**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 38701-74-5 |1,1,1,3,3,3-Hexafluoroisopropanol-d2, | 99+% | 254-091-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause eye injury.
Skin:
Causes skin irritation.
Ingestion:
May cause central nervous system depression, kidney damage, and
liver damage. Symptoms may include: headache, excitement, fatigue,
nausea, vomiting, stupor, and coma. May cause gastrointestinal
irritation with nausea, vomiting and diarrhea. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause irritation of the respiratory tract with burning
pain in the nose and throat, coughing, wheezing, shortness of breath
and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is noncombustible.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 38701-74-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 59 deg C @ 760.00mm Hg
Freezing/Melting Point: -4 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.6460g/cm3
Molecular Formula: C3D2F6O
Molecular Weight: 166.02
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 38701-74-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,1,1,3,3,3-Hexafluoroisopropanol-d2, 99+ atom% D -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 38701-74-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 38701-74-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 38701-74-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,2,6,6-Tetramethyl-4-Piperidinol, 99%
| 2403-88-5 |
|
S-(+)-2-Pentanol, 98+%
| 26184-62-3 |
|
5-Amino-1,3,4-thiadiazole-2-thiol, 98%
| 2349-67-9 |
|
Tetrabromophenolphthalein Ethyl Ester, Reagent ACS, 95+% (UV-VIS)
| 1176-74-5 |
|
1,1,1,3,3,3-Hexafluoroisopropanol-d2, 99+ atom% d
| 38701-74-5 |
|
4-(Trifluoromethoxy)benzoic acid, 99% (titr.)
| 330-12-1 |
|
Digoxin, 95.0 to 101.0% (HPLC), Calculated on a Dry Basis
| 20830-75-5 |
|
6-Azauracil, 99%
| 461-89-2 |
|
5-Azacytidine, 99%
| 320-67-2 |
|
6-Undecanone, 97%
| 927-49-1 |
|
2-Nitrosotoluene, 97%
| 611-23-4 |
|
Guanidine sulfate, 99%
| 593-87-3 |
|
5-Bromosalicylic Acid, 98%
| 89-55-4 |
|
n-Ethylhydroxylamine hydrochloride,97%
| 42548-78-7 |
|
2,3,4,6-Tetra-o-acetyl-betha-d-glucopyranosyl azide, 98%
| 13992-25-1 |
|
Silver chromate, 99%
| 7784-01-2 |
|
1,2-O-Cyclohexylidene-3-O-Methyl-Alpha-D-Glucofuranose, 98%
| 13322-87-7 |
|
5-Bromo-2'-Deoxyuridine, 99+%
| 59-14-3 |
|
2-Chloro-4'-fluoroacetophenone, 99%
| 456-04-2 |
|
Furfuryl acetate, 99%
| 623-17-6 |
|
1,5-Anhydro-3,4,6-Tri-O-Benzyl-2-Deoxy-D-Arabinohex-1-Enitol, 99+%
| 55628-54-1 |
|
Chlorodiphenylmethane, 98%
| 90-99-3 |
|
Diethylbenzene (Techn), 90% (GC)
| 7732-18-5 |
|
2,5-Dimethoxy-4-Nitroaniline, 98+%
| 6313-37-7 |
|
7-Amino-1,3-Naphthalenedisulfonic Acid, Tech.
| 86-65-7 |
|
1,7-Diaza-12-Crown-4, 98%
| 294-92-8 |
|
n-Acetylneuraminic acid
| 131-48-6 |
|
4-Methylsulphonylbenzenesulphonyl Chloride 95%
| 82964-91-8 |
|
1,4-Naphthoquinone, 99% (UV-Vis)
| 130-15-4 |
|
Triacetin, 99%
| 102-76-1 |
|
Methyl 4-Nitrobenzoate, 99+%
| 619-50-1 |
|
Lauryl methacrylate, 65%
| 142-90-5 |
|
Palatine Fast Black Wan
| 5610-64-0 |
|
Benzyl carbamate, 99%
| 621-84-1 |
|
2,2-Diethoxyacetophenone, 98%
| 6175-45-7 |
|
2-Isopropenylaniline, 98+%
| 52562-19-3 |
|
5-Methylsalicylic acid, 98%
| 89-56-5 |
|
(2R,3S)-1-Carboxy-4-Isopropyl-2,3-Dihydroxycyclohexa-4,6-Diene,
| 0-01-1 |
|
Glycinamide Hydrochloride, 98%
| 1668-10-6 |
|
L-(+)-Gulose, 98%
| 6027-89-0 |
|
2'-Chloroacetanilide, 99+%
| 533-17-5 |
|
2-Chloro-3,5-Dibromo-1-Fluorobenzene, 98%
| 0-00-1 |
|
p-Toluidine
| 106-49-0 |
|
DL-5-Methyltryptophan, 98%
| 951-55-3 |
|
Methyl disulfide, p.a.
| 624-92-0 |
|
2-Chloroadenosine hemihydrate, 97%
| 146-77-0 |
|
Diphenylacetonitrile, 99+%
| 86-29-3 |
|
1,4-Di-tert-butylbenzene, 99%
| 1012-72-2 |
|
2-Nitrobenzamide, 98%
| 610-15-1 |
|
Tetrakis(dimethylamino)ethylene, 98%
| 996-70-3 |
|
|