**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1665-00-5 |Dichloromethane-D2 | 100 | 216-776-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 40
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Limited evidence of a carcinogenic effect.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. At high concentrations may cause lacrimation (tearing) and
irritation.
Skin:
May be absorbed through the skin. Causes irritation with burning
pain, itching, and redness. Prolonged exposure may result in skin
burns.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause narcotic effects in high concentration. May cause
dizziness, incoordination, and unconsciousness. Central nervous
system effects may include confusion, ataxia (failure of muscular
coordination), vertigo, tinnitus, weakness, disorientation, lethargy,
drowsiness, and finally coma. May cause blood changes. Overexposure
may cause an increase in carboxyhemoglobin levels in the blood. Can
produce delayed pulmonary edema.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
Prolonged or repeated skin contact may cause dermatitis. May cause
reproductive and fetal effects. Laboratory experiments have resulted
in mutagenic effects. Chronic exposure may cause lung, liver, and
pancreatic tumors. May cause conjunctivitis and/or corneal burns.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors mixed with air in
proper proportion will propagate a flame. Vapors may be heavier than
air. They can spread along the ground and collect in low or confined
areas. Containers may explode when heated. Combustible material; may
burn but does not ignite readily. Will form explosive mixtures in
atmospheres having high oxygen contents.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, or water spray.
For large fires, use dry chemical, carbon dioxide, alcohol-resistant
foam, or water spray. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Loosen closure
cautiously before opening. Avoid breathing dust, vapor, mist, or
gas. Do not get in eyes, on skin, or on clothing. Keep container
tightly closed. Keep away from heat, sparks and flame. Do not ingest
or inhale.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Keep from contact with oxidizing materials. Store in a
cool, dry, well-ventilated area away from incompatible substances.
Keep away from metals. Store below 40C. Keep away from active
metals.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 1665-00-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: ethereal odor - chloroform-like
pH: Not available.
Vapor Pressure: 350 mm Hg @ 20
Viscosity: Not available.
Boiling Point: 40 deg C
Freezing/Melting Point: -97 deg C
Autoignition Temperature: 556 deg C ( 1,032.80 deg F)
Flash Point: Not applicable.
Explosion Limits, lower: 13 vol %
Explosion Limits, upper: 23 vol %
Decomposition Temperature: Not available.
Solubility in water: Moderately soluble in water
Specific Gravity/Density: 1.33 (Water=1)
Molecular Formula: CH2Cl2
Molecular Weight: 84.92
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. May form explosive mixtures in atmospheres
having high oxygen content.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants, active metals.
Incompatibilities with Other Materials:
Strong oxidizing agents, liquid oxygen, nitric acid, potassium,
lithium, sodium, caustics (e.g. ammonia, ammonium hydroxide, calcium
hydroxide, potassium hydroxide, sodium hydroxide),
potassium-tert-butoxide, sodium potassium alloys, powdered aluminum,
Active metals (such as potassium and magnesium)., nitrogen
tetroxide, N-methyl-N-nitososurea + potassium hydroxide, powdered
magnesium.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1665-00-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Dichloromethane-D2 -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Bluegill/Sunfish: 230mg/L; 24H; StaticFish: Fathead Minnow:
196mg/L; 96HThis chemical has a moderate potential to affect some
aquatic organisms. It is resistant to biodegradation, and has a low
potential to persist in the aquatic environment. 96-hr. EC50 (loss of
equilibrium); Fathead minnow: 99mg/L; 96-hr. EC10: 66.3 mg/L.
Bluegill sunfish: 96-hr. LC50=220 mg/L; Water flea: 24-hr. LC50=2270
mg/L; No observed effect level:1550 mg/L.
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DICHLOROMETHANE
Hazard Class: 6.1
UN Number: 1593
Packing Group: III
IMO
Shipping Name: DICHLOROMETHANE
Hazard Class: 6.1
UN Number: 1593
Packing Group: III
RID/ADR
Shipping Name: DICHLOROMETHANE
Hazard Class: 6.1
UN Number: 1593
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 1665-00-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1665-00-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1665-00-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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