**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 67815-56-9 |2,3,6-Trifluoroaniline | 99% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. Methemoglobinemia is characterized by
dizziness, drowsiness, headache, shortness of breath, cyanosis
(bluish discoloration of skin due to deficient oxygenation of the
blood), rapid heart rate and chocolate-brown colored blood. May form
methemoglobin which in sufficient concentration causes cyanosis
(bluish discoloration of skin due to deficient oxygenation of the
blood).
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Aspiration may
lead to pulmonary edema. Methemoglobinemia is characterized by
dizziness, drowsiness, headache, shortness of breath, cyanosis
(bluish discoloration of skin due to deficient oxygenation of the
blood), rapid heart rate and chocolate-brown blood. Inhalation of
aniline causes anoxia due to the formation of methemoglobin.
Inhalation at high concentrations may cause CNS depression and
asphixiation.
Chronic:
Absorption into the body leads to the formation of methemoglobin
which in sufficient concentrations causes cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out
with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 67815-56-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless - pale-yellow
Odor: aniline-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 61 deg C ( 141.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.3900g/cm3
Molecular Formula: F3C6H2NH2
Molecular Weight: 147.10
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67815-56-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,3,6-Trifluoroaniline -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 67815-56-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 67815-56-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67815-56-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/23/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Chlorosulfonic acid, 97%
| 7790-94-5 |
|
alpha-Bromo-3,5-difluorotoluene, 98%
| 141776-91-2 |
|
Methyl 3-(trifluoromethyl)benzoate, 99%
| 2557-13-3 |
|
3,4-Difluorotoluene, 99%
| 2927-34-6 |
|
trans-2,4-Difluorocinnamic acid, 98%
| 94977-52-3 |
|
4-Fluoro-2-(trifluoromethyl)benzaldehyde, 98%
| 90176-80-0 |
|
2,4-Dichloro-5-fluorobenzoic acid, 99%
| 86522-89-6 |
|
3,5-Bis(Trifluoromethyl)Phenylacetonitrile , 98%
| 85068-32-2 |
|
3,5-Dichloro-4-fluorobenzotrifluoride, 98%
| 77227-81-7 |
|
2-Fluoro-4-methylaniline, 99%
| 452-80-2 |
|
2,6-Difluorotoluene, 99%
| 443-84-5 |
|
3-Fluoro-4-methoxybenzoic acid, 98%
| 403-20-3 |
|
DL-beta-Ethylphenethyl alcohol, 98%
| 2035-94-1 |
|
(S)-(+)-3-Hydroxytetrahydrofuran, 99%
| 86087-23-2 |
|
S-(+)-Ketamine hydrochloride, 99%
| 33795-24-3 |
|
1,3-Butadiene, 98%
| 106-99-0 |
|
Pentaethylenehexamine, Tech., 30.5% Nitrogen
| 4067-16-7 |
|
4-Nitrophenetole, 98%
| 100-29-8 |
|
4-Aminotoluene-2-sulfonic acid, 97%
| 118-88-7 |
|
Poly(vinyl propionate), solution in toluene, average MW ca. 34,000
| 108-88-3 |
|
Poly(Vinyltoluene), Mixed Isomers, Average MW ca. 80.000 (GPC)
| 9017-21-4 |
|
Poly(isodecyl methacrylate), solution in toluene, average M.W. ca.
| 108-88-3 |
|
Poly(Octadecyl Methacrylate), Solution in Toluene, Average MW ca.
| 25639-21-8 |
|
Polyethylenimine, 37 Wt% Aqueous Solution, 80% Ethoxylated
| 7732-18-5 |
|
3-(Trimethylsilyl)-Propionic Acid, Sodium Salt, 99+%
| 37013-20-0 |
|
Hexyl acrylate
| 2499-95-8 |
|
2,3,4-Trichloroanisole, 98%
| 54135-80-7 |
|
1,6-Hexanediol dimethacrylate
| 6606-59-3 |
|
N-Carbobenzyloxy-L-Glutamic Acid 1-Methyl Ester, 98%
| 5672-83-3 |
|
Cinchonidine, 98.5-101% (On The Dried Substance)
| 485-71-2 |
|
N-Carbobenzyloxy-L-Threonine Methyl Ester, 98%
| 57224-63-2 |
|
(+)-(4,6-O-Benzylidene)methyl-alpha-D-glucopyranoside, 97%
| 3162-96-7 |
|
N-(9-Fluorenylmethoxycarbonyl)-L-proline pentafluorophenyl ester, 97%
| 86060-90-4 |
|
5-Bromoindoxyl acetate, 98%
| 17357-14-1 |
|
Cis-Himic Anhydride, 97%
| 129-64-6 |
|
L-Proline benzyl ester hydrochloride, 98%
| 16652-71-4 |
|
Hexamminecobalt (III) Chloride, 99.999%
| 10534-89-1 |
|
4-Bromo-2-Methylaniline Hydrochloride, 98%
| 13194-70-2 |
|
Ferrocenecarboxaldehyde, 98%
| 12093-10-6 |
|
1,1'-Ferrocenedicarboxylic Acid, 96%
| 1293-87-4 |
|
Chromium hexacarbonyl, 99%
| 13007-92-6 |
|
Lanthanum oxide, 99.99%
| 1312-81-8 |
|
Platinum (IV) Oxide, 83% Pt
| 1314-15-4 |
|
Lead(II) oxide, 99.999%
| 1317-36-8 |
|
Arsenic (III) Oxide, 99.999%
| 1327-53-3 |
|
Tris(2,2,6,6-Tetramethyl-3,5-Heptanedionato)Gadolinium, 99.9%
| 14768-15-1 |
|
Phenylphosphinic acid, 99%
| 1779-48-2 |
|
Triethyl Phosphite, 98%
| 122-52-1 |
|
2,3,6-Trifluoroaniline, 99%
| 67815-56-9 |
|
Alpha,Alpha,Alpha,2-Tetrafluoro-p-Tolunitrile, 98%
| 146070-34-0 |
|
|