**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 97-08-5 |4-Chloro-3-nitrobenzenesulfonyl chlori| 99 | 202-558-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. May cause
systemic effects. May cause burning sensation, coughing, wheezing,
laryngitis, shortness of breath, headache, nausea, and vomiting.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Runoff from
fire control or dilution water may cause pollution.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with sand, dry lime or soda ash and place in
a closed container for disposal. Provide ventilation. Do not get
water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Keep container
tightly closed. Do not get on skin or in eyes. Do not ingest or
inhale. Do not allow contact with water. Discard contaminated shoes.
Keep from contact with moist air and steam.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Corrosives area. Keep containers tightly closed. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 97-08-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: light brown
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 61 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: May decompose.
Specific Gravity/Density: Not available.
Molecular Formula: C6H3Cl2NO4S
Molecular Weight: 256.07
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water. Moisture sensitive.
Conditions to Avoid:
Incompatible materials, moisture, temperatures above 150C, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, moisture, water.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, oxides of
sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 97-08-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Chloro-3-nitrobenzenesulfonyl chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 97-08-5: 2
Canada
CAS# 97-08-5 is listed on Canada's NDSL List.
CAS# 97-08-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 97-08-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Methyl Benzilate, 99%
| 76-89-1 |
|
Methyl (r)-(+)-Lactate
| 17392-83-5 |
|
2-Thiophenecarboxylic acid hydrazide, 97%
| 2361-27-5 |
|
Acetonyltriphenylphosphonium chloride, 99%
| 1235-21-8 |
|
3,5-Dinitro-2-Methylbenzyl Alcohol, 97%
| 80866-93-9 |
|
Sodium perchlorate monohydrate
| 7601-89-0 |
|
Sodium periodate
| 7790-28-5 |
|
2,2,5,5-Tetramethyl-4-Methylene-3-Formyl- Imidazolidine-1-Oxyl, Free
| 82814-77-5 |
|
Sucrose Diacetate Hexaisobutyrate (Pract)
| 126-13-6 |
|
Sodium peroxide
| 1310-73-2 |
|
Sodium phosphate dibasic heptahydrate
| 7558-79-4 |
|
Dichloromethane-D2, 100.0 Atom % D
| 1665-00-5 |
|
6-Hydroxydopamine hydrobromide, 99%
| 636-00-0 |
|
Hepta-O-Acetyl-Cellobiosyl-Betha-Azide, 99%
| 33012-50-9 |
|
4-Fluorophenyl isocyanate, 99%
| 1195-45-5 |
|
Potassium Sodium Tartrate Tetrahydrate
| 6381-59-5 |
|
3,4-Dihydroxycinnamic acid, 99+%, predominantly trans isomer
| 331-39-5 |
|
Sodium Pyrophosphate Decahydrate
| 7722-88-5 |
|
Sodium Salicylate
| 54-21-7 |
|
Paraldehyde, 99.5% (gc)
| 123-63-7 |
|
4-Chloro-3-nitrobenzenesulfonyl chloride, 99% (titr.)
| 97-08-5 |
|
8-Hydroxyquinoline-N-oxide, 99%
| 1127-45-3 |
|
3-Bromo-4-Fluorobenzaldehyde, 99%
| 77771-02-9 |
|
1,2:5,6-Di-O-Cyclohexylidene-3-Cyano-Alpha -D-Allofuranose, 93%
| 62293-19-0 |
|
Trans-2-Hexenal, 99%
| 6728-26-3 |
|
Sodium Succinate Hexahydrate
| 6106-21-4 |
|
Sodium sulfate anhydrous
| 7757-82-6 |
|
1-(3-Methoxyphenyl)-piperazine dihydrochloride, 98%
| 6968-76-9 |
|
Sodium Sulfide Nonahydrate
| 1313-82-2 |
|
Glyoxalbis-(2-Hydroxyanil), P.A.
| 1149-16-2 |
|
4'-Methoxyacetophenone, 98%
| 100-06-1 |
|
Sodium Sulfite, Anhydrous
| 7757-83-7 |
|
Quinoline Yellow, Water Soluble
| 8004-92-0 |
|
Sodium L-(+)-tartrate dihydrate
| 868-18-8 |
|
2,5-Dimethylbenzoxazole, 99%
| 5676-58-4 |
|
1-Phenyldodecane, 97%
| 123-01-3 |
|
Sodium Tetraphenyl Boron
| 143-66-8 |
|
Sodium thiocyanate
| 540-72-7 |
|
2,6-Diiodo-4-Nitroaniline, 97%
| 5398-27-6 |
|
Linalool, 97%
| 78-70-6 |
|
Sodium Thiosulfate Anhydrous
| 7772-98-7 |
|
Sodium Thiosulfate Pentahydrate
| 10102-17-7 |
|
Phenoxyacetyl chloride, 98%
| 701-99-5 |
|
2,3:5,6-Di-O-Cyclohexylidene-D-Mannolactone, 98%
| 0-00-1 |
|
Palmitic acid sodium salt, 98%
| 408-35-5 |
|
Diazo Red RC
| 4274-03-7 |
|
Sodium tungstate dihydrate
| 10213-10-2 |
|
Biuret, 99%
| 108-19-0 |
|
5-Chlorobenzotriazole, 99%
| 94-97-3 |
|
Ethyl cyanoformate, 99%
| 623-49-4 |
|
|