**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 4067-16-7 |Pentaethylenehexamine | 69.5 | 223-775-9 |
|----------------|--------------------------------------|----------|-----------|
| 7727-37-9 |Nitrogen | 30.5 | 231-783-9 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C N
Risk Phrases: 22 34 43 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns. May cause sensitization by skin
contact. Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause severe and permanent damage to the
digestive tract. Causes gastrointestinal tract burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
Repeated or prolonged exposure may cause allergic reactions in
sensitive individuals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode in
the heat of a fire. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Do
NOT get water inside containers. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Do not ingest or
inhale. Use with adequate ventilation. Use only in a chemical fume
hood. Discard contaminated shoes.
Storage:
Store in a cool, dry place. Keep container closed when not in use.
Store in a tightly closed container. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 4067-16-7:
CAS# 7727-37-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear yellow viscous liquid
Odor: amine-like
pH: Not available.
Vapor Pressure: < 1 mbar @ 20 deg C
Viscosity: Not available.
Boiling Point: 380 deg C
Freezing/Melting Point: -35 deg C
Autoignition Temperature: 360 deg C ( 680.00 deg F)
Flash Point: 175 deg C ( 347.00 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: immiscible with water
Specific Gravity/Density: .9500g/cm3
Molecular Formula: H2N(CH2CH2NH)4CH2CH2NH2
Molecular Weight: 232.44
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4067-16-7: RZ2680000
CAS# 7727-37-9: QW9700000
LD50/LC50:
CAS# 4067-16-7: Oral, rat: LD50 = 1600 mg/kg.
CAS# 7727-37-9.
Carcinogenicity:
Pentaethylenehexamine -
Not listed by ACGIH, IARC, or NTP.
Nitrogen -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 8
UN Number: 2735
Packing Group: III
IMO
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: III
RID/ADR
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C N
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 4067-16-7: 2
CAS# 7727-37-9: 0
Canada
CAS# 4067-16-7 is listed on Canada's DSL List.
CAS# 7727-37-9 is listed on Canada's DSL List.
CAS# 4067-16-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 7727-37-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4067-16-7 is listed on the TSCA inventory.
CAS# 7727-37-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/15/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Chlorosulfonic acid, 97%
| 7790-94-5 |
|
alpha-Bromo-3,5-difluorotoluene, 98%
| 141776-91-2 |
|
Methyl 3-(trifluoromethyl)benzoate, 99%
| 2557-13-3 |
|
3,4-Difluorotoluene, 99%
| 2927-34-6 |
|
trans-2,4-Difluorocinnamic acid, 98%
| 94977-52-3 |
|
4-Fluoro-2-(trifluoromethyl)benzaldehyde, 98%
| 90176-80-0 |
|
2,4-Dichloro-5-fluorobenzoic acid, 99%
| 86522-89-6 |
|
3,5-Bis(Trifluoromethyl)Phenylacetonitrile , 98%
| 85068-32-2 |
|
3,5-Dichloro-4-fluorobenzotrifluoride, 98%
| 77227-81-7 |
|
2-Fluoro-4-methylaniline, 99%
| 452-80-2 |
|
2,6-Difluorotoluene, 99%
| 443-84-5 |
|
3-Fluoro-4-methoxybenzoic acid, 98%
| 403-20-3 |
|
DL-beta-Ethylphenethyl alcohol, 98%
| 2035-94-1 |
|
(S)-(+)-3-Hydroxytetrahydrofuran, 99%
| 86087-23-2 |
|
S-(+)-Ketamine hydrochloride, 99%
| 33795-24-3 |
|
1,3-Butadiene, 98%
| 106-99-0 |
|
Pentaethylenehexamine, Tech., 30.5% Nitrogen
| 4067-16-7 |
|
4-Nitrophenetole, 98%
| 100-29-8 |
|
4-Aminotoluene-2-sulfonic acid, 97%
| 118-88-7 |
|
Poly(vinyl propionate), solution in toluene, average MW ca. 34,000
| 108-88-3 |
|
Poly(Vinyltoluene), Mixed Isomers, Average MW ca. 80.000 (GPC)
| 9017-21-4 |
|
Poly(isodecyl methacrylate), solution in toluene, average M.W. ca.
| 108-88-3 |
|
Poly(Octadecyl Methacrylate), Solution in Toluene, Average MW ca.
| 25639-21-8 |
|
Polyethylenimine, 37 Wt% Aqueous Solution, 80% Ethoxylated
| 7732-18-5 |
|
3-(Trimethylsilyl)-Propionic Acid, Sodium Salt, 99+%
| 37013-20-0 |
|
Hexyl acrylate
| 2499-95-8 |
|
2,3,4-Trichloroanisole, 98%
| 54135-80-7 |
|
1,6-Hexanediol dimethacrylate
| 6606-59-3 |
|
N-Carbobenzyloxy-L-Glutamic Acid 1-Methyl Ester, 98%
| 5672-83-3 |
|
Cinchonidine, 98.5-101% (On The Dried Substance)
| 485-71-2 |
|
N-Carbobenzyloxy-L-Threonine Methyl Ester, 98%
| 57224-63-2 |
|
(+)-(4,6-O-Benzylidene)methyl-alpha-D-glucopyranoside, 97%
| 3162-96-7 |
|
N-(9-Fluorenylmethoxycarbonyl)-L-proline pentafluorophenyl ester, 97%
| 86060-90-4 |
|
5-Bromoindoxyl acetate, 98%
| 17357-14-1 |
|
Cis-Himic Anhydride, 97%
| 129-64-6 |
|
L-Proline benzyl ester hydrochloride, 98%
| 16652-71-4 |
|
Hexamminecobalt (III) Chloride, 99.999%
| 10534-89-1 |
|
4-Bromo-2-Methylaniline Hydrochloride, 98%
| 13194-70-2 |
|
Ferrocenecarboxaldehyde, 98%
| 12093-10-6 |
|
1,1'-Ferrocenedicarboxylic Acid, 96%
| 1293-87-4 |
|
Chromium hexacarbonyl, 99%
| 13007-92-6 |
|
Lanthanum oxide, 99.99%
| 1312-81-8 |
|
Platinum (IV) Oxide, 83% Pt
| 1314-15-4 |
|
Lead(II) oxide, 99.999%
| 1317-36-8 |
|
Arsenic (III) Oxide, 99.999%
| 1327-53-3 |
|
Tris(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Gadolinium, 99.9%
| 14768-15-1 |
|
Phenylphosphinic acid, 99%
| 1779-48-2 |
|
Triethyl Phosphite, 98%
| 122-52-1 |
|
2,3,6-Trifluoroaniline, 99%
| 67815-56-9 |
|
Alpha,Alpha,Alpha,2-Tetrafluoro-p-Tolunitrile, 98%
| 146070-34-0 |
|
|