**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 421-50-1 |1,1,1-TRIFLUOROACETONE | | 207-005-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F+
Risk Phrases: 12 19 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Extremely flammable. May form explosive peroxides. Irritating to
eyes, respiratory system and skin.The toxicological properties of
this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). Lachrymator (substance which increases the flow of
tears).
Skin:
Causes skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Extremely
flammable liquid and vapor. May form explosive peroxides.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Contents may
develop pressure upon prolonged storage. Avoid breathing dust,
vapor, mist, or gas. Avoid contact with skin and eyes. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind,
or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a dry area. Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 421-50-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Like chloroform
pH: Not available.
Vapor Pressure: > 1.75 bar @50 deg
Viscosity: mPas 15 deg C
Boiling Point: 22 deg C @ 760.00mm Hg
Freezing/Melting Point: -78 deg C
Autoignition Temperature: Not available.
Flash Point: -30 deg C ( -22.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density: 1.2520g/cm3
Molecular Formula: C3H3F3O
Molecular Weight: 112.05
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stability unknown.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 421-50-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,1,1-TRIFLUOROACETONE -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: I
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.1
UN Number: 1993
Packing Group: I
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F+
Risk Phrases:
R 12 Extremely flammable.
R 19 May form explosive peroxides.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 421-50-1: No information available.
Canada
CAS# 421-50-1 is listed on Canada's NDSL List.
CAS# 421-50-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 421-50-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-(Pyrrolidinocarbonylmethyl)piperazine, 95+%
| 39890-45-4 |
|
Procion blue HB
| 12236-82-7 |
|
Cyclopentadienyliron Dicarbonyl Dimer, 99%
| 38117-54-3 |
|
Bis(6-carboxypentyl-2,4,5-trichlorophenyl) oxalate
| 75203-51-9 |
|
Benzenesulfonamide, 97% (titr.)
| 98-10-2 |
|
(s)-(+)-Methyl mandelate, 98+%
| 21210-43-5 |
|
1-Monobutyrin (Pract)
| 557-25-5 |
|
1,5-Dibromo-3-Methylpentane, 98%
| 4457-72-1 |
|
(s)-(+)-2-Methylbutyric acid 98%
| 1730-91-2 |
|
6-Nitropiperonal, 98+%
| 712-97-0 |
|
Allyl Bromide, Stabilized with Ca. 300 ppm Propylene Oxide, 99%
| 106-95-6 |
|
6-Chloropurine, 99+%
| 87-42-3 |
|
1,4-Butanedithiol, 94%
| 1191-08-8 |
|
All-Trans-Retinal, 99% (UV-VIS)
| 0-00-1 |
|
1,1,4,7,7-Pentamethyldiethylenetriamine, 99+% (GC)
| 3030-47-5 |
|
Ethyl 3-(methylthio)propionate, 99+%
| 13327-56-5 |
|
1,1,1-Trifluoroacetone, 98+%
| 421-50-1 |
|
Acrylamide-bis premix 37.5:1 (2.6% concentration)
| 79-06-1 |
|
Aniline-2,3,4,5,6-d5, 99+ atom% D
| 4165-61-1 |
|
4-Fluorophenyl sulfone, 99%
| 383-29-9 |
|
1,2-Dibromoethylene, 98%, mixture of cis and trans
| 540-49-8 |
|
1-Methyl-2-formylbenzimidazole, 99+%
| 3012-80-4 |
|
4-Aminobenzo-15-Crown-5, Hydrochloride, 98%
| 0-00-1 |
|
2-Methylthio-2-imidazoline hydriodide, 99%
| 5464-11-9 |
|
Ethyl 2-bromoisobutyrate, 98%
| 600-00-0 |
|
Sarcosine, 98%
| 107-97-1 |
|
Phenyl vinyl sulfide, 97%
| 1822-73-7 |
|
5-Hydroxy-2-methyl-3-trifluoromethyl-1H-pyrazole, 99+%
| 0-01-1 |
|
3-Chloropyridine, 99%
| 626-60-8 |
|
2-Chloro-3-ethylbenzoxazolium tetrafluoro- borate, 97%
| 63175-96-2 |
|
1-Naphtaldehyde, 99% (gc)
| 66-77-3 |
|
2-Chloromercuri-4-nitrophenol
| 24579-90-6 |
|
Ethylenediamine Tetraacetic Acid, Dipotassium Salt Dihydrate
| 2001-94-7 |
|
Hydroxybutyl methyl cellulose
| 9041-56-9 |
|
1-Methyl-2-Pyrroleacetonitrile, 95%
| 24437-41-0 |
|
DL-Alanyl-DL-alanine
| 2867-20-1 |
|
1,8-Naphthalic anhydride, 97%
| 81-84-5 |
|
2-Iodo-1,1,1-trifluoroethane, 99%
| 353-83-3 |
|
Tetrapentylammonium Bromide, 99+%
| 866-97-7 |
|
4-Chromanone, 96%(GC)
| 491-37-2 |
|
1,2-Dimethoxy-4-(2-Propenyl)Benzene, 98%
| 93-15-2 |
|
Boc-Sarcosine, 99+%
| 13734-36-6 |
|
[Bis(trimethylsilyl)]sulfide, 98%
| 3385-94-2 |
|
Bicyclo(3.3.1)Nonan-9-One, 99%
| 17931-55-4 |
|
4-Bromo-o-xylene, tech. 75-80% (remainder 3-bromo-o-xylene)
| 576-23-8 |
|
4,4'-Oxydiphenol, 99%
| 1965-09-9 |
|
Anthranilonitrile, 98%
| 1885-29-6 |
|
Fmoc-L-Proline, 99%
| 71989-31-6 |
|
L-(+)-2-Amino-6-Phosphonohexanoic Acid 98% e.e.
| 0-00-1 |
|
DL-2-Aminobutyric Acid, 99+%
| 2835-81-6 |
|
|