**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 2638-94-0 |4,4'-Azobis(4-cyanovaleric acid) | 70% | 220-135-0 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 30% | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.Light sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable solid.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Remove all sources of ignition. Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from sources of ignition. Do not store in direct sunlight.
Store in a tightly closed container. Store in a dry area.
Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Exposure Limits
CAS# 2638-94-0:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white to light yellow
Odor: Not available.
pH: 2.5 - 3.5
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 110 - 120 deg C(dec.)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C12H16N4O4
Molecular Weight: 280.28
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
May decompose when exposed to light.
Conditions to Avoid:
Incompatible materials, light, ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 2638-94-0: YV6190500
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
4,4'-Azobis(4-cyanovaleric acid) -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.*
Hazard Class: 4.1
UN Number: 1325
Packing Group: II
IMO
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE SOLID, ORGANIC, N.O.S.
Hazard Class: 4.1
UN Number: 1325
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 2638-94-0: No information available.
CAS# 7732-18-5: No information available.
Canada
CAS# 2638-94-0 is listed on Canada's NDSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 2638-94-0 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2638-94-0 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/20/2004 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N-Phenylbis(trifluoromethane)sulfonimide, 97%
| 37595-74-7 |
|
4-Methoxy-M-Phenylenediamine Sulfate Hydrate, 98%
| 39156-41-7 |
|
mono-Methyl phthalate, 98%
| 4376-18-5 |
|
3-Bromobutyric acid, 97%
| 2623-86-1 |
|
n-Nonyltriphenylphosphonium bromide
| 60902-45-6 |
|
5-Bromo-4-chloro-3-indoxyl-??-D-fucopyranoside, 99%
| 17016-46-5 |
|
5-Isopropyl-2-methylphenol
| 499-75-2 |
|
9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene, 98%
| 161265-03-8 |
|
1-(4-Hydroxy-3-hydroxymethylphenyl)-2-(tert-butylbenzylamino)ethanol
| 24085-03-8 |
|
2-Ethyl-4-methylimidazole, 85%
| 616-47-7 |
|
3-Methylsulfolane
| 872-93-5 |
|
Cyclohexylmagnesium chloride, 1.3M solution in THF/toluene
| 108-88-3 |
|
Para red, dye content ca. 95%
| 6410-10-2 |
|
4-Chlorophenylmagnesium bromide, 0.9M solution in THF/toluene
| 108-88-3 |
|
4-Fluorophenylmagnesium bromide, 0.8M solution in THF
| 109-99-9 |
|
Diethylaluminiumchloride, 1.1M solution in toluene
| 96-10-6 |
|
Dimethylzinc, 1.2M solution in toluene
| 108-88-3 |
|
Lithium aluminium hydride, 2.4M solution in THF
| 109-99-9 |
|
Allylmagnesium chloride, 1.7M solution in THF
| 109-99-9 |
|
Tri-n-hexylaluminium, 0.4M in hexane
| 110-54-3 |
|
Diethylaluminium ethoxide, 1.3M solution in hexane
| 110-54-3 |
|
Methylmagnesium bromide, 1.7M solution in toluene/THF
| 75-16-1 |
|
Isopropylmagnesium chloride, 2.0M solution in THF
| 109-99-9 |
|
4,4'-Azobis(4-cyanovaleric acid), moistened with ca. 30% water, 97%
| 2638-94-0 |
|
3-Chloro-5-fluorobenzyl bromide, 97%
| 493024-39-8 |
|
3-Chloro-5-fluorobenzyl alcohol, 99%
| 79944-64-2 |
|
5-(4-Bromophenyl)furfural, 97%
| 20005-42-9 |
|
(s)-Glycidol
| 60456-23-7 |
|
5-(4-Nitrophenyl)furfural, 98%
| 7147-77-5 |
|
4-(1H-Pyrrol-1-yl)phenol, 97%
| 23351-09-9 |
|
2,2,5,5-Tetrakis(chloromethyl)cyclopentanone
| 67059-01-2 |
|
2,2,5,5-Tetrakis(hydroxymethyl)cyclopentanone
| 3322-70-1 |
|
Bis(trimethylsilyl)carbodiimide, 98%
| 1000-70-0 |
|
3-Methylbenzofuran-2-carbonyl chloride, 97%
| 2256-86-2 |
|
Metergoline
| 17692-51-2 |
|
3-Chloro-5-fluorobenzoic acid, 97%
| 25026-64-6 |
|
3-Chloro-5-fluorophenylacetic acid
| 202001-00-1 |
|
4-Fluoro-3-methylbenzaldehyde
| 135427-08-6 |
|
3-Chloro-5-fluorobenzaldehyde, 97%
| 90390-49-1 |
|
3-Chloro-2-fluorobenzaldehyde, 97%
| 85070-48-0 |
|
4-Fluoro-2-(trifluoromethyl)benzylamine
| 202522-22-3 |
|
4-Fluoro-3-(trifluoromethyl)benzylamine
| 67515-74-6 |
|
3-Chloro-5-fluoroaniline, 97%
| 4863-91-6 |
|
3-Fluoro-4-methoxyaniline, 99%
| 366-99-4 |
|
5-Fluoro-2-methylphenyl isocyanate, 97%
| 67191-93-9 |
|
1-(4-Fluorobenzyl)piperazine, 98%
| 70931-28-1 |
|
2,4,5-Trifluorobenzoic acid, 99.5+%
| 446-17-3 |
|
3-Chloro-5-fluorobenzonitrile, 98%
| 327056-73-5 |
|
3-Chloro-5-fluorophenyl acetonitrile, 98%
| 493038-93-0 |
|
Ethylenediamine Anhydrous
| 107-15-3 |
|
|