**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13683-41-5 |(1-Bromovinyl)trimethylsilane | ca 100 | 237-195-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. Ingestion of large amounts may cause CNS
depression.
Inhalation:
The toxicological properties of this substance have not been fully
investigated. Aspiration may lead to pulmonary edema. Vapors may
cause dizziness or suffocation. May cause burning sensation in the
chest.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT get water inside
containers. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers. A vapor suppressing foam may be
used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Use with
adequate ventilation. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Avoid
contact with skin and eyes. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not allow contact with water. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames. Keep from contact with moist air and
steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 13683-41-5:
United Kingdom, WEL - TWA: (listed as silica, amorphous): 6 mg/m3
(inhalable dust); 2.4 mg/m3 TWA (respirable dust)
United Kingdom, WEL - STEL: (listed as silica, amorphous): 18 mg/
STEL (inhalable dust); 7.2 mg/m3 STEL (respirable dust)
Russia: (listed as silica, amorphous): 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 55-57C @ 80mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 9 deg C ( 48.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.1600g/cm3
Molecular Formula: C5H11BrSi
Molecular Weight: 179.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat,
strong oxidants.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide, bromine fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 13683-41-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(1-Bromovinyl)trimethylsilane -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 28A After contact with skin, wash immediately with
plenty of water.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13683-41-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13683-41-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13683-41-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/05/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(1-Bromovinyl)trimethylsilane
| 13683-41-5 |
|
Beta-Cyclodextrin
| 7585-39-9 |
|
Chromium(III) benzoylacetonate
| 16432-36-3 |
|
Trans-1-Decalone, 98%
| 21370-71-8 |
|
1-Phenylpiperazine hydrochloride, 97%
| 2210-93-7 |
|
2,6-Diformyl-4-Chlorophenol, 99%
| 32596-43-3 |
|
2,3-Diethyl-5-methylpyrazine, 99%
| 18138-04-0 |
|
(1R,2S)-(-)-Ephedrine, 98.5% (Dry Substance)
| 299-42-3 |
|
3,3'-Diethylthiadicarbocyanine Iodide, Laser Grade, 99% (UV-VIS)
| 514-73-8 |
|
Palladium-Poly(Ethylenimine), Silica Gel Supported Powder, 40-200
| 0-01-1 |
|
1,5-Pentanedithiol, 98%
| 928-98-3 |
|
4-Methyl-1-cyclohexene, 97%
| 591-47-9 |
|
Benzyltriethylammonium Bromide, 99%
| 5197-95-5 |
|
3-methylanisole, 99%
| 100-84-5 |
|
2,4,4-Trimethyl-1-pentene, 99%
| 107-39-1 |
|
N,N'-Bis(Methoxymethyl)Diaza-18-Crown-6 97%
| 0-01-1 |
|
Trimethylacetic anhydride, 99%
| 1538-75-6 |
|
Ethyl 3-endo-aminobicyclo [2,2,1] heptane-2-endo-carboxylate
| 95630-76-5 |
|
p-Ethyltoluene, 98%
| 622-96-8 |
|
Folinic Acid, Calcium Salt Pentahydrate, 85.0-110.0%, HPLC (on dried
| 1492-18-8 |
|
Mesityl oxide, 91% (gc)
| 141-79-7 |
|
Acetyl Methyl Carbinol (Pract), 93% (Titr.)
| 513-86-0 |
|
2-Carboxybenzaldehyde, 99%
| 119-67-5 |
|
Copper(i) iodide, 98%
| 7681-65-4 |
|
5-Vinyl-2-Norbornene, Tech.
| 3048-64-4 |
|
1-Hexadecene, tech., 92%, alpha-olefin c16
| 629-73-2 |
|
5-Amino-4,6-Dichloropyrimidine, 97%
| 5413-85-4 |
|
2-(2-Chlorophenyl)ethylamine, 98%
| 13078-80-3 |
|
Carbobenzoxyhydrazide, 98%
| 5331-43-1 |
|
Butyl acrylate, 99% (GC)
| 141-32-2 |
|
Diphenyl methyl phosphine, 98% (gc)
| 1486-28-8 |
|
Lithium Cyclohexanebutyrate
| 62638-00-0 |
|
3,4-Dichloroanisole, 99+%
| 36404-30-5 |
|
d-Valine, 98+%
| 640-68-6 |
|
2,5-Di-Tert-Butylhydroquinone, 99% (Titr.)
| 88-58-4 |
|
1-Iodohexane, 97% (gc)
| 638-45-9 |
|
4-Fluorobenzylamine, 97+%
| 140-75-0 |
|
Trimethylsilylisocyanate, 97%
| 1118-02-1 |
|
alpha-Ethylphenethyl alcohol, 97%
| 701-70-2 |
|
Chromotropic Acid Disodium Salt Dihydrate
| 5808-22-0 |
|
Silver(I) Fluoride, 99+%
| 7775-41-9 |
|
4-Fluorophenoxyacetic acid, 99+%
| 405-79-8 |
|
Propionaldehyde diethyl acetal, 97%
| 4744-08-5 |
|
1-Fluoro-2-iodobenzene, 99%
| 348-52-7 |
|
Methyl 4-Oxo-3-Piperidinecarboxylate Hydrochloride, 98% (TLC)
| 56026-52-9 |
|
10-Chloro-9-Anthraldehyde, 97%
| 10527-16-9 |
|
4-Bromo-2-Methylaniline, 97%
| 583-75-5 |
|
9-Aminoacridine hydrochloride monohydrate, 99+%
| 134-50-9 |
|
4,4'-bis(dimethylamino)benzhydrol, tech., 85% (dry subst.)
| 119-58-4 |
|
Methyl 4-hydroxyphenylacetate, 99%
| 14199-15-6 |
|
|