**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 453-20-3 |3-Hydroxytetrahydrofuran | 97 | 207-219-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. Vapors may cause eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
The toxicological properties of this material have not been fully
investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. May be harmful if swallowed.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. The toxicological
properties of this substance have not been fully investigated. May
be harmful if inhaled.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep away from heat and flame. Avoid
breathing vapor or mist.
Storage:
Keep away from heat and flame. Store in a cool, dry place. Keep
container closed when not in use. Separate from oxidizing materials.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 453-20-3:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 181 deg C @ 760 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 81 deg C ( 177.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.09 g/cm3
Molecular Formula: C4H8O2
Molecular Weight: 88.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Normally stable; however, on long term storage, materials containing
similar functional groups form peroxides of unknown stability.
Conditions to Avoid:
Ignition sources, exposure to flame, heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acid anhydrides, acid chlorides.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 453-20-3: LU3450050
LD50/LC50:
Not available.
Carcinogenicity:
3-Hydroxytetrahydrofuran -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 453-20-3: No information available.
Canada
CAS# 453-20-3 is listed on Canada's NDSL List.
CAS# 453-20-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 453-20-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Diacetin (Pract), 98% (GC)
| 25395-31-7 |
|
D-(+)-Ribonic acid gamma-lactone, 96%
| 5336-08-3 |
|
Gamma-Valerolactone, 98%
| 108-29-2 |
|
Tri-Normal-Octylamine, 98%
| 1116-76-3 |
|
1,8-Diazabicyclo[5.4.0]undec-7-ene, 98%
| 6674-22-2 |
|
2-Phenyl-4-Quinolinecarboxylic Acid, 99%
| 132-60-5 |
|
Methylnorbornene-2,3-dicarboxylic anhydride 95%, mixture of isomers
| 25134-21-8 |
|
Ruthenium, powder,-200 mesh, 99.9%
| 7440-18-8 |
|
Lauryl gallate, 96+%
| 1166-52-5 |
|
2-Chloro-4-fluoro-5-methylaniline, 99.5+%
| 116759-33-2 |
|
Glycolic acid, 67% in water
| 79-14-1 |
|
Methyl Green, zinc chloride salt, high purity biological stain
| 7114-03-6 |
|
Rubidium Hydroxide, 99.9%, 50 wt% Solution in Water
| 1310-82-3 |
|
3-Iodopropionic Acid, 98%
| 141-76-4 |
|
Adenosine 5'-triphosphate disodium salt, trihydrate, 99% (HPLC)
| 987-65-5 |
|
Methyl-d3-amine hydrochloride, 98+ atom % D
| 593-51-1 |
|
Esculin Monohydrate, 97%
| 531-75-9 |
|
Quinoline Yellow, Spirit Soluble, 95%
| 8003-22-3 |
|
Pseudothiohydantoin, 97%
| 556-90-1 |
|
DL-Ethyl 2-bromovalerate, 99%
| 615-83-8 |
|
Calcium oxalate monohydrate, 98%
| 563-72-4 |
|
Potassium formate (pract)
| 590-29-4 |
|
4-Acetylpyridine, 98%
| 1122-54-9 |
|
4-Phosphonooxy-tempo hydrate, free radical
| 22690-04-6 |
|
4-Decylbenzoyl Chloride, 98% (Titr.)
| 54256-43-8 |
|
Trichloroacetyl chloride
| 76-02-8 |
|
3-Carbamoyl-2,2,5,5-tetramethyl-3- pyrrolin-1-yloxy, free radical
| 3229-73-0 |
|
2-Thiophenesulfonyl chloride
| 16629-19-9 |
|
1,10-Diiododecane, 97%
| 16355-92-3 |
|
2,3,4-Trihydroxybenzaldehyde, 98% (titr.)
| 2144-08-3 |
|
Thulium atomic absorption standard solution, 1 mg/ml Tm in 2% HNO3
| 7440-30-4 |
|
Sodium Polyanetholesulfonate
| 52993-95-0 |
|
Tetraphenylphosphonium Iodide, 99%
| 2065-67-0 |
|
2,3-Dichloro-1-propene, 98%
| 78-88-6 |
|
N-Cyanoimido-S,S-Dimethyl-Dithiocarbonate ca. 90%, Remainder Water
| 7732-18-5 |
|
9-Fluorenone-2-Carboxylic Acid, 97% (GC)
| 784-50-9 |
|
3-(3,4-Dimethoxyphenyl)-Propionic Acid, 99%
| 2107-70-2 |
|
1-Phenyl-1,3,8-Triazaspiro(4,5) Decan-- 4-One, 95% (TLC)
| 1021-25-6 |
|
Cycloheptylamine, 99%
| 5452-35-7 |
|
3,3-Dimethylglutarimide, 99%
| 1123-40-6 |
|
Alpha-d-Methylglucoside, 99%
| 97-30-3 |
|
D-(-)-2-Aminobutyric Acid, 99+%
| 2623-91-8 |
|
3-Hydroxytetrahydrofuran, 97%
| 453-20-3 |
|
p-Aminohippuric acid, sodium salt, monohydrate 98%
| 94-16-6 |
|
Pentafluorobenzoic acid, 99%
| 602-94-8 |
|
Anthraquinone-2-sulfonic acid, sodium salt monohydrate, 90%
| 131-08-8 |
|
5-Chlorosalicylic acid, 98%
| 321-14-2 |
|
Fluoranthene, 98%
| 206-44-0 |
|
N-(4-Methoxybenzylidene)-4-Butylaniline, 99% (Titr.)
| 26227-73-6 |
|
Hydroxypropyl Methyl Cellulose
| 9004-65-3 |
|
|