**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 40635-66-3 |Alpha-Acetoxy-Isobutyryl Chloride | 97 | 255-016-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. May cause chemical conjunctivitis and corneal damage.
Skin:
May cause severe irritation and possible burns. May cause irritation
and dermatitis. May cause cyanosis of the extremities. May cause skin
rash (in milder cases), and cold and clammy skin with cyanosis or
pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. May
cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Causes gastrointestinal tract burns. May cause perforation
of the digestive tract. May cause systemic effects.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract. Aspiration may lead to
pulmonary edema. May cause systemic effects. Inhalation at high
concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Do not get on
skin or in eyes. Do not ingest or inhale. Use with adequate
ventilation. Do not allow contact with water. Discard contaminated
shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames. Keep from
contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
refrigerated. (Store below 4C/39F.) Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 40635-66-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: chlorine-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 55.0 - 56.0 deg C @ 6.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 68 deg C ( 154.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density: 1.1360g/cm3
Molecular Formula: C6H9ClO3
Molecular Weight: 164.59
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, chloride fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 40635-66-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Alpha-Acetoxy-Isobutyryl Chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 40635-66-3: 2
Canada
CAS# 40635-66-3 is listed on Canada's DSL List.
CAS# 40635-66-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 40635-66-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #6 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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Allyltriphenylphosphonium bromide, 99%
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m-Anisidine
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Glycerol formal, mixture of alpha- and beta form, 99+%
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4-Amino-2,3,5,6-tetrafluorobenzamide, 97%
| 1548-74-9 |
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(2-Aminobenzoyl)hydrazide, 97%
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2-Isobutyl-3-methoxypyrazine, 99% (GC)
| 24683-00-9 |
|
Trichloroacetic acid, sodium salt, 99%
| 650-51-1 |
|
1-Bromoundecane (Pract), 97% (GC)
| 693-67-4 |
|
Coumarin 2, Laser Grade, 99+% (UV-Vis)
| 26078-25-1 |
|
Methyl 2-chloroacetoacetate, 95%
| 4755-81-1 |
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[(4-Fluorophenoxy)methyl]oxirane, 97%
| 108648-25-5 |
|
3,3-Dimethylacrylic Acid, 97%
| 541-47-9 |
|
N-Tert-Butylacrylamide
| 107-58-4 |
|
Decahydro-2-naphthol, 98%, Mixture of isomers
| 825-51-4 |
|
2,3-Quinoxalinedithiol
| 1199-03-7 |
|
Fast Blue BB, 98%
| 120-00-3 |
|
2,5-Dibromopyridine, 97%
| 624-28-2 |
|
Chlorophenol Red, Indicator Grade
| 4430-20-0 |
|
Lithium stearate, 95%
| 4485-12-5 |
|
Isobutyric Acid, P.A.
| 79-31-2 |
|
(2,2-Dichlorocyclopropyl)benzene, 97%
| 2415-80-7 |
|
P-Toluenesulfonamide
| 70-55-3 |
|
Benzalphthalide, 98%
| 575-61-1 |
|
Alpha-Bromo-2'- Acetonaphthone, 98%
| 613-54-7 |
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D-(+)-Digitoxose, 99+%
| 527-52-6 |
|
(S)-(+)-2-Hydroxy-3-methylbutanoic acid, 99+%
| 17407-55-5 |
|
Methyl formate, spectro grade, 98%
| 107-31-3 |
|
5,6,11,12-Tetrahydrodibenz(b,f)Azocin-- 6-One
| 6047-29-6 |
|
Bis(cyclopentadienyl)zirconium dichloride, 98+%
| 1291-32-3 |
|
4-Oxo-3-Aza-Tricyclo-(4.2.1.0(2,5))Nonane, 99+%
| 0-01-1 |
|
2-Nitrobenzoyl Chloride, 95%
| 610-14-0 |
|
Chrysanthemyl alcohol, 98%, mixture of cis and trans
| 18383-59-0 |
|
2-Nitrobenzenesulfonamide, 96%
| 5455-59-4 |
|
(R)-3-Isopropyl-2,5-Piperazinedione
| 143673-66-9 |
|
2,2'-Azodiphenol, 99% (UV-Vis)
| 2050-14-8 |
|
Coronene
| 191-07-1 |
|
Alpha, Alpha, Alpha-Trifluoro-O-Tolyl Isocyanate, 97%
| 2285-12-3 |
|
Isovaleryl Chloride, 98%
| 108-12-3 |
|
2-(4-Tolyl)malondialdehyde, 97% (GC)
| 27956-35-0 |
|
4-Nitrobenzoic acid, 99+%
| 62-23-7 |
|
1,2,3-Trichlorobenzene, 99%
| 87-61-6 |
|
Phenyl N-Phenylphosphoramidochloridate, 99+%
| 51766-21-3 |
|
Alpha-Acetoxy-Isobutyryl Chloride, 97%
| 40635-66-3 |
|
2-Fluorobenzotrichloride, 99%
| 488-98-2 |
|
6-Nitrochrysene, 99%
| 7496-02-8 |
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2-Chloroethyl-p-toluenesulfonate, 97%
| 80-41-1 |
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Kinetin
| 525-79-1 |
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2,4-Dimethyl-1,3-pentadiene, 98%
| 1000-86-8 |
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