**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 4165-61-1 |Aniline-2,3,4,5,6-d5 | 99+ atom | 224-015-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 20/21/22 40 50 48/23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect. Very toxic to aquatic
organisms. Toxic : danger of serious damage to health by prolonged
exposure through inhalation, contact with skin and if
swallowed.Hygroscopic (absorbs moisture from the air).Light
sensitive.
Potential Health Effects
Eye:
Causes mild eye irritation. May result in corneal injury.
Skin:
Causes skin burns. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. Methemoglobinemia is
characterized by dizziness, drowsiness, headache, shortness of
breath, cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood), rapid heart rate and chocolate-brown
blood. Effects of inhalation may be delayed.
Chronic:
May cause cancer according to animal studies.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Combustible liquid. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. For small fires,
use dry chemical, carbon dioxide, or water spray. For large fires,
use dry chemical, carbon dioxide, alcohol-resistant foam, or water
spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Remove all sources of ignition.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store under
nitrogen.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 4165-61-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 0.7 mmHg @ 25 C
Viscosity: Not available.
Boiling Point: 94 deg C @ 30.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 70 deg C ( 158.00 deg F)
Explosion Limits, lower: 1.30 vol %
Explosion Limits, upper: 11.00 vol %
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.0770g/cm3
Molecular Formula: C6D5H2N
Molecular Weight: 98.17
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May discolor on
exposure to light. May discolor on exposure to air.
Conditions to Avoid:
Incompatible materials, light, ignition sources, excess heat,
exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 4165-61-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Aniline-2,3,4,5,6-d5 -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ANILINE
Hazard Class: 6.1
UN Number: 1547
Packing Group: II
IMO
Shipping Name: ANILINE
Hazard Class: 6.1
UN Number: 1547
Packing Group: II
RID/ADR
Shipping Name: ANILINE
Hazard Class: 6.1
UN Number: 1547
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 48/23/24/25 Toxic : danger of serious damage to
health by prolonged exposure through inhalation,
contact with skin and if swallowed.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 28B After contact with skin, wash immediately with
plenty of water and soap.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 4165-61-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 4165-61-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4165-61-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/28/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-(Pyrrolidinocarbonylmethyl)piperazine, 95+%
| 39890-45-4 |
|
Procion blue HB
| 12236-82-7 |
|
Cyclopentadienyliron Dicarbonyl Dimer, 99%
| 38117-54-3 |
|
Bis(6-carboxypentyl-2,4,5-trichlorophenyl) oxalate
| 75203-51-9 |
|
Benzenesulfonamide, 97% (titr.)
| 98-10-2 |
|
(s)-(+)-Methyl mandelate, 98+%
| 21210-43-5 |
|
1-Monobutyrin (Pract)
| 557-25-5 |
|
1,5-Dibromo-3-Methylpentane, 98%
| 4457-72-1 |
|
(s)-(+)-2-Methylbutyric acid 98%
| 1730-91-2 |
|
6-Nitropiperonal, 98+%
| 712-97-0 |
|
Allyl Bromide, Stabilized with Ca. 300 ppm Propylene Oxide, 99%
| 106-95-6 |
|
6-Chloropurine, 99+%
| 87-42-3 |
|
1,4-Butanedithiol, 94%
| 1191-08-8 |
|
All-Trans-Retinal, 99% (UV-VIS)
| 0-00-1 |
|
1,1,4,7,7-Pentamethyldiethylenetriamine, 99+% (GC)
| 3030-47-5 |
|
Ethyl 3-(methylthio)propionate, 99+%
| 13327-56-5 |
|
1,1,1-Trifluoroacetone, 98+%
| 421-50-1 |
|
Acrylamide-bis premix 37.5:1 (2.6% concentration)
| 79-06-1 |
|
Aniline-2,3,4,5,6-d5, 99+ atom% D
| 4165-61-1 |
|
4-Fluorophenyl sulfone, 99%
| 383-29-9 |
|
1,2-Dibromoethylene, 98%, mixture of cis and trans
| 540-49-8 |
|
1-Methyl-2-formylbenzimidazole, 99+%
| 3012-80-4 |
|
4-Aminobenzo-15-Crown-5, Hydrochloride, 98%
| 0-00-1 |
|
2-Methylthio-2-imidazoline hydriodide, 99%
| 5464-11-9 |
|
Ethyl 2-bromoisobutyrate, 98%
| 600-00-0 |
|
Sarcosine, 98%
| 107-97-1 |
|
Phenyl vinyl sulfide, 97%
| 1822-73-7 |
|
5-Hydroxy-2-methyl-3-trifluoromethyl-1H-pyrazole, 99+%
| 0-01-1 |
|
3-Chloropyridine, 99%
| 626-60-8 |
|
2-Chloro-3-ethylbenzoxazolium tetrafluoro- borate, 97%
| 63175-96-2 |
|
1-Naphtaldehyde, 99% (gc)
| 66-77-3 |
|
2-Chloromercuri-4-nitrophenol
| 24579-90-6 |
|
Ethylenediamine Tetraacetic Acid, Dipotassium Salt Dihydrate
| 2001-94-7 |
|
Hydroxybutyl methyl cellulose
| 9041-56-9 |
|
1-Methyl-2-Pyrroleacetonitrile, 95%
| 24437-41-0 |
|
DL-Alanyl-DL-alanine
| 2867-20-1 |
|
1,8-Naphthalic anhydride, 97%
| 81-84-5 |
|
2-Iodo-1,1,1-trifluoroethane, 99%
| 353-83-3 |
|
Tetrapentylammonium Bromide, 99+%
| 866-97-7 |
|
4-Chromanone, 96%(GC)
| 491-37-2 |
|
1,2-Dimethoxy-4-(2-Propenyl)Benzene, 98%
| 93-15-2 |
|
Boc-Sarcosine, 99+%
| 13734-36-6 |
|
[Bis(trimethylsilyl)]sulfide, 98%
| 3385-94-2 |
|
Bicyclo(3.3.1)Nonan-9-One, 99%
| 17931-55-4 |
|
4-Bromo-o-xylene, tech. 75-80% (remainder 3-bromo-o-xylene)
| 576-23-8 |
|
4,4'-Oxydiphenol, 99%
| 1965-09-9 |
|
Anthranilonitrile, 98%
| 1885-29-6 |
|
Fmoc-L-Proline, 99%
| 71989-31-6 |
|
L-(+)-2-Amino-6-Phosphonohexanoic Acid 98% e.e.
| 0-00-1 |
|
DL-2-Aminobutyric Acid, 99+%
| 2835-81-6 |
|
|