**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 52562-19-3 |2-Isopropenylaniline | 98+ | 258-008-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and in contact with skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause cardiac disturbances. May cause
methemoglobinemia, cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), convulsions, and death. The
toxicological properties of this substance have not been fully
investigated. May cause central nervous system depression.
Inhalation:
May cause respiratory tract irritation. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), convulsions, tachycardia, dyspnea (labored breathing),
and death. The toxicological properties of this substance have not
been fully investigated. Aspiration may lead to pulmonary edema. May
cause cardiac abnormalities. Inhalation at high concentrations may
cause CNS depression and asphixiation.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death. Effects
may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 52562-19-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear slightly yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 95 deg C @ 13.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 78 deg C ( 172.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9780g/cm3
Molecular Formula: C9H11N
Molecular Weight: 133.19
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, chloroformates, acids, acid chlorides, acid
anhydrides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 52562-19-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Isopropenylaniline -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21 Harmful by inhalation and in contact with
skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
WGK (Water Danger/Protection)
CAS# 52562-19-3: No information available.
Canada
CAS# 52562-19-3 is listed on Canada's NDSL List.
CAS# 52562-19-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 52562-19-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,2,6,6-Tetramethyl-4-Piperidinol, 99%
| 2403-88-5 |
|
S-(+)-2-Pentanol, 98+%
| 26184-62-3 |
|
5-Amino-1,3,4-thiadiazole-2-thiol, 98%
| 2349-67-9 |
|
Tetrabromophenolphthalein Ethyl Ester, Reagent ACS, 95+% (UV-VIS)
| 1176-74-5 |
|
1,1,1,3,3,3-Hexafluoroisopropanol-d2, 99+ atom% d
| 38701-74-5 |
|
4-(Trifluoromethoxy)benzoic acid, 99% (titr.)
| 330-12-1 |
|
Digoxin, 95.0 to 101.0% (HPLC), Calculated on a Dry Basis
| 20830-75-5 |
|
6-Azauracil, 99%
| 461-89-2 |
|
5-Azacytidine, 99%
| 320-67-2 |
|
6-Undecanone, 97%
| 927-49-1 |
|
2-Nitrosotoluene, 97%
| 611-23-4 |
|
Guanidine sulfate, 99%
| 593-87-3 |
|
5-Bromosalicylic Acid, 98%
| 89-55-4 |
|
n-Ethylhydroxylamine hydrochloride,97%
| 42548-78-7 |
|
2,3,4,6-Tetra-o-acetyl-betha-d-glucopyranosyl azide, 98%
| 13992-25-1 |
|
Silver chromate, 99%
| 7784-01-2 |
|
1,2-O-Cyclohexylidene-3-O-Methyl-Alpha-D-Glucofuranose, 98%
| 13322-87-7 |
|
5-Bromo-2'-Deoxyuridine, 99+%
| 59-14-3 |
|
2-Chloro-4'-fluoroacetophenone, 99%
| 456-04-2 |
|
Furfuryl acetate, 99%
| 623-17-6 |
|
1,5-Anhydro-3,4,6-Tri-O-Benzyl-2-Deoxy-D-Arabinohex-1-Enitol, 99+%
| 55628-54-1 |
|
Chlorodiphenylmethane, 98%
| 90-99-3 |
|
Diethylbenzene (Techn), 90% (GC)
| 7732-18-5 |
|
2,5-Dimethoxy-4-Nitroaniline, 98+%
| 6313-37-7 |
|
7-Amino-1,3-Naphthalenedisulfonic Acid, Tech.
| 86-65-7 |
|
1,7-Diaza-12-Crown-4, 98%
| 294-92-8 |
|
n-Acetylneuraminic acid
| 131-48-6 |
|
4-Methylsulphonylbenzenesulphonyl Chloride 95%
| 82964-91-8 |
|
1,4-Naphthoquinone, 99% (UV-Vis)
| 130-15-4 |
|
Triacetin, 99%
| 102-76-1 |
|
Methyl 4-Nitrobenzoate, 99+%
| 619-50-1 |
|
Lauryl methacrylate, 65%
| 142-90-5 |
|
Palatine Fast Black Wan
| 5610-64-0 |
|
Benzyl carbamate, 99%
| 621-84-1 |
|
2,2-Diethoxyacetophenone, 98%
| 6175-45-7 |
|
2-Isopropenylaniline, 98+%
| 52562-19-3 |
|
5-Methylsalicylic acid, 98%
| 89-56-5 |
|
(2R,3S)-1-Carboxy-4-Isopropyl-2,3-Dihydroxycyclohexa-4,6-Diene,
| 0-01-1 |
|
Glycinamide Hydrochloride, 98%
| 1668-10-6 |
|
L-(+)-Gulose, 98%
| 6027-89-0 |
|
2'-Chloroacetanilide, 99+%
| 533-17-5 |
|
2-Chloro-3,5-Dibromo-1-Fluorobenzene, 98%
| 0-00-1 |
|
p-Toluidine
| 106-49-0 |
|
DL-5-Methyltryptophan, 98%
| 951-55-3 |
|
Methyl disulfide, p.a.
| 624-92-0 |
|
2-Chloroadenosine hemihydrate, 97%
| 146-77-0 |
|
Diphenylacetonitrile, 99+%
| 86-29-3 |
|
1,4-Di-tert-butylbenzene, 99%
| 1012-72-2 |
|
2-Nitrobenzamide, 98%
| 610-15-1 |
|
Tetrakis(dimethylamino)ethylene, 98%
| 996-70-3 |
|
|