**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 2679-89-2 |Diethyl ether-d10 | | 220-235-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F+
Risk Phrases: 12 19
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Extremely flammable. May form explosive peroxides.Extremely
flammable.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin irritation. Prolonged and/or repeated contact may
cause defatting of the skin and dermatitis. May be absorbed through
the skin. May cause skin burns.
Ingestion:
Aspiration hazard. Symptoms may include: headache, excitement,
fatigue, nausea, vomiting, stupor, and coma. May cause central
nervous system depression, characterized by excitement, followed by
headache, dizziness, drowsiness, and nausea. Advanced stages may
cause collapse, unconsciousness, coma and possible death due to
respiratory failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause respiratory tract irritation. May cause narcotic
effects in high concentration. May cause respiratory failure
possibly leading to death. May cause seizures and blood
abnormalities.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. Prolonged or repeated exposure can cause psychic
abnormalities such as anxiety, depression and excitability.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Possible aspiration hazard. Get medical aid
immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Extremely
flammable liquid and vapor. Containers may explode in the heat of a
fire. May form explosive peroxides.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Use dry chemical, carbon dioxide, or alcohol-resistant
foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Remove all sources of ignition. Absorb spill using an absorbent,
non-combustible material such as earth, sand, or vermiculite. Do not
use combustible materials such as sawdust.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with skin and eyes. If
peroxide formation is suspected, do not open or move container.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 2679-89-2:
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible.
Skin:
Wear impervious gloves.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: -40 deg C ( -40.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C4D10O
Molecular Weight: 84.20
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Ignition sources, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2679-89-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Diethyl ether-d10 -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
CAS# 60-29-7:
Fish toxicity:
LC50 (96hr) fathead minnow 2600 mg/l
flowthrough bioassay
LC50 (14 day) guppy 2140 mg/l
LC50 (48 hr)
golden orfe 2800 mg/l satic bioassay
Bioaccumulation: Calculated
bioconcentration factor 2.8 indicated that environmental
accumulation is unlikely.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DIETHYL ETHER
Hazard Class: 3
UN Number: 1155
Packing Group: I
IMO
Shipping Name: DIETHYL ETHER
Hazard Class: 3.1
UN Number: 1155
Packing Group: I
RID/ADR
Shipping Name: DIETHYL ETHER
Hazard Class: 3
UN Number: 1155
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F+
Risk Phrases:
R 12 Extremely flammable.
R 19 May form explosive peroxides.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 2679-89-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2679-89-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2679-89-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
n-Tridecanoic acid
| 638-53-9 |
|
Ethylidene diacetate, 99%
| 542-10-9 |
|
2-Ethoxynaphthoic acid, 98%
| 2224-00-2 |
|
1,1-Cyclohexanediacetic Acid, 99%
| 4355-11-7 |
|
2,2,4-Trimethyl-1,3-Pentanediol Diisobutyrate, 98% (GC)
| 6846-50-0 |
|
Adenosine 2':3'-Cyclic Monophosphate, Sodium Salt Hydrate
| 37063-35-7 |
|
Diethyl ether-d10, 99 atom% d
| 2679-89-2 |
|
Acetophenone-d8, 99+ atom% D
| 98-86-2 |
|
Normal-heptadecane, 99%
| 629-78-7 |
|
Heptafluoroisopropyl iodide, 99%
| 677-69-0 |
|
Ethyl 5-Chloro-2-Indolecarboxylate, 97%
| 4792-67-0 |
|
Trans-3-Hexenoic Acid, 97%
| 1577-18-0 |
|
1,2,3-Trifluoro-4-nitrobenzene, 97%
| 771-69-7 |
|
Emodin, tech., 95%
| 518-82-1 |
|
Allyl methacrylate, 98%, stabilized with 200 - 250 ppm MEHQ
| 96-05-9 |
|
Ethyl violet, 90% (uv-vis)
| 2390-59-2 |
|
2-(Carboxymethylthio)-4,6-dimethylpyrimidine monohydrate, 99%
| 55749-30-9 |
|
Acid Blue 161
| 6505-92-6 |
|
Pivaloylacetonitrile, 97% (GC)
| 59997-51-2 |
|
Alizarin, 97%
| 72-48-0 |
|
2-Bromopropiophenone, tech. 90-95%
| 2114-00-3 |
|
4-Chloro-3-fluorobenzaldehyde, 98%
| |
|
2,6-Dimethoxybenzonitrile, 97%
| 16932-49-3 |
|
Azobisisobutyronitrile
| 78-67-1 |
|
1,2-Dibromobenzene, 99+%
| 583-53-9 |
|
Benzil monohydrazone, 98%
| 5344-88-7 |
|
2-Amino-2-Methyl-1,3-Propanediol, 99% (Titr.)
| 115-69-5 |
|
N-Benzyl-2-Phenylethylamine, 99%
| 3647-71-0 |
|
Trans-Styrylacetic Acid, 96%
| 1914-58-5 |
|
Delta-Gluconolactone , 99%, Coarse Powder
| 90-80-2 |
|
2-Ethyl-2-(hydroxymethyl)-1,3-propanediol, 98%
| 77-99-6 |
|
1-(2-Aminobenzoyl)-1-Methylhydrazine, 99%
| 0-00-1 |
|
Tetrahydrofuran-d8, 99.5 atom % D
| 109-99-9 |
|
2-Bromophenylacetonitrile, 99+%
| 19472-74-3 |
|
1,2,3,4-Tetrahydro-2-naphthol, 97%
| 530-91-6 |
|
4'-Octyloxyacetophenone, 99.5+%
| 37062-63-8 |
|
1,1'-(Methylenedi-4,1-phenylene)bis- maleimide
| 13676-54-5 |
|
P-Nitroacetophenone, 97%
| 100-19-6 |
|
4-Chloro-tetrafluorothiophenol, 97%
| 0-00-1 |
|
Diethyl Pyrocarbonate, 97% (Titr.)
| 1609-47-8 |
|
cis-2-Hexen-1-ol, 95%
| 928-94-9 |
|
3-Methylcyclohexylamine, 98%, mixture of cis and trans
| 6850-35-7 |
|
Pinacyanol Chloride
| 2768-90-3 |
|
Diphenyl diselenide, 99%
| 1666-13-3 |
|
2-Imidazolidone (Pract)
| 120-93-4 |
|
4-Hydroxyquinazoline, 98%
| 491-36-1 |
|
Rhodium(III) Oxide Hydrate, ca 56% Rh
| 12036-35-0 |
|
2-Chloro-1H-benzimidazole, 97%
| 4857-06-1 |
|
4'-Fluoroacetophenone, 99%
| 403-42-9 |
|
2,5-Dithiobiurea, 99%
| 142-46-1 |
|
|