-3 |
|
2-Bromo-2-methylbutane, 95%
| 507-36-8 |
|
3-Doxyl-5-Alpha-Cholestane, Free Radical, 98%
| 18353-76-9 |
|
3-Bromopentane, 97%
| 1809-10-5 |
|
2-Bromovaleric acid, 98%
| 584-93-0 |
|
(S)-(+)-1-Iodo-2-Methylbutane, 99%
| 29394-58-9 |
|
2-Bromophenyl Isothiocyanate, 98%
| 13037-60-0 |
|
3-Bromophenyl Isothiocyanate, 97%
| 2131-59-1 |
|
Phenyl 2-(trimethylsilyl)ethyl sulfone, 99+%
| 73476-18-3 |
|
2,4-Dichlorophenyl Isothiocyanate, 95%
| 6590-96-1 |
|
2-Fluorophenyl Isothiocyanate, 98%
| 38985-64-7 |
|
4-Methoxyphenyl Isothiocyanate, 98%
| 2284-20-0 |
|
Propyl Isothiocyanate, 98%
| 628-30-8 |
|
2-Ethylhexyl Bromide, 95%
| 18908-66-2 |
|
1,2,3-Tribromopropane, 97%
| 96-11-7 |
|
Iron (II) Acetate, 95%
| 3094-87-9 |
|
1,2-Dibromobutane, 97%
| 533-98-2 |
|
2,3-Dibromobutane, 99%, Mixture of (+/-) and Meso
| 5408-86-6 |
|
|