**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 5130-24-5 |Vinyl chloroformate, stab with 50-100 | 99 | 225-874-2 |
| |ppm BHT | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 23 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Toxic by inhalation. Causes burns.Moisture
sensitive.Corrosive.Lachrymator (substance which increases the flow
of tears).
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May be harmful if absorbed through the skin.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. Ingestion of large amounts may cause
central nervous depression. Causes digestive tract irritation with
possible burns.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. Vapors may cause
dizziness or suffocation. Inhalation may produce burning sensation,
coughing, wheezing, laryngitis, shortness of breath, headache,
nausea, and vomiting.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately. May cause
methemoglobinemia, cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), convulsions, and death.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. Do not use mouth-to-mouth resuscitation if victim
ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide. DO NOT USE WATER!
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Wash area with soap and water. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove
all sources of ignition. Absorb spill using an absorbent,
non-combustible material such as earth, sand, or vermiculite. Do not
use combustible materials such as sawdust. Use a spark-proof tool.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use spark-proof tools and explosion
proof equipment. Keep container tightly closed. Keep away from heat,
sparks and flame. Do not get on skin or in eyes. Do not ingest or
inhale. Use with adequate ventilation. Store protected from light. Do
not allow contact with water. Use only in a chemical fume hood.
Prevent build up of vapors to explosive concentration. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat, sparks, and flame. Refrigerator/flammables.
Keep containers tightly closed. Store protected from moisture. Store
protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 5130-24-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 45.52 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 68 - 69 deg C @ 735.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: -4 deg C ( 24.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: 1.2530g/cm3
Molecular Formula: C3H3ClO2
Molecular Weight: 106.51
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Moisture sensitive. Light sensitive. Forms explosive mixtures with
air.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Acids, strong bases, alcohols, amines, air, direct light.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 5130-24-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Vinyl chloroformate, stab with 50-100 ppm BHT -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 3 (8)
UN Number: 2924
Packing Group: I
IMO
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3.2 (8)
UN Number: 2924
Packing Group: I
RID/ADR
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3
UN Number: 2924
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 23 Toxic by inhalation.
R 34 Causes burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 5130-24-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 5130-24-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5130-24-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/23/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3'-Fluoro-4'-methoxyacetophenone, 99%
| 455-91-4 |
|
1,4-Cyclohexanebis(methylamine) (pract) cis and trans mixture, 95%
| 2549-93-1 |
|
Benzyl-2-bromoacetate, 96%
| 5437-45-6 |
|
n-(tert-Butoxycarbonyl)ethanolamine, 98%
| 26690-80-2 |
|
DL-2,4-Diaminobutyric acid dihydrochloride , 98%
| 65427-54-5 |
|
n-Acetyl-l-tryptophan ethyl ester, 99%
| 2382-80-1 |
|
1,2-Pentanediol, 97%
| 5343-92-0 |
|
Methyl 5-bromovalerate, 97%
| 5454-83-1 |
|
Ethyl P-Nitrocinnamate, 99% Predominantly Trans
| 953-26-4 |
|
Ethyl 6-bromohexanoate, 99%
| 25542-62-5 |
|
2-BROMO-4-FLUOROANILINE, 97%
| 1003-98-1 |
|
d-Xylonic gamma-lactone, 96%
| 15384-37-9 |
|
6-Bromo-2-Naphthyl-Beta-D-Galactopyranoside, 98%
| 15572-30-2 |
|
d-Trehalose anhydrous
| 6138-23-4 |
|
2-(P-Toluenesulfonyl)Ethanol
| 22381-54-0 |
|
D-Glucuronic Acid, 98%
| 6556-12-3 |
|
DL-Lysine, 98%
| 70-54-2 |
|
(s)-(+)-2-(Methoxymethyl)pyrrolidine, 99%
| 63126-47-6 |
|
1,1-Diphenylhydrazine hydrochloride, 99%
| 530-47-2 |
|
4-Iodo-D-phenylalanine, monohydrate, 97%
| 0-00-1 |
|
L-Iditol, 99%
| 488-45-9 |
|
N-(9-Fluorenylmethoxycarbonyl)-L-Phenylalanine Pentafluorophenyl
| 86060-92-6 |
|
N-(9-Fluorenylmethoxycarbonyl)-L-Valine Pentafluorophenyl Ester, 97%
| 86060-87-9 |
|
N-(9-Fluorenylmethoxycarbonyl)glycine Pentafluorophenyl Ester, 97%
| 86060-85-7 |
|
N-Epsilon-(Tert-Butoxycarbonyl)-L-Lysine, 97%
| 2418-95-3 |
|
N-Alpha-(Tert-Butoxycarbonyl)-L-Lysine, 99%
| 13734-28-6 |
|
L-Leucine-4-Nitroanilide, 99%
| 4178-93-2 |
|
Vinyl chloroformate, 99%, stabilized with 50-100 ppm BHT
| 5130-24-5 |
|
o-(5-Norbornene-2,3-dicarboximido)-n,n,n', n'-tetramethyluronium bf4,
| 125700-73-4 |
|
O-((Ethoxycarbonyl)Cyanomethyleneamino)-N, N,N',N'-Tetramethyluronium
| 136849-72-4 |
|
l-Aspartyl-l-phenylalanine
| 13433-09-5 |
|
Dodecanedioyl Dichloride, 98%
| 4834-98-4 |
|
2,2,2-Trifluoroethanesulfonyl Chloride, 99 %
| 1648-99-3 |
|
2-Bromo-2-methylbutane, 95%
| 507-36-8 |
|
3-Doxyl-5-Alpha-Cholestane, Free Radical, 98%
| 18353-76-9 |
|
3-Bromopentane, 97%
| 1809-10-5 |
|
2-Bromovaleric acid, 98%
| 584-93-0 |
|
(S)-(+)-1-Iodo-2-Methylbutane, 99%
| 29394-58-9 |
|
2-Bromophenyl Isothiocyanate, 98%
| 13037-60-0 |
|
3-Bromophenyl Isothiocyanate, 97%
| 2131-59-1 |
|
Phenyl 2-(trimethylsilyl)ethyl sulfone, 99+%
| 73476-18-3 |
|
2,4-Dichlorophenyl Isothiocyanate, 95%
| 6590-96-1 |
|
2-Fluorophenyl Isothiocyanate, 98%
| 38985-64-7 |
|
4-Methoxyphenyl Isothiocyanate, 98%
| 2284-20-0 |
|
Propyl Isothiocyanate, 98%
| 628-30-8 |
|
2-Ethylhexyl Bromide, 95%
| 18908-66-2 |
|
1,2,3-Tribromopropane, 97%
| 96-11-7 |
|
Iron (II) Acetate, 95%
| 3094-87-9 |
|
1,2-Dibromobutane, 97%
| 533-98-2 |
|
2,3-Dibromobutane, 99%, Mixture of (+/-) and Meso
| 5408-86-6 |
|
|