**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1577-18-0 |Trans-3-Hexenoic Acid | 97 | 216-417-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. The toxicological properties of this substance have not been
fully investigated. May cause systemic effects.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract. The
toxicological properties of this substance have not been fully
investigated. Inhalation may be fatal as a result of spasm,
inflammation, edema of the larynx and bronchi, chemical pneumonitis
and pulmonary edema. Aspiration may lead to pulmonary edema. May
cause systemic effects.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of
water. Vapors may be heavier than air. They can spread along the
ground and collect in low or confined areas. Containers may explode
when heated.
Extinguishing Media:
Water may be ineffective. Use agent most appropriate to extinguish
fire. Cool containers with flooding quantities of water until well
after fire is out. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Absorb spill using
an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Discard contaminated shoes.
Storage:
Keep away from heat, sparks, and flame. Keep container closed when
not in use. Keep under a nitrogen blanket. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1577-18-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless - light yellow
Odor: acetic odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 207 - 209 deg C
Freezing/Melting Point: 11 - 12 deg C
Autoignition Temperature: Not applicable.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: slightly soluble in water
Specific Gravity/Density: .9600g/cm3
Molecular Formula: C2H5CH=CHCH2CO2H
Molecular Weight: 114.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1577-18-0 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Trans-3-Hexenoic Acid -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1577-18-0: No information available.
Canada
CAS# 1577-18-0 is listed on Canada's DSL List.
CAS# 1577-18-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1577-18-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
n-Tridecanoic acid
| 638-53-9 |
|
Ethylidene diacetate, 99%
| 542-10-9 |
|
2-Ethoxynaphthoic acid, 98%
| 2224-00-2 |
|
1,1-Cyclohexanediacetic Acid, 99%
| 4355-11-7 |
|
2,2,4-Trimethyl-1,3-Pentanediol Diisobutyrate, 98% (GC)
| 6846-50-0 |
|
Adenosine 2':3'-Cyclic Monophosphate, Sodium Salt Hydrate
| 37063-35-7 |
|
Diethyl ether-d10, 99 atom% d
| 2679-89-2 |
|
Acetophenone-d8, 99+ atom% D
| 98-86-2 |
|
Normal-heptadecane, 99%
| 629-78-7 |
|
Heptafluoroisopropyl iodide, 99%
| 677-69-0 |
|
Ethyl 5-Chloro-2-Indolecarboxylate, 97%
| 4792-67-0 |
|
Trans-3-Hexenoic Acid, 97%
| 1577-18-0 |
|
1,2,3-Trifluoro-4-nitrobenzene, 97%
| 771-69-7 |
|
Emodin, tech., 95%
| 518-82-1 |
|
Allyl methacrylate, 98%, stabilized with 200 - 250 ppm MEHQ
| 96-05-9 |
|
Ethyl violet, 90% (uv-vis)
| 2390-59-2 |
|
2-(Carboxymethylthio)-4,6-dimethylpyrimidine monohydrate, 99%
| 55749-30-9 |
|
Acid Blue 161
| 6505-92-6 |
|
Pivaloylacetonitrile, 97% (GC)
| 59997-51-2 |
|
Alizarin, 97%
| 72-48-0 |
|
2-Bromopropiophenone, tech. 90-95%
| 2114-00-3 |
|
4-Chloro-3-fluorobenzaldehyde, 98%
| |
|
2,6-Dimethoxybenzonitrile, 97%
| 16932-49-3 |
|
Azobisisobutyronitrile
| 78-67-1 |
|
1,2-Dibromobenzene, 99+%
| 583-53-9 |
|
Benzil monohydrazone, 98%
| 5344-88-7 |
|
2-Amino-2-Methyl-1,3-Propanediol, 99% (Titr.)
| 115-69-5 |
|
N-Benzyl-2-Phenylethylamine, 99%
| 3647-71-0 |
|
Trans-Styrylacetic Acid, 96%
| 1914-58-5 |
|
Delta-Gluconolactone , 99%, Coarse Powder
| 90-80-2 |
|
2-Ethyl-2-(hydroxymethyl)-1,3-propanediol, 98%
| 77-99-6 |
|
1-(2-Aminobenzoyl)-1-Methylhydrazine, 99%
| 0-00-1 |
|
Tetrahydrofuran-d8, 99.5 atom % D
| 109-99-9 |
|
2-Bromophenylacetonitrile, 99+%
| 19472-74-3 |
|
1,2,3,4-Tetrahydro-2-naphthol, 97%
| 530-91-6 |
|
4'-Octyloxyacetophenone, 99.5+%
| 37062-63-8 |
|
1,1'-(Methylenedi-4,1-phenylene)bis- maleimide
| 13676-54-5 |
|
P-Nitroacetophenone, 97%
| 100-19-6 |
|
4-Chloro-tetrafluorothiophenol, 97%
| 0-00-1 |
|
Diethyl Pyrocarbonate, 97% (Titr.)
| 1609-47-8 |
|
cis-2-Hexen-1-ol, 95%
| 928-94-9 |
|
3-Methylcyclohexylamine, 98%, mixture of cis and trans
| 6850-35-7 |
|
Pinacyanol Chloride
| 2768-90-3 |
|
Diphenyl diselenide, 99%
| 1666-13-3 |
|
2-Imidazolidone (Pract)
| 120-93-4 |
|
4-Hydroxyquinazoline, 98%
| 491-36-1 |
|
Rhodium(III) Oxide Hydrate, ca 56% Rh
| 12036-35-0 |
|
2-Chloro-1H-benzimidazole, 97%
| 4857-06-1 |
|
4'-Fluoroacetophenone, 99%
| 403-42-9 |
|
2,5-Dithiobiurea, 99%
| 142-46-1 |
|
|