**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3048-64-4 |5-vinyl-2-Norbornene | ca 100 | 221-259-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 36
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to eyes.Lachrymator (substance which increases
the flow of tears).
Potential Health Effects
Eye:
May cause eye irritation. Lachrymator (substance which increases
the flow of tears).
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation. Vapors may cause dizziness
or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. A vapor suppressing foam
may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact
with skin and eyes. Empty containers retain product residue, (liquid
and/or vapor), and can be dangerous. Keep away from heat, sparks and
flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry place. Store in a tightly closed
container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 3048-64-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: 6 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 141 deg C @ 760.00mm Hg
Freezing/Melting Point: -80 deg C
Autoignition Temperature: Not available.
Flash Point: 27 deg C ( 80.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H12
Molecular Weight: 120.19
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, none reported, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3048-64-4: RC0350000
LD50/LC50:
CAS# 3048-64-4: Draize test, rabbit, eye: 100 uL Moderate; Draize
test, rabbit, skin: 500 uL Moderate; Inhalation, mouse: LC50 = 17700
mg/m3/2H; Inhalation, mouse: LC50 = 15100 mg/m3; Inhalation, rat:
LC50 = 2231 ppm/4H; Oral, mouse: LD50 = 4690 mg/kg; Oral, rat: LD50 =
5190 uL/kg; Skin, rabbit: LD50 = 15900 uL/kg.
Carcinogenicity:
5-vinyl-2-Norbornene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36 Irritating to eyes.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 3048-64-4: No information available.
Canada
CAS# 3048-64-4 is listed on Canada's NDSL List.
CAS# 3048-64-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3048-64-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/11/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
(1-Bromovinyl)trimethylsilane
| 13683-41-5 |
|
Beta-Cyclodextrin
| 7585-39-9 |
|
Chromium(III) benzoylacetonate
| 16432-36-3 |
|
Trans-1-Decalone, 98%
| 21370-71-8 |
|
1-Phenylpiperazine hydrochloride, 97%
| 2210-93-7 |
|
2,6-Diformyl-4-Chlorophenol, 99%
| 32596-43-3 |
|
2,3-Diethyl-5-methylpyrazine, 99%
| 18138-04-0 |
|
(1R,2S)-(-)-Ephedrine, 98.5% (Dry Substance)
| 299-42-3 |
|
3,3'-Diethylthiadicarbocyanine Iodide, Laser Grade, 99% (UV-VIS)
| 514-73-8 |
|
Palladium-Poly(Ethylenimine), Silica Gel Supported Powder, 40-200
| 0-01-1 |
|
1,5-Pentanedithiol, 98%
| 928-98-3 |
|
4-Methyl-1-cyclohexene, 97%
| 591-47-9 |
|
Benzyltriethylammonium Bromide, 99%
| 5197-95-5 |
|
3-methylanisole, 99%
| 100-84-5 |
|
2,4,4-Trimethyl-1-pentene, 99%
| 107-39-1 |
|
N,N'-Bis(Methoxymethyl)Diaza-18-Crown-6 97%
| 0-01-1 |
|
Trimethylacetic anhydride, 99%
| 1538-75-6 |
|
Ethyl 3-endo-aminobicyclo [2,2,1] heptane-2-endo-carboxylate
| 95630-76-5 |
|
p-Ethyltoluene, 98%
| 622-96-8 |
|
Folinic Acid, Calcium Salt Pentahydrate, 85.0-110.0%, HPLC (on dried
| 1492-18-8 |
|
Mesityl oxide, 91% (gc)
| 141-79-7 |
|
Acetyl Methyl Carbinol (Pract), 93% (Titr.)
| 513-86-0 |
|
2-Carboxybenzaldehyde, 99%
| 119-67-5 |
|
Copper(i) iodide, 98%
| 7681-65-4 |
|
5-Vinyl-2-Norbornene, Tech.
| 3048-64-4 |
|
1-Hexadecene, tech., 92%, alpha-olefin c16
| 629-73-2 |
|
5-Amino-4,6-Dichloropyrimidine, 97%
| 5413-85-4 |
|
2-(2-Chlorophenyl)ethylamine, 98%
| 13078-80-3 |
|
Carbobenzoxyhydrazide, 98%
| 5331-43-1 |
|
Butyl acrylate, 99% (GC)
| 141-32-2 |
|
Diphenyl methyl phosphine, 98% (gc)
| 1486-28-8 |
|
Lithium Cyclohexanebutyrate
| 62638-00-0 |
|
3,4-Dichloroanisole, 99+%
| 36404-30-5 |
|
d-Valine, 98+%
| 640-68-6 |
|
2,5-Di-Tert-Butylhydroquinone, 99% (Titr.)
| 88-58-4 |
|
1-Iodohexane, 97% (gc)
| 638-45-9 |
|
4-Fluorobenzylamine, 97+%
| 140-75-0 |
|
Trimethylsilylisocyanate, 97%
| 1118-02-1 |
|
alpha-Ethylphenethyl alcohol, 97%
| 701-70-2 |
|
Chromotropic Acid Disodium Salt Dihydrate
| 5808-22-0 |
|
Silver(I) Fluoride, 99+%
| 7775-41-9 |
|
4-Fluorophenoxyacetic acid, 99+%
| 405-79-8 |
|
Propionaldehyde diethyl acetal, 97%
| 4744-08-5 |
|
1-Fluoro-2-iodobenzene, 99%
| 348-52-7 |
|
Methyl 4-Oxo-3-Piperidinecarboxylate Hydrochloride, 98% (TLC)
| 56026-52-9 |
|
10-Chloro-9-Anthraldehyde, 97%
| 10527-16-9 |
|
4-Bromo-2-Methylaniline, 97%
| 583-75-5 |
|
9-Aminoacridine hydrochloride monohydrate, 99+%
| 134-50-9 |
|
4,4'-bis(dimethylamino)benzhydrol, tech., 85% (dry subst.)
| 119-58-4 |
|
Methyl 4-hydroxyphenylacetate, 99%
| 14199-15-6 |
|
|