**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 87-61-6 |1,2,3-Trichlorobenzene | 99% | 201-757-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to skin.
Potential Health Effects
Eye:
Causes eye irritation and possible burns.
Skin:
Causes skin irritation. Prolonged exposure may result in skin burns.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Contact with metals may evolve flammable hydrogen
gas. Containers may explode when heated. Combustible material; may
burn but does not ignite readily.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Scoop up with a nonsparking tool, then place into a
suitable container for disposal. Avoid generating dusty conditions.
Remove all sources of ignition. Provide ventilation. Do not get
water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid breathing dust, vapor, mist, or gas. Keep container tightly
closed. Do not get on skin or in eyes. Avoid ingestion and
inhalation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 87-61-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Flakes
Color: white
Odor: Moth-powder odor
pH: Not available.
Vapor Pressure: .07 mm Hg @ 25 deg
Viscosity: Not available.
Boiling Point: 218 - 219 deg C @ 760.00mm Hg
Freezing/Melting Point: 53 - 55 deg C
Autoignition Temperature: 571 deg C ( 1,059.80 deg F)
Flash Point: 126 deg C ( 258.80 deg F)
Explosion Limits, lower: 2.50 vol %
Explosion Limits, upper: 6.60 vol %
Decomposition Temperature:
Solubility in water: very soluble in ether, benzene
Specific Gravity/Density: 1.69
Molecular Formula: C6H3Cl3
Molecular Weight: 181.45
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 87-61-6: DC2095000
LD50/LC50:
CAS# 87-61-6: Oral, rat: LD50 = 1830 mg/kg.
Oral, rat:
Carcinogenicity:
1,2,3-Trichlorobenzene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
log Pow 4.49 Fish toxicity: LC50 (14day) guppy 3.3 mg/l
(Konemann,W.H. Qualitative Structure-Activity Relationships for
Kinetics and Toxicity of Aquatic Pollutants and their Mixtures to
Fish 1979, Univ.Utrecht). LD50 intraperitoneal rainbow trout 5600
mg/kg (Hodson,P.V. et al Environ.Toxicol.Chem.1988, 7(6), 443-454).
Invertebrate toxicity: EC50 (30min) Photobacterium phosphoreum 14 ppm
Microtox test (Kaiser,K.L.E. et al Water Pollut.Res.J.Can.1991,
26(3), 361-431).
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 38 Irritating to skin.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 87-61-6: 3
Canada
CAS# 87-61-6 is listed on Canada's DSL List.
CAS# 87-61-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 87-61-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/08/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Trifluoroacetyl Triflate
| 68602-57-3 |
|
Allyltriphenylphosphonium bromide, 99%
| 1560-54-9 |
|
m-Anisidine
| 536-90-3 |
|
Glycerol formal, mixture of alpha- and beta form, 99+%
| 4740-78-7 |
|
4-Amino-2,3,5,6-tetrafluorobenzamide, 97%
| 1548-74-9 |
|
(2-Aminobenzoyl)hydrazide, 97%
| 1904-58-1 |
|
Reinecke salt monohydrate, reagent ACS (crystals), 93+% (gravimetry)
| 13573-16-5 |
|
2-Isobutyl-3-methoxypyrazine, 99% (GC)
| 24683-00-9 |
|
Trichloroacetic acid, sodium salt, 99%
| 650-51-1 |
|
1-Bromoundecane (Pract), 97% (GC)
| 693-67-4 |
|
Coumarin 2, Laser Grade, 99+% (UV-Vis)
| 26078-25-1 |
|
Methyl 2-chloroacetoacetate, 95%
| 4755-81-1 |
|
[(4-Fluorophenoxy)methyl]oxirane, 97%
| 108648-25-5 |
|
3,3-Dimethylacrylic Acid, 97%
| 541-47-9 |
|
N-Tert-Butylacrylamide
| 107-58-4 |
|
Decahydro-2-naphthol, 98%, Mixture of isomers
| 825-51-4 |
|
2,3-Quinoxalinedithiol
| 1199-03-7 |
|
Fast Blue BB, 98%
| 120-00-3 |
|
2,5-Dibromopyridine, 97%
| 624-28-2 |
|
Chlorophenol Red, Indicator Grade
| 4430-20-0 |
|
Lithium stearate, 95%
| 4485-12-5 |
|
Isobutyric Acid, P.A.
| 79-31-2 |
|
(2,2-Dichlorocyclopropyl)benzene, 97%
| 2415-80-7 |
|
P-Toluenesulfonamide
| 70-55-3 |
|
Benzalphthalide, 98%
| 575-61-1 |
|
Alpha-Bromo-2'- Acetonaphthone, 98%
| 613-54-7 |
|
D-(+)-Digitoxose, 99+%
| 527-52-6 |
|
(S)-(+)-2-Hydroxy-3-methylbutanoic acid, 99+%
| 17407-55-5 |
|
Methyl formate, spectro grade, 98%
| 107-31-3 |
|
5,6,11,12-Tetrahydrodibenz(b,f)Azocin-- 6-One
| 6047-29-6 |
|
Bis(cyclopentadienyl)zirconium dichloride, 98+%
| 1291-32-3 |
|
4-Oxo-3-Aza-Tricyclo-(4.2.1.0(2,5))Nonane, 99+%
| 0-01-1 |
|
2-Nitrobenzoyl Chloride, 95%
| 610-14-0 |
|
Chrysanthemyl alcohol, 98%, mixture of cis and trans
| 18383-59-0 |
|
2-Nitrobenzenesulfonamide, 96%
| 5455-59-4 |
|
(R)-3-Isopropyl-2,5-Piperazinedione
| 143673-66-9 |
|
2,2'-Azodiphenol, 99% (UV-Vis)
| 2050-14-8 |
|
Coronene
| 191-07-1 |
|
Alpha, Alpha, Alpha-Trifluoro-O-Tolyl Isocyanate, 97%
| 2285-12-3 |
|
Isovaleryl Chloride, 98%
| 108-12-3 |
|
2-(4-Tolyl)malondialdehyde, 97% (GC)
| 27956-35-0 |
|
4-Nitrobenzoic acid, 99+%
| 62-23-7 |
|
1,2,3-Trichlorobenzene, 99%
| 87-61-6 |
|
Phenyl N-Phenylphosphoramidochloridate, 99+%
| 51766-21-3 |
|
Alpha-Acetoxy-Isobutyryl Chloride, 97%
| 40635-66-3 |
|
2-Fluorobenzotrichloride, 99%
| 488-98-2 |
|
6-Nitrochrysene, 99%
| 7496-02-8 |
|
2-Chloroethyl-p-toluenesulfonate, 97%
| 80-41-1 |
|
Kinetin
| 525-79-1 |
|
2,4-Dimethyl-1,3-pentadiene, 98%
| 1000-86-8 |
|
|