**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 6850-35-7 |3-Methylcyclohexylamine, mixture of ci| 98 | 229-940-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 10 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Causes severe burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause cyanosis of the extremities. May cause
skin rash (in milder cases), and cold and clammy skin with cyanosis
or pale color.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the
digestive tract. Ingestion of large amounts may cause CNS
depression. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. Vapors may cause
dizziness or suffocation. May cause systemic effects. May cause
burning sensation, coughing, wheezing, laryngitis, shortness of
breath, headache, nausea, and vomiting.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with sand, dry lime or soda ash and place in
a closed container for disposal. Remove all sources of ignition. Use
a spark-proof tool. Provide ventilation. A vapor suppressing foam
may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Keep away from heat,
sparks and flame. Do not ingest or inhale. Use and store under
nitrogen. Use only in a chemical fume hood. Discard contaminated
shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area. Keep containers tightly
closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 6850-35-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 150 deg C @ 730.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 22 deg C ( 71.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: .8550g/cm3
Molecular Formula: C7H15N
Molecular Weight: 113.20
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Absorbs carbon
dioxide from the air.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Acid anhydrides, acid chlorides, acids, carbon dioxide, strong
oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 6850-35-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-Methylcyclohexylamine, mixture of cis and trans -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S.*
Hazard Class: 3 (8)
UN Number: 2733
Packing Group: II
IMO
Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S.
Hazard Class: 3.2 (8)
UN Number: 2733
Packing Group: II
RID/ADR
Shipping Name: AMINES, FLAMMABLE, CORROSIVE, N.O.S.
Hazard Class: 3
UN Number: 2733
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 10 Flammable.
R 35 Causes severe burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 6850-35-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 6850-35-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6850-35-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
n-Tridecanoic acid
| 638-53-9 |
|
Ethylidene diacetate, 99%
| 542-10-9 |
|
2-Ethoxynaphthoic acid, 98%
| 2224-00-2 |
|
1,1-Cyclohexanediacetic Acid, 99%
| 4355-11-7 |
|
2,2,4-Trimethyl-1,3-Pentanediol Diisobutyrate, 98% (GC)
| 6846-50-0 |
|
Adenosine 2':3'-Cyclic Monophosphate, Sodium Salt Hydrate
| 37063-35-7 |
|
Diethyl ether-d10, 99 atom% d
| 2679-89-2 |
|
Acetophenone-d8, 99+ atom% D
| 98-86-2 |
|
Normal-heptadecane, 99%
| 629-78-7 |
|
Heptafluoroisopropyl iodide, 99%
| 677-69-0 |
|
Ethyl 5-Chloro-2-Indolecarboxylate, 97%
| 4792-67-0 |
|
Trans-3-Hexenoic Acid, 97%
| 1577-18-0 |
|
1,2,3-Trifluoro-4-nitrobenzene, 97%
| 771-69-7 |
|
Emodin, tech., 95%
| 518-82-1 |
|
Allyl methacrylate, 98%, stabilized with 200 - 250 ppm MEHQ
| 96-05-9 |
|
Ethyl violet, 90% (uv-vis)
| 2390-59-2 |
|
2-(Carboxymethylthio)-4,6-dimethylpyrimidine monohydrate, 99%
| 55749-30-9 |
|
Acid Blue 161
| 6505-92-6 |
|
Pivaloylacetonitrile, 97% (GC)
| 59997-51-2 |
|
Alizarin, 97%
| 72-48-0 |
|
2-Bromopropiophenone, tech. 90-95%
| 2114-00-3 |
|
4-Chloro-3-fluorobenzaldehyde, 98%
| |
|
2,6-Dimethoxybenzonitrile, 97%
| 16932-49-3 |
|
Azobisisobutyronitrile
| 78-67-1 |
|
1,2-Dibromobenzene, 99+%
| 583-53-9 |
|
Benzil monohydrazone, 98%
| 5344-88-7 |
|
2-Amino-2-Methyl-1,3-Propanediol, 99% (Titr.)
| 115-69-5 |
|
N-Benzyl-2-Phenylethylamine, 99%
| 3647-71-0 |
|
Trans-Styrylacetic Acid, 96%
| 1914-58-5 |
|
Delta-Gluconolactone , 99%, Coarse Powder
| 90-80-2 |
|
2-Ethyl-2-(hydroxymethyl)-1,3-propanediol, 98%
| 77-99-6 |
|
1-(2-Aminobenzoyl)-1-Methylhydrazine, 99%
| 0-00-1 |
|
Tetrahydrofuran-d8, 99.5 atom % D
| 109-99-9 |
|
2-Bromophenylacetonitrile, 99+%
| 19472-74-3 |
|
1,2,3,4-Tetrahydro-2-naphthol, 97%
| 530-91-6 |
|
4'-Octyloxyacetophenone, 99.5+%
| 37062-63-8 |
|
1,1'-(Methylenedi-4,1-phenylene)bis- maleimide
| 13676-54-5 |
|
P-Nitroacetophenone, 97%
| 100-19-6 |
|
4-Chloro-tetrafluorothiophenol, 97%
| 0-00-1 |
|
Diethyl Pyrocarbonate, 97% (Titr.)
| 1609-47-8 |
|
cis-2-Hexen-1-ol, 95%
| 928-94-9 |
|
3-Methylcyclohexylamine, 98%, mixture of cis and trans
| 6850-35-7 |
|
Pinacyanol Chloride
| 2768-90-3 |
|
Diphenyl diselenide, 99%
| 1666-13-3 |
|
2-Imidazolidone (Pract)
| 120-93-4 |
|
4-Hydroxyquinazoline, 98%
| 491-36-1 |
|
Rhodium(III) Oxide Hydrate, ca 56% Rh
| 12036-35-0 |
|
2-Chloro-1H-benzimidazole, 97%
| 4857-06-1 |
|
4'-Fluoroacetophenone, 99%
| 403-42-9 |
|
2,5-Dithiobiurea, 99%
| 142-46-1 |
|
|