**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 32780-06-6 |(S)-??5-Hydroxymethyl-??5-butyrolactone | 97% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas. Runoff
from fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Use with adequate ventilation. Wash clothing before
reuse.
Storage:
Store in a tightly closed container. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 32780-06-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: pale yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 110 - 115 deg C @ 2.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible with water
Specific Gravity/Density: 1.2370g/cm3
Molecular Formula: C5H8O3
Molecular Weight: 116.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 32780-06-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(S)-??5-Hydroxymethyl-??5-butyrolactone -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 32780-06-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 32780-06-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 32780-06-6 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/25/1999 Revision #3 Date: 1/14/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ninhydrin, reagent ACS
| 485-47-2 |
|
p-Nitrophenyl-alpha-D-Maltoside Hydrate, 99%
| 17400-77-0 |
|
Molybdenum(VI) oxide
| 1313-27-5 |
|
4-Nitrophenyl-alpha-D-Galactopyranoside.
| 7493-95-0 |
|
4-Methylumbelliferylphosphate disodium salt trihydrate, 99%
| 22919-26-2 |
|
4-Methylumbelliferyl palmitate, 99%
| 17695-48-6 |
|
Sodium cyanoborodeuteride, 98 atom % d
| 25895-62-9 |
|
Tetrabromo-O-Sulfobenzoic Acid Cyclic Anhydride, 95%
| 68460-01-5 |
|
4-Methylumbelliferyl-beta-D-glucopyranoside, 99%
| 18997-57-4 |
|
Sodium phosphate, monobasic monohydrate, reagent ACS (crystals)
| 7558-80-7 |
|
Methyl-alpha-D-galacatopyranoside, 98+%
| 3396-99-4 |
|
Morpholine, Reagent ACS, 99+% (Titr.)
| 110-91-8 |
|
N-Acetyl-L-Cysteine, 98%
| 616-91-1 |
|
N-Amyl Acetate, P.A.
| 628-63-7 |
|
1-Pentanol, 99%
| 71-41-0 |
|
(2-Hydroxyethyl)triphenylphosphonium chloride, 98%
| 23250-03-5 |
|
3-Indoxyl sulfate potassium salt
| 2642-37-7 |
|
Indoxyl-beta-D-glucuronide cyclohexylammonium salt
| 35804-66-1 |
|
n-Butyl acetate, spectrophotometric grade, 99+%
| 123-86-4 |
|
alpha-D-Galactose 1-phosphate dipotassium salt pentahydrate
| 19046-60-7 |
|
Glycine-7-amido-4-methylcoumarin hydrobromide
| 113728-13-5 |
|
N-Acetyl-L-tyrosine ethyl ester monohydrate, 99%
| 840-97-1 |
|
5-Bromo-6-Chloro-3-Indolyl-Beta-D-Galactopyranoside
| 93863-88-8 |
|
5-Bromo-4-Chloro-3-Indolyl-Beta-D-Glucuronide Cyclohexylammonium Salt
| 18656-96-7 |
|
5-Bromo-6-Chloro-3-Indolyl Phosphate p-Toluidine Salt
| 6769-80-8 |
|
L-Alanine-4-Methyl-7-Coumarinylamide Trifluoroacetate
| 96594-10-4 |
|
4-Methylumbelliferyl-alpha-D-glucopyranoside hydrate, 99%
| 17833-43-1 |
|
(S)-(+)-gamma-(Trityloxymethyl)-gamma-butyrolactone, 96%
| 73968-62-4 |
|
(R)-(+)-alpha, alpha-Diphenyl-2-pyrrolidinemethanol, 98%
| 22348-32-9 |
|
(R)-(+)-2-Hydroxy-1,2,2-triphenylethyl acetate, 99%
| 95061-47-5 |
|
(S)-(-)-2-Hydroxy-1,2,2-triphenylethyl acetate, 99%
| 95061-51-1 |
|
(-)-Bis[(S)-1-phenylethyl]amine hydrochloride, 99%
| 40648-92-8 |
|
1-Butanol, reagent ACS, 99.4%
| 71-36-3 |
|
(4S,5R)-(-)-4-Methyl-5-phenyl-2-oxazolidinone, 99%
| 16251-45-9 |
|
1-Bromobutane, 99+%
| 109-65-9 |
|
(4R,5S)-(+)-4-Methyl-5-phenyl-2-oxazolidinone, 99%
| 77943-39-6 |
|
(S)-??5-Hydroxymethyl-??5-butyrolactone, 97%
| 32780-06-6 |
|
(R)-(-)-O-ACETYLMANDELIC ACID, 99%
| 51019-43-3 |
|
N-Isopropylethylenediamine, 98%
| 19522-67-9 |
|
Ammonium Acetate
| 631-61-8 |
|
(1R,2R)-trans-1,2-Cyclohexanediol, 98%
| 1072-86-2 |
|
1-Chlorobutane, Sequenation Grade
| 109-69-3 |
|
(1S,2S)-trans-1,2-Cyclohexanediol, 98%
| 57794-08-8 |
|
Normal-Butylamine, P.A.
| 109-73-9 |
|
Decane, 99+%
| 124-18-5 |
|
Ethyl Chlorothiolformate, 97+%
| 2941-64-2 |
|
Triisopropylnaphthalenesulfonic Acid Sodium Salt (pract), 90%
| 1323-19-9 |
|
n-Ethylmaleimide, 99+%
| 128-53-0 |
|
(+)-Bis[(R)-1-phenylethyl]amine hydrochloride, 99%
| 82398-30-9 |
|
(R)-(+)-N-Benzyl-1-phenylethylamine hydrochloride, 99%
| 128593-66-8 |
|
|