**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 60456-23-7 |(S)-Glycidol | | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 21/22 23 36/37/38 42/43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin and if swallowed. Toxic by inhalation.
Irritating to eyes, respiratory system and skin. May cause
sensitization by inhalation and skin contact.
Potential Health Effects
The toxicological properties of this material have not been
investigated. Use appropriate procedures to prevent opportunities
for direct contact with the skin or eyes and to prevent inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid
ingestion and inhalation.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Deep freeze (below -20C).
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits. Use process
enclosure, local exhaust ventilation, or other engineering controls
to control airborne levels.
Exposure Limits
CAS# 60456-23-7:
Personal Protective Equipment
Eyes:
Wear safety glasses and chemical goggles if splashing
is possible.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: none reported
pH: Not available.
Vapor Pressure: 20 mm Hg @ 52 C
Viscosity: Not available.
Boiling Point: 149 deg C
Freezing/Melting Point: 0 deg C
Autoignition Temperature: Not available.
Flash Point: 178 deg F ( 81.11 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.1100g/cm3
Molecular Formula: C3H6O2
Molecular Weight: 74.08
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases.
Hazardous Polymerization: Will occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 60456-23-7: RR0508100
LD50/LC50:
Not available.
Carcinogenicity:
(S)-Glycidol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 21/22 Harmful in contact with skin and if
swallowed.
R 23 Toxic by inhalation.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 60456-23-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 60456-23-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 60456-23-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #3 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N-Phenylbis(trifluoromethane)sulfonimide, 97%
| 37595-74-7 |
|
4-Methoxy-M-Phenylenediamine Sulfate Hydrate, 98%
| 39156-41-7 |
|
mono-Methyl phthalate, 98%
| 4376-18-5 |
|
3-Bromobutyric acid, 97%
| 2623-86-1 |
|
n-Nonyltriphenylphosphonium bromide
| 60902-45-6 |
|
5-Bromo-4-chloro-3-indoxyl-??-D-fucopyranoside, 99%
| 17016-46-5 |
|
5-Isopropyl-2-methylphenol
| 499-75-2 |
|
9,9-Dimethyl-4,5-bis(diphenylphosphino)xanthene, 98%
| 161265-03-8 |
|
1-(4-Hydroxy-3-hydroxymethylphenyl)-2-(tert-butylbenzylamino)ethanol
| 24085-03-8 |
|
2-Ethyl-4-methylimidazole, 85%
| 616-47-7 |
|
3-Methylsulfolane
| 872-93-5 |
|
Cyclohexylmagnesium chloride, 1.3M solution in THF/toluene
| 108-88-3 |
|
Para red, dye content ca. 95%
| 6410-10-2 |
|
4-Chlorophenylmagnesium bromide, 0.9M solution in THF/toluene
| 108-88-3 |
|
4-Fluorophenylmagnesium bromide, 0.8M solution in THF
| 109-99-9 |
|
Diethylaluminiumchloride, 1.1M solution in toluene
| 96-10-6 |
|
Dimethylzinc, 1.2M solution in toluene
| 108-88-3 |
|
Lithium aluminium hydride, 2.4M solution in THF
| 109-99-9 |
|
Allylmagnesium chloride, 1.7M solution in THF
| 109-99-9 |
|
Tri-n-hexylaluminium, 0.4M in hexane
| 110-54-3 |
|
Diethylaluminium ethoxide, 1.3M solution in hexane
| 110-54-3 |
|
Methylmagnesium bromide, 1.7M solution in toluene/THF
| 75-16-1 |
|
Isopropylmagnesium chloride, 2.0M solution in THF
| 109-99-9 |
|
4,4'-Azobis(4-cyanovaleric acid), moistened with ca. 30% water, 97%
| 2638-94-0 |
|
3-Chloro-5-fluorobenzyl bromide, 97%
| 493024-39-8 |
|
3-Chloro-5-fluorobenzyl alcohol, 99%
| 79944-64-2 |
|
5-(4-Bromophenyl)furfural, 97%
| 20005-42-9 |
|
(s)-Glycidol
| 60456-23-7 |
|
5-(4-Nitrophenyl)furfural, 98%
| 7147-77-5 |
|
4-(1H-Pyrrol-1-yl)phenol, 97%
| 23351-09-9 |
|
2,2,5,5-Tetrakis(chloromethyl)cyclopentanone
| 67059-01-2 |
|
2,2,5,5-Tetrakis(hydroxymethyl)cyclopentanone
| 3322-70-1 |
|
Bis(trimethylsilyl)carbodiimide, 98%
| 1000-70-0 |
|
3-Methylbenzofuran-2-carbonyl chloride, 97%
| 2256-86-2 |
|
Metergoline
| 17692-51-2 |
|
3-Chloro-5-fluorobenzoic acid, 97%
| 25026-64-6 |
|
3-Chloro-5-fluorophenylacetic acid
| 202001-00-1 |
|
4-Fluoro-3-methylbenzaldehyde
| 135427-08-6 |
|
3-Chloro-5-fluorobenzaldehyde, 97%
| 90390-49-1 |
|
3-Chloro-2-fluorobenzaldehyde, 97%
| 85070-48-0 |
|
4-Fluoro-2-(trifluoromethyl)benzylamine
| 202522-22-3 |
|
4-Fluoro-3-(trifluoromethyl)benzylamine
| 67515-74-6 |
|
3-Chloro-5-fluoroaniline, 97%
| 4863-91-6 |
|
3-Fluoro-4-methoxyaniline, 99%
| 366-99-4 |
|
5-Fluoro-2-methylphenyl isocyanate, 97%
| 67191-93-9 |
|
1-(4-Fluorobenzyl)piperazine, 98%
| 70931-28-1 |
|
2,4,5-Trifluorobenzoic acid, 99.5+%
| 446-17-3 |
|
3-Chloro-5-fluorobenzonitrile, 98%
| 327056-73-5 |
|
3-Chloro-5-fluorophenyl acetonitrile, 98%
| 493038-93-0 |
|
Ethylenediamine Anhydrous
| 107-15-3 |
|
|