**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 79-14-1 |Glycolic acid | 67 | 201-180-5 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 33 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May be harmful if swallowed.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. May react
with metals and lead to the formation of flammable hydrogen gas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Do not get in eyes, on skin, or on clothing. Keep
container tightly closed. Do not ingest or inhale. Use with adequate
ventilation. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 79-14-1:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: none reported
pH: acidic
Vapor Pressure: 8.1 mm Hg @ 80C
Viscosity: Not available.
Boiling Point: 113 deg C
Freezing/Melting Point: 10 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: 1.27
Molecular Formula: C2H4O3
Molecular Weight: 76.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 79-14-1: MC5250000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 79-14-1: Draize test, rabbit, eye: 2 mg Severe; Inhalation,
rat: LC50 = 7.1 ug/m3/4H; Oral, rat: LD50 = 1950 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Glycolic acid -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 79-14-1: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 79-14-1 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 79-14-1 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 79-14-1 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 4/13/1998 Revision #3 Date: 3/28/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Diacetin (Pract), 98% (GC)
| 25395-31-7 |
|
D-(+)-Ribonic acid gamma-lactone, 96%
| 5336-08-3 |
|
Gamma-Valerolactone, 98%
| 108-29-2 |
|
Tri-Normal-Octylamine, 98%
| 1116-76-3 |
|
1,8-Diazabicyclo[5.4.0]undec-7-ene, 98%
| 6674-22-2 |
|
2-Phenyl-4-Quinolinecarboxylic Acid, 99%
| 132-60-5 |
|
Methylnorbornene-2,3-dicarboxylic anhydride 95%, mixture of isomers
| 25134-21-8 |
|
Ruthenium, powder,-200 mesh, 99.9%
| 7440-18-8 |
|
Lauryl gallate, 96+%
| 1166-52-5 |
|
2-Chloro-4-fluoro-5-methylaniline, 99.5+%
| 116759-33-2 |
|
Glycolic acid, 67% in water
| 79-14-1 |
|
Methyl Green, zinc chloride salt, high purity biological stain
| 7114-03-6 |
|
Rubidium Hydroxide, 99.9%, 50 wt% Solution in Water
| 1310-82-3 |
|
3-Iodopropionic Acid, 98%
| 141-76-4 |
|
Adenosine 5'-triphosphate disodium salt, trihydrate, 99% (HPLC)
| 987-65-5 |
|
Methyl-d3-amine hydrochloride, 98+ atom % D
| 593-51-1 |
|
Esculin Monohydrate, 97%
| 531-75-9 |
|
Quinoline Yellow, Spirit Soluble, 95%
| 8003-22-3 |
|
Pseudothiohydantoin, 97%
| 556-90-1 |
|
DL-Ethyl 2-bromovalerate, 99%
| 615-83-8 |
|
Calcium oxalate monohydrate, 98%
| 563-72-4 |
|
Potassium formate (pract)
| 590-29-4 |
|
4-Acetylpyridine, 98%
| 1122-54-9 |
|
4-Phosphonooxy-tempo hydrate, free radical
| 22690-04-6 |
|
4-Decylbenzoyl Chloride, 98% (Titr.)
| 54256-43-8 |
|
Trichloroacetyl chloride
| 76-02-8 |
|
3-Carbamoyl-2,2,5,5-tetramethyl-3- pyrrolin-1-yloxy, free radical
| 3229-73-0 |
|
2-Thiophenesulfonyl chloride
| 16629-19-9 |
|
1,10-Diiododecane, 97%
| 16355-92-3 |
|
2,3,4-Trihydroxybenzaldehyde, 98% (titr.)
| 2144-08-3 |
|
Thulium atomic absorption standard solution, 1 mg/ml Tm in 2% HNO3
| 7440-30-4 |
|
Sodium Polyanetholesulfonate
| 52993-95-0 |
|
Tetraphenylphosphonium Iodide, 99%
| 2065-67-0 |
|
2,3-Dichloro-1-propene, 98%
| 78-88-6 |
|
N-Cyanoimido-S,S-Dimethyl-Dithiocarbonate ca. 90%, Remainder Water
| 7732-18-5 |
|
9-Fluorenone-2-Carboxylic Acid, 97% (GC)
| 784-50-9 |
|
3-(3,4-Dimethoxyphenyl)-Propionic Acid, 99%
| 2107-70-2 |
|
1-Phenyl-1,3,8-Triazaspiro(4,5) Decan-- 4-One, 95% (TLC)
| 1021-25-6 |
|
Cycloheptylamine, 99%
| 5452-35-7 |
|
3,3-Dimethylglutarimide, 99%
| 1123-40-6 |
|
Alpha-d-Methylglucoside, 99%
| 97-30-3 |
|
D-(-)-2-Aminobutyric Acid, 99+%
| 2623-91-8 |
|
3-Hydroxytetrahydrofuran, 97%
| 453-20-3 |
|
p-Aminohippuric acid, sodium salt, monohydrate 98%
| 94-16-6 |
|
Pentafluorobenzoic acid, 99%
| 602-94-8 |
|
Anthraquinone-2-sulfonic acid, sodium salt monohydrate, 90%
| 131-08-8 |
|
5-Chlorosalicylic acid, 98%
| 321-14-2 |
|
Fluoranthene, 98%
| 206-44-0 |
|
N-(4-Methoxybenzylidene)-4-Butylaniline, 99% (Titr.)
| 26227-73-6 |
|
Hydroxypropyl Methyl Cellulose
| 9004-65-3 |
|
|