**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 541-47-9 |3,3-Dimethylacrylic Acid | 97 | 208-782-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Use with adequate ventilation. Wash
clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 541-47-9:
Russia: 5 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: slightly yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 10000 mm Hg @ 60C
Viscosity: Not available.
Boiling Point: 194 - 195 deg C @ 760.00mmHg
Freezing/Melting Point: 68.50 - 69.50 deg C
Autoignition Temperature: 465 deg C ( 869.00 deg F)
Flash Point: 93 deg C ( 199.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in acetone, xylene, ethanol and
Specific Gravity/Density:
Molecular Formula: C5H8O2
Molecular Weight: 100.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 541-47-9: GQ5425000
LD50/LC50:
CAS# 541-47-9: Draize test, rabbit, eye: 1 mg Severe; Draize test,
rabbit, eye: 250 ug/24H Severe; Draize test, rabbit, skin: 100 mg/24H
Moderate; Oral, mouse: LD50 = 2580 mg/kg; Oral, rat: LD50 = 3560
mg/kg; Skin, rabbit: LD50 = >3200 mg/kg.
Carcinogenicity:
3,3-Dimethylacrylic Acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 541-47-9: 1
Canada
CAS# 541-47-9 is listed on Canada's DSL List.
CAS# 541-47-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 541-47-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/23/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Trifluoroacetyl Triflate
| 68602-57-3 |
|
Allyltriphenylphosphonium bromide, 99%
| 1560-54-9 |
|
m-Anisidine
| 536-90-3 |
|
Glycerol formal, mixture of alpha- and beta form, 99+%
| 4740-78-7 |
|
4-Amino-2,3,5,6-tetrafluorobenzamide, 97%
| 1548-74-9 |
|
(2-Aminobenzoyl)hydrazide, 97%
| 1904-58-1 |
|
Reinecke salt monohydrate, reagent ACS (crystals), 93+% (gravimetry)
| 13573-16-5 |
|
2-Isobutyl-3-methoxypyrazine, 99% (GC)
| 24683-00-9 |
|
Trichloroacetic acid, sodium salt, 99%
| 650-51-1 |
|
1-Bromoundecane (Pract), 97% (GC)
| 693-67-4 |
|
Coumarin 2, Laser Grade, 99+% (UV-Vis)
| 26078-25-1 |
|
Methyl 2-chloroacetoacetate, 95%
| 4755-81-1 |
|
[(4-Fluorophenoxy)methyl]oxirane, 97%
| 108648-25-5 |
|
3,3-Dimethylacrylic Acid, 97%
| 541-47-9 |
|
N-Tert-Butylacrylamide
| 107-58-4 |
|
Decahydro-2-naphthol, 98%, Mixture of isomers
| 825-51-4 |
|
2,3-Quinoxalinedithiol
| 1199-03-7 |
|
Fast Blue BB, 98%
| 120-00-3 |
|
2,5-Dibromopyridine, 97%
| 624-28-2 |
|
Chlorophenol Red, Indicator Grade
| 4430-20-0 |
|
Lithium stearate, 95%
| 4485-12-5 |
|
Isobutyric Acid, P.A.
| 79-31-2 |
|
(2,2-Dichlorocyclopropyl)benzene, 97%
| 2415-80-7 |
|
P-Toluenesulfonamide
| 70-55-3 |
|
Benzalphthalide, 98%
| 575-61-1 |
|
Alpha-Bromo-2'- Acetonaphthone, 98%
| 613-54-7 |
|
D-(+)-Digitoxose, 99+%
| 527-52-6 |
|
(S)-(+)-2-Hydroxy-3-methylbutanoic acid, 99+%
| 17407-55-5 |
|
Methyl formate, spectro grade, 98%
| 107-31-3 |
|
5,6,11,12-Tetrahydrodibenz(b,f)Azocin-- 6-One
| 6047-29-6 |
|
Bis(cyclopentadienyl)zirconium dichloride, 98+%
| 1291-32-3 |
|
4-Oxo-3-Aza-Tricyclo-(4.2.1.0(2,5))Nonane, 99+%
| 0-01-1 |
|
2-Nitrobenzoyl Chloride, 95%
| 610-14-0 |
|
Chrysanthemyl alcohol, 98%, mixture of cis and trans
| 18383-59-0 |
|
2-Nitrobenzenesulfonamide, 96%
| 5455-59-4 |
|
(R)-3-Isopropyl-2,5-Piperazinedione
| 143673-66-9 |
|
2,2'-Azodiphenol, 99% (UV-Vis)
| 2050-14-8 |
|
Coronene
| 191-07-1 |
|
Alpha, Alpha, Alpha-Trifluoro-O-Tolyl Isocyanate, 97%
| 2285-12-3 |
|
Isovaleryl Chloride, 98%
| 108-12-3 |
|
2-(4-Tolyl)malondialdehyde, 97% (GC)
| 27956-35-0 |
|
4-Nitrobenzoic acid, 99+%
| 62-23-7 |
|
1,2,3-Trichlorobenzene, 99%
| 87-61-6 |
|
Phenyl N-Phenylphosphoramidochloridate, 99+%
| 51766-21-3 |
|
Alpha-Acetoxy-Isobutyryl Chloride, 97%
| 40635-66-3 |
|
2-Fluorobenzotrichloride, 99%
| 488-98-2 |
|
6-Nitrochrysene, 99%
| 7496-02-8 |
|
2-Chloroethyl-p-toluenesulfonate, 97%
| 80-41-1 |
|
Kinetin
| 525-79-1 |
|
2,4-Dimethyl-1,3-pentadiene, 98%
| 1000-86-8 |
|
|