**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 540-49-8 |1,2-Dibromoethylene, mixture of cis an| 98 | 208-747-6 |
| |d trans | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 36/37/38 20
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Harmful by
inhalation.Lachrymator (substance which increases the flow of
tears).Toxic.
Potential Health Effects
Eye:
Lachrymator (substance which increases the flow of tears). Causes
severe eye irritation and possible burns.
Skin:
Causes severe skin irritation and possible burns.
Ingestion:
Harmful if swallowed. May cause severe gastrointestinal tract
irritation with nausea, vomiting and possible burns. Ingestion of
large amounts may cause CNS depression.
Inhalation:
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema. May
cause burning sensation, coughing, wheezing, laryngitis, shortness of
breath, headache, nausea, and vomiting.
Chronic:
Narcotic in high concentrations.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Immediately flush
eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid immediately. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water. Induce vomiting
only when instructed to do so by a physician.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill using an absorbent, non-combustible material such as
earth, sand, or vermiculite. Do not use combustible materials such
as sawdust. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Do not
ingest or inhale. Use only in a chemical fume hood. Discard
contaminated shoes. Do not breathe vapor.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 540-49-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 21 mm Hg @ 26 deg C
Viscosity: Not available.
Boiling Point: 110 deg C @ 754.00mmHg
Freezing/Melting Point: -53 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: practically insoluble
Specific Gravity/Density: 2.2460g/cm3
Molecular Formula: C2H2Br2
Molecular Weight: 185.85
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, magnesium.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide, bromide fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 540-49-8: KV7700000
LD50/LC50:
Not available.
Oral, rat: LD50 = 117
Carcinogenicity:
1,2-Dibromoethylene, mixture of cis and trans -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 20 Harmful by inhalation.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 540-49-8: No information available.
Canada
CAS# 540-49-8 is listed on Canada's NDSL List.
CAS# 540-49-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 540-49-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
1-(Pyrrolidinocarbonylmethyl)piperazine, 95+%
| 39890-45-4 |
|
Procion blue HB
| 12236-82-7 |
|
Cyclopentadienyliron Dicarbonyl Dimer, 99%
| 38117-54-3 |
|
Bis(6-carboxypentyl-2,4,5-trichlorophenyl) oxalate
| 75203-51-9 |
|
Benzenesulfonamide, 97% (titr.)
| 98-10-2 |
|
(s)-(+)-Methyl mandelate, 98+%
| 21210-43-5 |
|
1-Monobutyrin (Pract)
| 557-25-5 |
|
1,5-Dibromo-3-Methylpentane, 98%
| 4457-72-1 |
|
(s)-(+)-2-Methylbutyric acid 98%
| 1730-91-2 |
|
6-Nitropiperonal, 98+%
| 712-97-0 |
|
Allyl Bromide, Stabilized with Ca. 300 ppm Propylene Oxide, 99%
| 106-95-6 |
|
6-Chloropurine, 99+%
| 87-42-3 |
|
1,4-Butanedithiol, 94%
| 1191-08-8 |
|
All-Trans-Retinal, 99% (UV-VIS)
| 0-00-1 |
|
1,1,4,7,7-Pentamethyldiethylenetriamine, 99+% (GC)
| 3030-47-5 |
|
Ethyl 3-(methylthio)propionate, 99+%
| 13327-56-5 |
|
1,1,1-Trifluoroacetone, 98+%
| 421-50-1 |
|
Acrylamide-bis premix 37.5:1 (2.6% concentration)
| 79-06-1 |
|
Aniline-2,3,4,5,6-d5, 99+ atom% D
| 4165-61-1 |
|
4-Fluorophenyl sulfone, 99%
| 383-29-9 |
|
1,2-Dibromoethylene, 98%, mixture of cis and trans
| 540-49-8 |
|
1-Methyl-2-formylbenzimidazole, 99+%
| 3012-80-4 |
|
4-Aminobenzo-15-Crown-5, Hydrochloride, 98%
| 0-00-1 |
|
2-Methylthio-2-imidazoline hydriodide, 99%
| 5464-11-9 |
|
Ethyl 2-bromoisobutyrate, 98%
| 600-00-0 |
|
Sarcosine, 98%
| 107-97-1 |
|
Phenyl vinyl sulfide, 97%
| 1822-73-7 |
|
5-Hydroxy-2-methyl-3-trifluoromethyl-1H-pyrazole, 99+%
| 0-01-1 |
|
3-Chloropyridine, 99%
| 626-60-8 |
|
2-Chloro-3-ethylbenzoxazolium tetrafluoro- borate, 97%
| 63175-96-2 |
|
1-Naphtaldehyde, 99% (gc)
| 66-77-3 |
|
2-Chloromercuri-4-nitrophenol
| 24579-90-6 |
|
Ethylenediamine Tetraacetic Acid, Dipotassium Salt Dihydrate
| 2001-94-7 |
|
Hydroxybutyl methyl cellulose
| 9041-56-9 |
|
1-Methyl-2-Pyrroleacetonitrile, 95%
| 24437-41-0 |
|
DL-Alanyl-DL-alanine
| 2867-20-1 |
|
1,8-Naphthalic anhydride, 97%
| 81-84-5 |
|
2-Iodo-1,1,1-trifluoroethane, 99%
| 353-83-3 |
|
Tetrapentylammonium Bromide, 99+%
| 866-97-7 |
|
4-Chromanone, 96%(GC)
| 491-37-2 |
|
1,2-Dimethoxy-4-(2-Propenyl)Benzene, 98%
| 93-15-2 |
|
Boc-Sarcosine, 99+%
| 13734-36-6 |
|
[Bis(trimethylsilyl)]sulfide, 98%
| 3385-94-2 |
|
Bicyclo(3.3.1)Nonan-9-One, 99%
| 17931-55-4 |
|
4-Bromo-o-xylene, tech. 75-80% (remainder 3-bromo-o-xylene)
| 576-23-8 |
|
4,4'-Oxydiphenol, 99%
| 1965-09-9 |
|
Anthranilonitrile, 98%
| 1885-29-6 |
|
Fmoc-L-Proline, 99%
| 71989-31-6 |
|
L-(+)-2-Amino-6-Phosphonohexanoic Acid 98% e.e.
| 0-00-1 |
|
DL-2-Aminobutyric Acid, 99+%
| 2835-81-6 |
|
|