**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | Balance | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 10191-60-3 |N-Cyanoimido-S,S-Dimethyl-Dithiocarbon| ca. 90% | 233-467-6 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Lachrymator
(substance which increases the flow of tears).
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury. Lachrymator
(substance which increases the flow of tears). May cause chemical
conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause cardiac disturbances. May cause central nervous
system depression.
Inhalation:
Causes respiratory tract irritation. May cause cardiac
abnormalities. Can produce delayed pulmonary edema. Inhalation at
high concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Containers may explode when heated. Runoff from fire control or
dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Do NOT get water
inside containers. For small fires, use dry chemical, carbon
dioxide, or water spray. For large fires, use dry chemical, carbon
dioxide, alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation. Use with adequate ventilation. Wash clothing before
reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7732-18-5:
CAS# 10191-60-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 50.00 - 51.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: 112 deg C ( 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C4H6N2S2
Molecular Weight: 146.22
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and
toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7732-18-5: ZC0110000
CAS# 10191-60-3 unlisted.
LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 10191-60-3.
Carcinogenicity:
Water -
Not listed by ACGIH, IARC, or NTP.
N-Cyanoimido-S,S-Dimethyl-Dithiocarbonate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 10191-60-3: No information available.
Canada
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 10191-60-3 is listed on Canada's NDSL List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 10191-60-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 10191-60-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Diacetin (Pract), 98% (GC)
| 25395-31-7 |
|
D-(+)-Ribonic acid gamma-lactone, 96%
| 5336-08-3 |
|
Gamma-Valerolactone, 98%
| 108-29-2 |
|
Tri-Normal-Octylamine, 98%
| 1116-76-3 |
|
1,8-Diazabicyclo[5.4.0]undec-7-ene, 98%
| 6674-22-2 |
|
2-Phenyl-4-Quinolinecarboxylic Acid, 99%
| 132-60-5 |
|
Methylnorbornene-2,3-dicarboxylic anhydride 95%, mixture of isomers
| 25134-21-8 |
|
Ruthenium, powder,-200 mesh, 99.9%
| 7440-18-8 |
|
Lauryl gallate, 96+%
| 1166-52-5 |
|
2-Chloro-4-fluoro-5-methylaniline, 99.5+%
| 116759-33-2 |
|
Glycolic acid, 67% in water
| 79-14-1 |
|
Methyl Green, zinc chloride salt, high purity biological stain
| 7114-03-6 |
|
Rubidium Hydroxide, 99.9%, 50 wt% Solution in Water
| 1310-82-3 |
|
3-Iodopropionic Acid, 98%
| 141-76-4 |
|
Adenosine 5'-triphosphate disodium salt, trihydrate, 99% (HPLC)
| 987-65-5 |
|
Methyl-d3-amine hydrochloride, 98+ atom % D
| 593-51-1 |
|
Esculin Monohydrate, 97%
| 531-75-9 |
|
Quinoline Yellow, Spirit Soluble, 95%
| 8003-22-3 |
|
Pseudothiohydantoin, 97%
| 556-90-1 |
|
DL-Ethyl 2-bromovalerate, 99%
| 615-83-8 |
|
Calcium oxalate monohydrate, 98%
| 563-72-4 |
|
Potassium formate (pract)
| 590-29-4 |
|
4-Acetylpyridine, 98%
| 1122-54-9 |
|
4-Phosphonooxy-tempo hydrate, free radical
| 22690-04-6 |
|
4-Decylbenzoyl Chloride, 98% (Titr.)
| 54256-43-8 |
|
Trichloroacetyl chloride
| 76-02-8 |
|
3-Carbamoyl-2,2,5,5-tetramethyl-3- pyrrolin-1-yloxy, free radical
| 3229-73-0 |
|
2-Thiophenesulfonyl chloride
| 16629-19-9 |
|
1,10-Diiododecane, 97%
| 16355-92-3 |
|
2,3,4-Trihydroxybenzaldehyde, 98% (titr.)
| 2144-08-3 |
|
Thulium atomic absorption standard solution, 1 mg/ml Tm in 2% HNO3
| 7440-30-4 |
|
Sodium Polyanetholesulfonate
| 52993-95-0 |
|
Tetraphenylphosphonium Iodide, 99%
| 2065-67-0 |
|
2,3-Dichloro-1-propene, 98%
| 78-88-6 |
|
N-Cyanoimido-S,S-Dimethyl-Dithiocarbonate ca. 90%, Remainder Water
| 7732-18-5 |
|
9-Fluorenone-2-Carboxylic Acid, 97% (GC)
| 784-50-9 |
|
3-(3,4-Dimethoxyphenyl)-Propionic Acid, 99%
| 2107-70-2 |
|
1-Phenyl-1,3,8-Triazaspiro(4,5) Decan-- 4-One, 95% (TLC)
| 1021-25-6 |
|
Cycloheptylamine, 99%
| 5452-35-7 |
|
3,3-Dimethylglutarimide, 99%
| 1123-40-6 |
|
Alpha-d-Methylglucoside, 99%
| 97-30-3 |
|
D-(-)-2-Aminobutyric Acid, 99+%
| 2623-91-8 |
|
3-Hydroxytetrahydrofuran, 97%
| 453-20-3 |
|
p-Aminohippuric acid, sodium salt, monohydrate 98%
| 94-16-6 |
|
Pentafluorobenzoic acid, 99%
| 602-94-8 |
|
Anthraquinone-2-sulfonic acid, sodium salt monohydrate, 90%
| 131-08-8 |
|
5-Chlorosalicylic acid, 98%
| 321-14-2 |
|
Fluoranthene, 98%
| 206-44-0 |
|
N-(4-Methoxybenzylidene)-4-Butylaniline, 99% (Titr.)
| 26227-73-6 |
|
Hydroxypropyl Methyl Cellulose
| 9004-65-3 |
|
|